Biomass pretreatment for fast pyrolysis to liquids

• US 8,425,766 B2
• Filed: 07/11/2012
• Issued: 04/23/2013
• Est. Priority Date: 03/10/2011
• Status: Active Grant

• Current Assignee: MARD Incorporated
• Original Assignee: Kior Inc.
• Inventors: Bartek, Robert, Brady, Michael, Stamires, Dennis
• Primary Examiner(s): MCCAIG, BRIAN A
• Application Number:
  US13/546,271
• Publication Number:
  US 20120272565A1
• Time in Patent Office: 286 Days
• Field of Search: 208400-405, 585/469, 585/638, 585/733
• US Class Current: 208/400
• CPC Class Codes: C10B 49/16 with moving solid heat-carriers in divided form
• CPC Class Codes: C10B 53/02 of cellulose-containing material production of pyroligneous acid C10C5/00
• CPC Class Codes: C10B 57/08 Non-mechanical pretreatment of the charge C10L9/00 takes precedence, e.g. desulfurization
• CPC Class Codes: C10C 5/00 Production of pyroligneous acid distillation of wood, dry distillation of organic wastecarbonisation of wood C10B
• CPC Class Codes: C10G 1/02 by distillation
• CPC Class Codes: C10G 1/08 with moving catalysts
• CPC Class Codes: C10G 2300/1011 Biomass
• CPC Class Codes: C10L 1/02 essentially based on components consisting of carbon, hydrogen, and oxygen only
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel
• CPC Class Codes: Y02P 30/20 using bio-feedstock

Abstract

Aspects of the present invention relate to methods, systems, and compositions for preparing a solid biomass for fast pyrolysis. The method includes contacting the solid biomass with an inorganic material present in an effective amount for increasing fast pyrolysis yield of an organic liquid product (e.g., bio-oil). In various embodiments, the inorganic material is selected from the group consisting of aluminum sulfate, aluminum nitrate, aluminum chloride, aluminum hydroxide, ammonium hydroxide, magnesium hydroxide, potassium hydroxide, and combinations thereof.

Claims

1. A method for producing an organic liquid product from a solid biomass, the method comprising:

(a) pre-processing the solid biomass to produce a modified solid biomass, wherein the step of pre-processing comprises demineralization, solvent explosion, heat treatment or any combination of any of the foregoing, wherein in the solid biomass is subjected to one or more of;

(1) demineralization and wherein the demineralization comprises

(i) contacting the solid biomass with a solvent to produce a swelled biomass;

(ii) removing at least part of the solvent from the swelled biomass; and

(iii) optionally repeating the steps of contacting and removing;

(2) solvent explosion and wherein the solvent is ammonia, water or carbon dioxide;

(b) contacting the pre-processed biomass with an inorganic material present in an effective amount for increasing pyrolysis yield of an organic liquid product to form a pre-treated biomass, wherein the inorganic material is aluminum sulfate, ammonium hydroxide, or any combination of any of the foregoing; and

(c) subjecting the solid pre-treated biomass to a pyrolysis reaction in the presence of the inorganic material to produce the organic liquid product.

2. The method of claim 1 wherein in the step of pre-processing, the demineralization reduces ash content of the biomass to less than 10 wt %.

3. The method of claim 1 wherein in the step of pre-processing, solvent explosion is carried before or after demineralization.

4. The method of claim 1 wherein in the step of pre-processing, the solid biomass is subjected to heat treatment at a temperature ranging from 100°

C. to 375°

C.

5. The method of claim 1 wherein the solid biomass is contacted with the inorganic material before being subjected to solvent explosion.

6. The method of claim 1 further comprising forming biomass particles after the pre-processing step.

7. The method of claim 1 wherein the inorganic material is present between about 0.1 wt % to about 4 wt % in the pre-treated biomass.

8. A method for producing an organic liquid product from a solid biomass, the method comprising:

(a) contacting the solid biomass with a solvent to produce a swelled biomass;

(b) removing at least part of the solvent from the swelled biomass to remove at least part of the minerals from the biomass forming a demineralized solid biomass;

(c) contacting the demineralized solid biomass with an inorganic material present in an effective amount for increasing pyrolysis yield of an organic liquid product to form a pre-treated biomass, wherein the inorganic material is aluminum sulfate, ammonium hydroxide, or any combination of any of the foregoing; and

(d) subjecting the solid pre-treated biomass to a pyrolysis reaction in the presence of the inorganic material to produce the organic liquid product.

9. The method of claim 8 wherein the solvent is an acid or a base.

10. The method of claim 8 wherein the solvent is a liquid pyrolysis product.

11. The method of claim 8 wherein demineralization reduces ash content of the biomass to less than 10 wt %.

12. The method of claim 8 further subjecting the solid biomass to solvent explosion before step a), after step b) or after step c).

13. The method of claim 8 wherein the inorganic material is present between about 0.1 wt % to about 4 wt % in the pre-treated biomass.

14. A method for pretreating a solid biomass for pyrolysis, the method comprising:

(a) pre-processing the solid biomass to produce a modified solid biomass, wherein the step of pre-processing comprises demineralization, solvent explosion, heat treatment or any combinations of the foregoing, wherein the solid biomass is subjected to solvent explosion and wherein the solvent is ammonia, water or carbon dioxide; and

(b) contacting the pre-processed biomass with an inorganic material present in an effective amount for increasing pyrolysis yield of an organic liquid product to form a pre-treated biomass, wherein the inorganic material is aluminum sulfate, ammonium hydroxide, or any combination of any of the foregoing.

15. The method of claim 14 wherein in the step of pre-processing, the solid biomass is subjected to heat treatment at a temperature ranging from 100°

C. to 375°

C.

16. The method of claim 14 further comprising forming biomass particles after the pre-processing step.

17. The method of claim 14 wherein the demineralization step reduces ash content of the biomass to less than 10 wt %.