Nanoporous media templated from unsymmetrical amphiphilic porogens

• US 8,436,062 B2
• Filed: 05/04/2011
• Issued: 05/07/2013
• Est. Priority Date: 04/20/2005
• Status: Expired due to Fees

• Current Assignee: International Business Machines Corporation
• Original Assignee: International Business Machines Corporation
• Inventors: Cha, Jennifer Nam, Hedrick, James Lupton, Kim, Ho-Cheol, Lee, Victor Yee-Way, Magbitang, Teddie Peregrino, Miller, Robert Dennis, Volksen, Willi
• Primary Examiner(s): Eashoo, Mark
• Assistant Examiner(s): MCCULLEY, MEGAN CASSANDRA
• Application Number:
  US13/101,017
• Publication Number:
  US 20110245433A1
• Time in Patent Office: 734 Days
• Field of Search: 521/77, 521/63
• US Class Current: 521/63
• CPC Class Codes: C08G 63/66 Polyesters containing oxygen in the form of ether groups C08G63/42, C08G63/58 take precedence
• CPC Class Codes: C08J 9/26 by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out
• CPC Class Codes: C08K 5/5419 containing at least one Si—C bond
• CPC Class Codes: C08L 67/00 Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain of polyester-amides C08L77/12; of polyester-imides C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes

Abstract

Substantially or roughly spherical micellar structures useful in the formation of nanoporous materials by templating are disclosed. A roughly spherical micellar structure is formed by organization of one or more spatially unsymmetric organic amphiphilic molecules. Each of those molecules comprises a branched moiety and a second moiety. The branched moiety can form part of either the core or the surface of the spherical micellar structure, depending on the polarity of the environment. The roughly spherical micellar structures form in a thermosetting polymer matrix. They are employed in a templating process whereby the amphiphilic molecules are dispersed in the polymer matrix, the matrix is cured, and the porogens are then removed, leaving nanoscale pores.

Claims

1. A substantially spherical micellar structure formed by one or more spatially unsymmetric organic amphiphilic molecules, each comprising:

(a) a branched moiety that forms part of either the core or the surface of the substantially spherical micellar structure, and

(b) a second moiety that forms part of either

(b1) the surface of the substantially spherical micellar structure when the branched moiety forms part of the core, or

(b2) the core of the substantially spherical micellar structure when the branched moiety forms part of the surface,

wherein the second moiety is a linear polymeric moiety having a degree of polymerization of between 50 and 500, and

wherein the substantially spherical micellar structure exists in a thermosetting polymeric matrix.

2. A micellar structure according to claim 1, wherein either the branched moiety is lyophilic and the second moiety is lyophobic, or the branched moiety is lyophobic and the second moiety is lyophilic.

3. A micellar structure according to claim 1, wherein the branched moiety is dendritic.

4. A micellar structure according to claim 1, wherein the branched moiety is hyperbranched.

5. A micellar structure according to claim 1, wherein one of either the branched moiety or the second moiety is polar, and the other of them is non-polar.

6. A micellar structure according to claim 1, wherein the branched moiety is non-polar.

7. A micellar structure according to claim 1, wherein the micellar structure has a diameter in the range of about 1 nm to about 10 nm.

8. A micellar structure according to claim 1, wherein end groups of the branched moiety are selected to facilitate self-assembly of the amphiphilic molecules.

9. A micellar structure according to claim 1, wherein a core of the micellar structure is insoluble in the thermosetting polymeric matrix prior to curing, and an outer shell of the structure is soluble in the thermosetting polymeric matrix prior to curing.

10. A micellar structure according to claim 1, wherein the micellar structure exists in the thermosetting polymeric matrix after curing.