Liquid degassing membrane contactors, components, systems and related methods

• US 8,449,659 B2
• Filed: 09/28/2011
• Issued: 05/28/2013
• Est. Priority Date: 09/28/2010
• Status: Active Grant

• Current Assignee: Solventum Intellectual Properties Company (Solventum Corp.)
• Original Assignee: Celgard LLC (Asahi Kasei Corporation)
• Inventors: Taylor, Gareth P., Price, Timothy D., Vido, Tony R., Bouldin, Elmer Wayne Jr.
• Primary Examiner(s): Greene, Jason M
• Application Number:
  US13/247,213
• Publication Number:
  US 20120247337A1
• Time in Patent Office: 608 Days
• Field of Search: 96/4, 96/6, 96/8, 96/10, 95/45, 95/46, 210/321.8, 210/321.88, 210/321.89
• US Class Current: 96/6
• CPC Class Codes: B01D 19/0031 by filtration
• CPC Class Codes: B01D 2311/13 Use of sweep gas
• CPC Class Codes: B01D 2313/10 Specific supply elements
• CPC Class Codes: B01D 2313/21 Specific headers, end caps
• CPC Class Codes: B01D 2313/56 Specific mechanisms for loading the membrane in a module
• CPC Class Codes: B01D 2317/02 Elements in series
• CPC Class Codes: B01D 2317/04 Elements in parallel
• CPC Class Codes: B01D 63/02 Hollow fibre modules
• CPC Class Codes: Y10T 29/4987 Elastic joining of parts

Abstract

The present invention is directed to contactors, modules, components, systems, and/or methods of manufacture, and/or methods of use including degassing liquids. The contactor or module is integrally potted, has planar, disc shaped end caps, and a cylindrical housing or shell receiving and supporting a membrane structure. Each of the planar disc shaped end caps has a central opening therein adapted to receive a liquid end port or nozzle and is held in place in the housing or shell by at least one retaining element. The integrally potted membrane structure is preferably potted in place in the housing or shell by an inverted potting process involving the use of a removable plunger or plug to recess the potting.

Claims

1. A liquid degassing membrane contactor or module, comprising:

a cylindrical housing or shell made of a length of modified pipe,

at least one integrally potted hollow fiber membrane structure in said cylindrical housing with the ends of said membrane structure recessed in said housing a recess of at least 1″

from each end, and

respective disc shaped end caps adapted to be received in each open end of said housing.

2. The liquid degassing membrane contactor of claim 1, wherein said membrane structure is recessed in said housing a recess of at least 2″

from each end.

3. The liquid degassing membrane contactor of claim 1, wherein said disc shaped end caps each having at least one of liquid and gas ports therein and adapted to be held in place in said cylindrical housing by at least one retaining element being a retaining or locking ring received in a groove in the interior of said cylindrical housing.

4. The liquid degassing membrane contactor of claim 1, wherein said planar disc shaped end caps each having a central opening therein adapted to receive a liquid end port or nozzle, and another opening therein adapted to receive a gas end port or pipe.

5. The liquid degassing membrane contactor of claim 1, wherein said integrally potted membrane structure including a perforated core, a plurality of hollow fiber membranes, a tube sheet or potting affixing each end of the hollow fibers and adhering to the interior of said housing.

6. The liquid degassing membrane contactor of claim 1, wherein said integrally potted membrane structure being potted in place in said housing by an inverted potting process involving the use of a removable plunger or plug and trimming the ends of the potting and opening the ends of the hollow fibers using a cutting means to produce recessed tube sheets.

7. The liquid degassing membrane contactor of claim 1, wherein said length of pipe of said cylindrical housing is formed of a modified section of pipe including in each end a larger diameter section for receiving an end cap, a groove for receiving a retaining ring, and a flared entrance for facilitating the insertion of the end cap and retaining ring.

8. The liquid degassing membrane contactor of claim 7, wherein said length of pipe is selected from standard PVC, ABS, polypropylene, steel, stainless steel, or other pipe material that will bond with epoxy to facilitate integral potting.

9. A spiral-type hollow fiber membrane fabric-containing module or contactor, comprising:

a module housing made of a modified section of pipe;

a pair of end caps adapted to fit in the ends of said module housing;

liquid end ports in each of said end caps;

at least one gas port in at least one of said end caps or in the side of said module housing near one end thereof;

at least one membrane structure adapted to fit in said module housing, each membrane structure comprising;

a. a plurality of hollow fiber membranes each having a lumen, said membranes being formed into a fabric-like array in which the hollow fibers substantially are mutually-parallel and constitute the fabric weft, and are held in spaced-apart relationship by filaments constituting the fabric warp;

b. the array being wound upon an axis which is substantially parallel to the hollow fibers into a spirally-wound membrane bundle having two bundle ends and a cylindrical exterior surface;

c. each of the two bundle ends being potted in resinous potting material serving to seal the bundle end into an adjacent monolithic tube sheet, a portion of the bundle between the two tube sheets being free from potting material to form a shell-side region, and the lumen ends of the hollow fibers constituting a first one of the bundle ends being exposed and communicating with the exterior of the bundle;

d. the module shell, casing or housing having first and second housing ends and a cylindrical housing interior and being suitably shaped to contain the membrane bundle, the tube sheet (potting) recessed relative to the first housing end sealing the first bundle end to the cylindrical housing interior, said module housing which contains the bundle defining two regions mutually communicating through the membrane including (i) a shell-side space exterior to the portion of the bundle between the tube sheets and within the housing, and (ii) a lumen-side space including the hollow fiber lumens and the first bundle end;

wherein an interior face of a first of said end caps and an interior of said module housing adjacent the first tube sheet, together with the cylindrical housing interior and the first bundle end, seal a first module housing end and define a first chamber communicating with the membrane lumens;

wherein an interior face of a second of said end caps and an interior of said module housing adjacent a second tube sheet recessed from the second housing end, together with the cylindrical housing interior and a second bundle end, seal a second module housing end and define a second chamber communicating with the membrane lumens;

said liquid ends ports being operatively connected to the shell-side space of the membrane structure, and arranged to permit fluid injection and withdrawal there through; and

the at least one gas port communicating with at least one of the first and second chambers, and arranged to permit gas injection and withdrawal there through.

10. The spiral-type hollow fiber membrane fabric-containing module or contactor of claim 9, further comprising:

at least two gas ports with one gas port in each of at least each of said end caps or in each side of said module housing near each end thereof.

11. The spiral-type hollow fiber membrane fabric-containing module or contactor of claim 9, further comprising:

a hollow mandrel in each of said membrane structures having a longitudinal axis and a cylindrical exterior surface, an axial bore, and perforations along the surface which communicate with the bore.

12. The high pressure spiral-type hollow fiber membrane fabric-containing module or contactor of claim 9, further comprising:

both of the lumen ends of the hollow fibers are exposed and communicate with the exterior of the bundle.

13. The spiral-type hollow fiber membrane fabric-containing module or contactor of claim 9, further comprising:

wherein said module housing is a section or length of standard pipe modified to receive and retain end caps.

14. The spiral-type hollow fiber membrane fabric-containing module or contactor of claim 13, further comprising:

wherein the module housing and end caps will contain and restrain the membrane structure should it fail.

15. A system for degassing liquids, comprising:

at least one liquid degassing module of claim 9.

16. The system for degassing liquids of claim 15, comprising:

at least two liquid degassing modules of claim 9.

17. An integrally potted hollow fiber membrane contactor comprising:

planar, disc shaped end caps,

a high pressure cylindrical housing receiving and supporting a membrane element including a perforated core, a plurality of hollow fiber membranes, a tube sheet affixing each end of the hollow fibers and adhering to the interior of the housing,

each of the planar disc shaped end caps having a central opening therein adapted to receive a liquid end port, another opening therein adapted to receive a gas end port, and is adapted to be held in place in the cylindrical housing by at least one retaining element being a retaining ring received in a groove in the interior of the cylindrical housing,

the integrally potted membrane structure is potted in place in the housing by an inverted potting process involving the use of a removable plunger to provide recessed potting and by trimming the end of the potting and opening the ends of the hollow fibers using an internal lathe means, and

the housing including a larger diameter section for receiving the end cap, the groove for receiving the retaining ring, and a flared entrance for facilitating the insertion of the end cap and retaining ring.