Coated article with low-E coating including IR reflecting layer(s) and corresponding method

• US 8,440,037 B2
• Filed: 10/24/2006
• Issued: 05/14/2013
• Est. Priority Date: 07/10/2000
• Status: Active Grant

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Centre Luxembourgeois de Recherches pour le Verre et la Ceramique SA, Guardian Industries Corporation (KOCH Industries Incorporated)
• Inventors: Dietrich, Anton, Lingle, Philip J., Muller, Jens-Peter, Lemmer, Jean-Marc
• Primary Examiner(s): SCHATZ, CHRISTOPHER T
• Application Number:
  US11/585,227
• Publication Number:
  US 20070036990A1
• Time in Patent Office: 2,394 Days
• Field of Search: 427/452, 427/567, 427/574, 427/578, 427/579, 427/255.11, 427/255.18, 427/255.27, 156 99-109
• US Class Current: 156/99
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 17/10229 Metallic layers sandwiched by dielectric layers
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3626 one layer at least containing a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: C03C 17/3694 one layer having a composition gradient through its thickness
• CPC Class Codes: C03C 2217/78 Coatings specially designed to be durable, e.g. scratch-resistant
• CPC Class Codes: C03C 2218/154 by sputtering
• CPC Class Codes: C23C 14/0015 characterized by the colour of the layer
• CPC Class Codes: C23C 14/0084 Producing gradient compositions
• CPC Class Codes: C23C 14/0652 Silicon nitride
• CPC Class Codes: Y10T 428/12576 Boride, carbide or nitride component
• CPC Class Codes: Y10T 428/12611 Oxide-containing component
• CPC Class Codes: Y10T 428/12632 Four or more distinct components with alternate recurrence of each type component
• CPC Class Codes: Y10T 428/12854 Next to Co-, Fe-, or Ni-base component
• CPC Class Codes: Y10T 428/31678 : Of metal

Abstract

A coated article is provided that may be heat treated in certain example embodiments. A coating of the coated article includes a zinc oxide inclusive layer located over and contacting a contact layer that is in contact with an infrared (IR) reflecting layer of a material such as silver. It has been found that the use of such a zinc oxide inclusive layer results in improved thermal stability upon heat treatment, increased visible transmission, and/or lower sheet resistance (R_s).

Claims

1. A method of making a heat treated coated article comprising a coating supported by a glass substrate, the method comprising:

sputter-depositing a first dielectric layer comprising silicon nitride over at least the glass substrate;

sputter-depositing a first layer comprising zinc oxide over at least the layer comprising silicon nitride, the first layer comprising zinc oxide thickness from 40-150 Å

;

sputter-depositing a first infrared (IR) reflecting layer comprising silver over and contacting the first layer comprising zinc oxide;

sputter-depositing a second dielectric layer comprising silicon nitride on the glass substrate over at least the first IR reflecting layer;

sputter-depositing a second layer comprising zinc oxide over at least the first IR reflecting layer and the first and second dielectric layers comprising silicon nitride, the second layer comprising zinc oxide having a thickness of from 40-150 Å

;

sputter-depositing a second IR reflecting layer comprising silver over and contacting the second layer comprising zinc oxide;

sputter-depositing a layer comprising an oxide of NiCr over and contacting the second IR reflecting layer by sputtering a target comprising NiCr in an atmosphere comprising at least argon gas and a significant amount of oxygen gas, so that the layer comprising the oxide of NiCr is an oxide as it is sputter-deposited on the substrate;

sputter-depositing a third layer comprising zinc oxide over and contacting the layer comprising the oxide of NiCr;

depositing another dielectric layer located over at least the third layer comprising zinc oxide;

wherein, following said depositing steps, the layer comprising the oxide of NiCr is fully oxidized; and

heat treating the coated article after the aforesaid layers have been deposited on the glass substrate, so that when measured monolithically following heat treatment the coated article has a visible transmission of at least 80%, a sheet resistance (R_s) of less than or equal to 2.5 ohms/square, and a normal emissivity (E) of less than or equal to about 0.04.

2. The method of claim 1, wherein at least one of the first and second layers comprising zinc oxide further comprises aluminum.

3. The method of claim 1, wherein each of the first, second and third layers comprising zinc oxide further comprise aluminum.

4. The method of claim 1, further comprising depositing a layer comprising tin oxide so as to be located between the first IR reflecting layer and the second layer comprising zinc oxide.

5. The method of claim 1, further comprising depositing a layer comprising tin oxide so as to be located between the third layer comprising zinc oxide and said another dielectric layer, wherein said another dielectric layer comprises silicon nitride, and wherein the layer comprising tin oxide contacts the third layer comprising zinc oxide and the another dielectric layer comprising silicon nitride.

6. The method of claim 1, wherein the first dielectric layer comprises silicon nitride which is Si-rich so as to be represented by Si_xN_y, where x/y is from 0.8 to 1.4.

7. The method of claim 1, wherein when measured monolithically following heat treatment the coated article has a visible transmission of at least 81% and a sheet resistance (R_s) of less than or equal to 2.1 ohms/square.

8. The method of claim 1, further comprising laminating the glass substrate with the layers thereon to another substrate to form a laminate, the laminate having a visible transmission of at least 76% and a sheet resistance (R_s) of less than or equal to 3.0 ohms/square.