Vehicle window glass and manufacturing method therefor

• US 8,445,096 B2
• Filed: 01/11/2007
• Issued: 05/21/2013
• Est. Priority Date: 01/17/2006
• Status: Active Grant

• Current Assignee: Nippon Sheet Glass Company Limited (Nippon Telegraph and Telephone Corporation)
• Original Assignee: Nippon Sheet Glass Company Limited (Nippon Telegraph and Telephone Corporation)
• Inventors: Muromachi, Takashi, Ogawa, Hisashi, Yoshida, Mamoru, Iwai, Nobuki
• Primary Examiner(s): Simone, Catherine A
• Application Number:
  US12/087,758
• Publication Number:
  US 20090080066A1
• Time in Patent Office: 2,322 Days
• Field of Search: 428/156, 428/172, 428/192, 428/141, 428/143, 428/144, 428/145, 428/148, 428/149, 428/426, 428/428, 428/432, 428/328, 428/329, 428/330, 428/689, 428/702, 428/697, 428/701
• US Class Current: 428/156
• CPC Class Codes: B60J 1/00 Windows; Windscreens; Accessories therefor B60J10/00 takes precedence; air curtains instead of windows B60J9/04 ; sealing strips for windshields B60J10/70; sealing sash guides for sliding window panes B60J10/74; glass partitions inside vehicles to protect occupants against personal attack B60R21/12
• CPC Class Codes: C03C 17/002 for flat glass, e.g. float glass
• CPC Class Codes: C03C 17/007 containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
• CPC Class Codes: C03C 17/009 Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 2217/216 ZnO
• CPC Class Codes: C03C 2217/23 Mixtures
• CPC Class Codes: C03C 2217/231 In2O3/SnO2
• CPC Class Codes: C03C 2217/24 Doped oxides
• CPC Class Codes: C03C 2217/283 Borides, phosphides
• CPC Class Codes: C03C 2217/29 Mixtures
• CPC Class Codes: C03C 2217/475 Inorganic materials
• CPC Class Codes: C03C 2217/476 Tin oxide or doped tin oxide
• CPC Class Codes: C03C 2217/948 Layers comprising indium tin oxide [ITO]
• CPC Class Codes: C03C 2218/114 by brushing, pouring or doctorblading
• CPC Class Codes: Y10T 428/24479 including variation in thickness
• CPC Class Codes: Y10T 428/24612 Composite web or sheet
• CPC Class Codes: Y10T 428/24777 Edge feature

Abstract

A glass substrate is held by a glass substrate holding member in the vertical direction, and a nozzle is used to eject an infrared cutoff liquid onto the upper portion of the glass substrate. The infrared cutoff liquid flows vertically downward so as to be applied onto the glass substrate. The film thickness of the lower portion of an infrared cutoff film is greater than that of the upper portion. The glass substrate is dried for approximately five minutes at room temperature. Then, the glass substrate onto which the infrared cutoff liquid has been applied is placed in an oven preheated to 200° C., heated for ten minutes, and then cooled. The glass substrate having the infrared cutoff film thereon is installed in a railroad vehicle such that the lower portion of the glass substrate is located on the lower side with respect to the railroad vehicle.

Claims

1. A vehicle window glass comprising:

a single sheet of glass plate; and

an infrared cutoff film formed on the single sheet of glass plate;

wherein a film thickness of the infrared cutoff film on a lower portion of the vehicle window glass is greater than the film thickness on an upper portion of the vehicle window glass when the vehicle window glass in mounted in a vehicle, and

wherein a variation from a minimum value in the film thickness on the upper portion to a maximum value on the lower portion is at least 1000 nm per 600 mm in a vertical direction of the vehicle window glass when mounted in the vehicle.

2. The vehicle window glass according to claim 1, wherein said infrared cutoff film contains a silica component and an infrared cutoff component.

3. The vehicle window glass according to claim 2, wherein said infrared cutoff component comprises at least one selected from the group consisting of tin-doped indium oxide (ITO) fine particles, antimony-doped tin oxide (ATO) fine particles, aluminum-doped zinc oxide (AZO) fine particles, indium-doped zinc oxide (IZO) fine particles, tin-doped zinc oxide fine particles, silicon-doped zinc oxide fine particles, lanthanum hexaboride fine particles, and cerium hexaboride fine particles.

4. The vehicle window glass according to claim 2, wherein said infrared cutoff component is 20 to 45 mass % of a total mass of said infrared cutoff film.

5. The vehicle window glass according to claim 1, wherein the film thickness of said infrared cutoff film continuously varies from the upper portion to the lower portion.

6. The vehicle window glass according to claim 1, wherein a greatest film thickness of the infrared cutoff film on the lower portion is not smaller than twice a smallest film thickness of the infrared cutoff film of the upper portion.

7. The vehicle window glass according to claim 1, wherein a thinnest part of the infrared cutoff film on the upper portion has an optical transmittance of 30% or lower within the wavelength range from 1000 to 1600 nm and an optical transmittance of 20% or lower within the wavelength range from 1600 to 2500 nm, and a thickest part of the infrared cutoff film on the lower side portion has an optical transmittance of 20% or lower within the wavelength range from 1000 to 1600 nm and an optical transmittance of 10% or lower within the wavelength range from 1600 to 2500 nm.

8. The vehicle window glass according to claim 1, wherein a 1550 nm wavelength optical transmittance of a thickest part of the infrared cutoff film on the lower portion where the film thickness is greatest is not higher than 50% of the 1550 nm wavelength optical transmittance of a thinnest part of the infrared cutoff film on the upper side portion where the film thickness is smallest.

9. A production method for the vehicle window glass according to claim 1, the method comprising:

forming the infrared cutoff film by applying an infrared cutoff liquid onto a surface of the sheet of glass plate by using flow coating in such a way that the film thickness on the lower portion of the vehicle window glass is greater than the film thickness on the upper portion of the vehicle window glass when the vehicle window glass is mounted in the vehicle.