Electrophotographic photosensitive member and electrophotographic apparatus

• US 8,440,377 B2
• Filed: 11/18/2010
• Issued: 05/14/2013
• Est. Priority Date: 11/26/2009
• Status: Active Grant

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Ozawa, Tomohito, Yamada, Motoya, Akiyama, Kazuyoshi, Tazawa, Daisuke
• Primary Examiner(s): Huff, Mark F
• Assistant Examiner(s): ALAM, RASHID A
• Application Number:
  US12/949,053
• Publication Number:
  US 20110123915A1
• Time in Patent Office: 908 Days
• Field of Search: 430 585- 596
• US Class Current: 430/59.1
• CPC Class Codes: G03G 5/0433 all layers being inorganic
• CPC Class Codes: G03G 5/08228 at least one with varying composition

Abstract

An electrophotographic photosensitive member includes a substrate, a photoconductive layer, an intermediate layer, and a surface layer sequentially formed. The intermediate layer contains silicon, carbon and hydrogen, and a distribution of a hydrogen ratio, which is a ratio of the number of hydrogen atoms to the number of silicon, carbon and hydrogen atoms, in the intermediate layer has a maximum region. A largest hydrogen atomic ratio in the intermediate layer is larger than a hydrogen atomic ratio in the surface layer, and the hydrogen atomic ratio in the surface layer is 0.30 to 0.45. A distribution of a carbon atomic ratio, which is a ratio of the number of carbon atoms to the number of silicon and carbon atoms, in the intermediate layer has a maximum and a minimum region. A carbon atomic ratio in the maximum region is 0.53 to 0.63, a carbon atomic ratio in the minimum region is 0.47 or more, and the maximum hydrogen region in the intermediate layer is partially superimposed on the minimum carbon region.

Claims

1. An electrophotographic photosensitive member comprising a substrate, a photoconductive layer on the substrate, an intermediate layer on the photoconductive layer, and a surface layer formed from hydrogenated amorphous silicon carbide on the intermediate layer,

wherein the intermediate layer contains silicon atoms, carbon atoms, and hydrogen atoms,

a distribution of a hydrogen atomic ratio, which is defined by a ratio (H/(Si+C+H)) of the number of hydrogen atoms (H) to a sum of the number of silicon atoms (Si), the number of carbon atoms (C), and the number of hydrogen atoms (H), in the intermediate layer has a maximum region in a layer thickness direction of the intermediate layer,

a largest value of the hydrogen atomic ratio in the maximum region of the distribution of the hydrogen atomic ratio in the intermediate layer is larger than a hydrogen atomic ratio in the surface layer,

the hydrogen atomic ratio in the surface layer is 0.30 to 0.45 inclusive,

a distribution of a carbon atomic ratio, which is defined by a ratio (C/(Si+C)) of the number of carbon atoms (C) to a sum of the number of silicon atoms (Si) and the number of carbon atoms (C), in the intermediate layer has a maximum region and a minimum region in the layer thickness direction of the intermediate layer,

a carbon atomic ratio in the maximum region of the distribution of the carbon atomic ratio in the intermediate layer is 0.53 to 0.63 inclusive,

a carbon atomic ratio in the minimum region of the distribution of the carbon atomic ratio in the intermediate layer is 0.47 or more, and is smaller than the carbon atomic ratio in the maximum region of the distribution of the carbon atomic ratio in the intermediate layer, and

at least a part of the maximum region of the hydrogen atomic ratio in the intermediate layer is superimposed on the minimum region of the carbon atomic ratio in the intermediate layer.

2. The electrophotographic photosensitive member according to claim 1, wherein when a largest value of the carbon atomic ratio in the maximum region of the distribution of the carbon atomic ratio in the intermediate layer is set as C1, a hydrogen atomic ratio at a position where the carbon atomic ratio in the maximum region of the distribution of the carbon atomic ratio in the intermediate layer becomes the largest value is set as H1, a smallest value of the carbon atomic ratio in the minimum region of the distribution of the carbon atomic ratio in the intermediate layer is set as C2, and the largest value of the hydrogen atomic ratio in the maximum region of the distribution of the hydrogen atomic ratio is set as H2, the following expressions 1 and 2 are satisfied:

−

0.06≦

C2−

C1≦

−

0.01 

 

(Expression

     1)

0.05≦

H2−

H1≦

0.15 

 

(Expression

     2).

3. The electrophotographic photosensitive member according to claim 1, wherein the largest value of the hydrogen atomic ratio in the maximum region of the distribution of the hydrogen atomic ratio in the intermediate layer is 0.50 or less.

4. The electrophotographic photosensitive member according to claim 1, wherein a distance d2 from the maximum region of the distribution of the carbon atomic ratio in the intermediate layer to the surface layer is 300 angstroms to 5000 angstroms inclusive.

5. The electrophotographic photosensitive member according to claim 1, wherein in the intermediate layer, a ratio (d2/s1) of the distance d2 from the maximum region of the distribution of the carbon atomic ratio in the intermediate layer to the surface layer, to a layer thickness d1 of the surface layer is 0.05 or more.

6. The electrophotographic photosensitive member according to claim 1, wherein the carbon atomic ratio in the surface layer is 0.61 to 0.75 inclusive, and a sum of an atomic density of silicon atoms and an atomic density of carbon atoms is 6.60×

1022 atom/cm3 or more.

7. The electrophotographic photosensitive member according to claim 1, wherein the photoconductive layer comprises hydrogenated amorphous silicon.

8. An electrophotographic apparatus comprising the electrophotographic photosensitive member according to claim 1.