Method for forming an organic light emitting diode device

• US 8,440,479 B2
• Filed: 03/30/2010
• Issued: 05/14/2013
• Est. Priority Date: 05/28/2009
• Status: Expired due to Fees

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Nguyen, Kelvin, Zhang, Lu, Vaddi, Butchi R.
• Primary Examiner(s): Smith, Zandra
• Assistant Examiner(s): Perkins, Pamela E
• Application Number:
  US12/749,637
• Publication Number:
  US 20100304513A1
• Time in Patent Office: 1,141 Days
• Field of Search: None
• US Class Current: 438/29
• CPC Class Codes: H05B 33/04 Sealing arrangements , e.g. against humidity
• CPC Class Codes: H05B 33/10 Apparatus or processes specially adapted to the manufacture of electroluminescent light sources
• CPC Class Codes: H10K 30/88 Passivation; Containers; Encapsulations
• CPC Class Codes: H10K 50/8426 Peripheral sealing arrangements, e.g. adhesives, sealants
• CPC Class Codes: H10K 50/87 Arrangements for heating or cooling
• CPC Class Codes: H10K 59/38 comprising colour filters or colour changing media [CCM]
• CPC Class Codes: H10K 71/00 Manufacture or treatment specially adapted for the organic devices covered by this subclass
• CPC Class Codes: H10K 71/421 using coherent electromagnetic radiation, e.g. laser annealing
• CPC Class Codes: Y02E 10/549 Organic PV cells

Abstract

A method for sealing an organic light emitting diode (OLED) device is disclosed wherein the OLED device comprises a color filter. A color filter is deposited on a first glass plate or substrate and a glass-based frit is then deposited in a loop around the color filter, The deposited fit loop is then heated by electromagnetic energy to evaporate organic constituents and to sinter the fit in a pre-sintering step. An OLED device may then be assembled by positioning a second glass plate comprising an organic light emitting material deposited thereon in overlying registration with the first glass plate, with the color filer and the organic light emitting material positioned between the plates. The fit is then heated with a laser to form a hermetic seal between the first and second glass plates.

Claims

1. A method of forming an organic light emitting diode device (10) comprising:

depositing a color filter (24) on a first glass plate (12), the color filter comprising dyes or pigments that produce a primary color in the color filter;

depositing a glass-based frit (26) on the first glass plate as a loop circumscribing the color filter; and

irradiating the glass-based frit with electromagnetic radiation to densify the glass-based frit on the first glass plate.

2. The method according to claim 1, further comprising heating the glass-based frit to remove organic binders in the glass-based frit without densifying the frit glass.

3. The method according to claim 2, wherein the heating comprises heating the first glass plate on a heated support (32).

4. The method according to claim 1, further comprising heating the first glass plate on a heated support during the irradiating.

5. The method according to claim 1, wherein the irradiation comprises irradiating the glass-based frit with microwaves.

6. The method according to claim 1, wherein the irradiation comprises irradiating the glass-based frit with IR light.

7. The method according to claim 1, further comprising:

depositing an organic light emitting material (22) on a second glass plate (14);

aligning the first glass plate (12) with the second glass plate (14) in an overlapping relationship; and

heating the glass-based frit (26) with a laser (46) to soften the glass-based frit and form a hermetic seal between the first and second glass plates, wherein the color filter (24) and the organic light emitting material (22) are enclosed between the first and second glass substrates and the glass-based frit.

8. A method of forming an organic light emitting diode device (10) comprising:

depositing a color filter (24) on a first glass plate (12);

depositing a glass-based frit (26) on the first glass plate as a loop circumscribing the color filter;

depositing an organic light emitting material (22) on a second glass plate (14);

impinging electromagnetic radiation on the glass-based frit to densify the glass-based frit on the first glass plate;

aligning the first glass plate with the second glass plate in an overlapping relationship; and

heating the glass-based frit with a laser (46) to soften the glass based frit and form a hermetic seal between the first and second glass plates, wherein the color filter and the organic light emitting material are enclosed between the first and second glass substrates and the hermetic seal.

9. The method according to claim 8, wherein the electromagnetic radiation is light energy comprising a wavelength between about 500 nm and 1200 nm.

10. The method according to claim 9, wherein the light energy comprises a laser beam.

11. The method according to claim 10, wherein a width of the laser beam is greater than a width of the glass-based frit.

12. The method according to claim 9, wherein the light energy is broadband IR light emitted by an IR lamp.

13. The method according to claim 8, wherein the electromagnetic energy is microwave energy.

14. The method according to claim 8, wherein the color filter (24) comprises dyes or pigments that produce one or more primary colors.

15. The method according to claim 8, wherein the organic light emitting material (22) is shielded from the impinging electromagnetic energy by a mask 36.

16. The method according to claim 8, wherein the first or second glass plate is supported by a heated support (32) and heated to a temperature greater than an ambient temperature, but less than about 100°

C. while the hermetic seal is formed.

17. The method according to claim 8, wherein a temperature of the glass-based frit (26) during the impinging with electromagnetic energy is between about 325°

C. and about 420°

C.

18. A method of forming an organic light emitting diode device (10) comprising:

depositing a color filter (24) on a first glass plate (12), the color filter comprising dyes or pigments;

depositing a glass-based frit paste (26) on the first glass plate as a loop circumscribing the color filter;

positioning a resistive heating element (42) in contact with the glass-based frit paste;

flowing an electric current through the resistive heating element to heat the frit paste to a first temperature and drive off organic binders in the frit without densifying the glass-based frit paste; and

varying a magnitude of the electric current through the resistive heating element to heat the glass-based frit paste to a second temperature greater than the first temperature, thereby densifying the glass-based frit paste.

19. The method according to claim 18, further comprising:

forming an organic light emitting material on a second glass plate;

aligning the first glass plate with the second glass plate in an overlapping relationship; and

heating the densified glass-based frit paste with a laser to soften the glass-based frit and form a hermetic seal between the first and second glass plates, wherein the color filter and the organic light emitting material are enclosed between the first and second glass substrates and the hermetic seal.

20. The method according to claim 18, further comprising heating the first glass plate on a heated support while a current is flowing through the resistive heating element.