Oxidation process

• US 8,449,777 B2
• Filed: 07/17/2008
• Issued: 05/28/2013
• Est. Priority Date: 07/26/2007
• Status: Active Grant

• Current Assignee: Great Lakes Clean Water Limited Partnership
• Original Assignee: Great Lakes Clean Water Limited Partnership
• Inventors: Bain, Thomas W., Swales, Graham Edward
• Primary Examiner(s): STELLING, LUCAS A
• Application Number:
  US12/219,186
• Publication Number:
  US 20090026147A1
• Time in Patent Office: 1,776 Days
• Field of Search: 210/750, 210/760, 210/765, 210/721, 210/746, 210/192, 210/204, 210/137, 210/96.1, 210/167.3, 210/198.1, 210/808, 210/764, 210/766, 210/20, 210/5, 261/DIG.42, 422/28, 422/33
• US Class Current: 210/746
• CPC Class Codes: C02F 1/78 with ozone C02F1/4672 takes precedence
• CPC Class Codes: C02F 2209/44 Time
• CPC Class Codes: C02F 2301/066 Overpressure, high pressure
• CPC Class Codes: C02F 2303/04 Disinfection
• CPC Class Codes: G01N 33/18 Water
• CPC Class Codes: Y02W 10/37 using solar energy

Abstract

A batch process for the treatment of an aqueous solution so that the treated product is more desirable for disposal includes obtaining an influent batch of aqueous solution for treatment, treating the batch of solution by an advanced oxidation process. The advanced oxidation process including causing ozone to be mixed with the solution, maintaining the mixture of solution and ozone at a pressure above atmospheric for a time of at least two seconds. In a preferred embodiment of the process, the process includes continuously recirculating the fluid to be treated, through a recirculation conduit, the recirculation conduit including an ozone injector and the ozone injector is adapted to inject ozone into the aqueous solution as the aqueous solution circulates through an ozone injector. Influent to be treated may be selected from the group including sewage, septage, leachate, ballast or other aqueous solutions where it is desirable to treat the fluid prior to disposal, further treatment, or reuse. The process is carried out to improve a level of disinfection and/or denutrification of the effluent.

Claims

1. A batch process for the treatment of an aqueous sewage solution, said batch process comprising:

obtaining an influent batch of aqueous sewage solution for treatment, said batch of aqueous sewage solution having a batch size volume, and said batch of aqueous sewage solution having a phosphorus content prior to disposal,

treating said batch of aqueous sewage solution by an advanced oxidation and denutrification process, said advanced oxidation and denutrification process including causing ozone to be mixed with said aqueous sewage solution, said ozone acting on said aqueous sewage solution to decrease the BOD thereof;

providing a treatment tank for holding said batch of aqueous sewage solution, a recirculation conduit fluidly connected to said treatment tank at an inlet and an outlet, said recirculation conduit having an ozone injector, and a pump mounted to said recirculation conduit, said pump being operable to urge flow of said batch of aqueous sewage solution through said recirculation conduit, said batch of aqueous sewage solution thereby being urged past said ozone injector,

said oxidation and denutrification process including continuously recirculating the batch of aqueous sewage solution through the recirculation conduit and continuously injecting ozone into the batch of aqueous sewage solution as the batch of aqueous sewage solution recirculates through the ozone injector,

the advanced oxidation and denutrification process including providing a pressure portion of said recirculation conduit downstream of the ozone injector, maintaining said pressure portion of said recirculation conduit at a higher pressure than said treatment tank, said pressure portion being maintained at a selected gauge pressure of at least one and a half atmospheres, and maintaining a selected residence time of said aqueous sewage solution passing through said pressure portion of at least 2 seconds in said pressure portion, said ozone engaging said aqueous sewage solution during said residence time;

continuously returning said aqueous sewage solution from said pressure portion to said treatment tank, and

continuously recirculating the batch of aqueous sewage solution, for a recirculation time of at least 5 minutes before disposal, said recirculating including operating said pump to pump a flow volume of at least three and one third times the batch size volume during said batch process, whereby said batch of aqueous sewage solution urged through said recirculation conduit by said pump is repeatedly pressurized and depressurized during treatment thereof;

filtering said batch of aqueous sewage solution after said recirculation time to reduce the phosphorus content of said treated batch of aqueous sewage solution; and

disposing of said treated batch of aqueous sewage solution, after said filtering.

2. The process of claim 1 wherein said aqueous sewage solution is maintained at a selected pressure of at least 1.5 atmospheres for a selected residence time of at least 6 seconds in said pressure portion.

3. The process of claim 2 wherein said aqueous sewage solution is maintained at a selected pressure of at least 1.5 atmospheres for a selected residence time of at least 12 seconds, in said pressure portion.

4. The process of claim 2 wherein the influent batch of aqueous sewage solution comprises a nitrogen content prior to treatment, and the process further comprises off gassing nitrogen gasses as said batch of aqueous sewage solution recirculates, said off gassing of nitrogen occurring from outside of said pressure portion of said recirculation conduit.

5. The process of claim 1 wherein said aqueous sewage solution is maintained at a selected pressure of at least 2.0 atmospheres for the selected residence time of at least 2 seconds, in said pressure portion.

6. The process of claim 1 wherein the process is carried out in a system having an oxygen concentrator connected to an ozone generator through an oxygen conduit, the oxygen conduit having an oxygen flow control valve and said process comprises controlling the flow of oxygen to said ozone generator to maximize the amount of ozone produced while minimizing the amount of oxygen and/or nitrogen downstream of the ozone generator.

7. The process of claim 1 wherein said batch of aqueous sewage solution is continuously recirculated for a total time of at least thirty (30) minutes before disposal.

8. The process of claim 1 the process including degassing of said treated aqueous sewage solution, downstream of said pressure portion of said recirculation conduit, and removing said degassed gasses.

9. The process of claim 1 wherein said recirculation conduit includes a sensor to sense the oxidation/reduction potential of the aqueous sewage solution, the process further comprising continuously circulating the aqueous sewage solution through the recirculation conduit and through the ozone injector, until the ORP of the treated aqueous sewage solution rises to a predetermined level.

10. The process of claim 9 wherein the processing is continued until the ORP is at least +650 mV.

11. The process of claim 9 wherein the processing is continued until the ORP is at least +675 mV.

12. The process of claim 9 wherein the process is continued until the ORP is at least +800 mV.

13. The process of claim 1 wherein the pump is selected and operated so as to pump a flow volume equal to at least 10 times the batch size volume during said process.

14. The process of claim 1 wherein the pump is selected and operated so as to pump a flow volume equal to at least 13 times the batch size volume during said process.

15. The process of claim 1 wherein the pump is selected and operated so as to pump a flow volume equal to at least 20 times the batch size volume during said process.

16. A batch process for the treatment of an aqueous sewage solution, said batch process comprising:

providing a treatment tank for holding a batch of aqueous sewage solution, a recirculation conduit fluidly connected to said treatment tank at an inlet and an outlet, said recirculation conduit having an ozone injector, and a pump mounted to said recirculation conduit, said pump being operable to urge flow of said batch of aqueous sewage solution through said recirculation conduit, said batch of aqueous sewage solution thereby being urged past said ozone injector,

establishing said batch of aqueous sewage solution for treatment in the treatment tank, said batch of aqueous sewage solution having a batch size volume;

treating said batch of aqueous sewage solution by an advanced oxidation and denutrification process, said advanced oxidation and denutrification process including causing ozone to be mixed with said aqueous sewage solution, said ozone acting on said aqueous sewage solution to decrease the BOD thereof;

said oxidation and denutrification process including recirculating the batch of aqueous sewage solution through the recirculation conduit and continuously injecting ozone into the batch of aqueous sewage solution while doing so;

the advanced oxidation and denutrification process including providing a pressure portion of said recirculation conduit downstream of the ozone injector, maintaining said pressure portion of said recirculation conduit at a higher pressure than said treatment tank, said pressure portion being maintained at a selected gauge pressure of at least one and a half atmospheres, and maintaining a selected residence time of said aqueous sewage solution passing through said pressure portion of at least 2 seconds in said pressure portion, said ozone engaging said aqueous sewage solution during said residence time;

continuously returning said aqueous sewage solution from said pressure portion to said treatment tank, and

continuously recirculating the batch of aqueous sewage solution, said recirculating including operating said pump to pump a flow volume of at least three and one third times the batch size volume during said batch process, so that said batch of aqueous sewage solution urged through said recirculation conduit by said pump is repeatedly pressurized and depressurized during treatment of thereof.

17. The process of claim 16 wherein said process includes filtering said aqueous sewage solution after said recirculating, to reduce the phosphorus content of said treated aqueous sewage solution and, disposing of said treated aqueous sewage solution, after said filtering.

18. A process for disinfecting a batch of an aqueous sewage solution to be treated, wherein said process comprises:

employing an apparatus that includes;

a first part and a second part;

the first part including a tank for receiving the aqueous sewage solution to be treated;

the second part including piping in fluid communication with said tank;

said piping including an inlet mounted to draw the aqueous sewage solution to be treated from said tank,

said piping including an outlet mounted to return the aqueous sewage solution to said tank;

a pump mounted to urge the aqueous sewage solution from said tank, through said second part, and then back into said tank; and

a source of ozone operable to introduce ozone into said second part of said apparatus;

establishing the batch of the aqueous sewage solution to be treated in said tank, said batch of aqueous sewage solution having a batch volume;

urging flow of the aqueous sewage solution to be treated through said second part of said apparatus;

establishing a pressure portion of said second part of said apparatus upstream of said outlet, pressure in said pressure portion being an elevated pressure relative to pressure in said tank;

maintaining the pressure in said pressure portion at a pressure of at least 1.5 atm;

said step of urging including raising pressure in said aqueous sewage solution to the pressure of said pressure portion;

dissolving ozone in said aqueous sewage solution;

treating said aqueous sewage solution with said ozone during passage thereof through said pressure portion while under the elevated pressure; and

returning said aqueous sewage solution to said tank;

the step of returning including allowing said aqueous sewage solution to return to the pressure of the tank;

repeatedly recirculating said aqueous sewage solution to be treated from said tank through said second part and back to said tank for at least five minutes, until treatment of said batch has been completed; and

said recirculating including recirculating a volume of flow corresponding to at least three and one third times said batch volume through said pressure portion during said process.

19. The process of claim 18 wherein said process includes establishing a residence time of said aqueous sewage solution being treated in said pressure portion, said residence time in said pressure portion being at least 2 seconds.

20. The process of claim 19 wherein said residence time is at least 6 seconds.

21. The process of claim 19 wherein said residence time is at least 12 seconds.

22. The process of claim 19 wherein said pressure portion is maintained at a pressure of at least 2 atm.

23. The process of claim 18 wherein said recirculating continues for at least 30 minutes.

24. The process of claim 18 wherein said process includes off-gassing nitrogen from said tank during said process.

25. The process of claim 18 wherein said process additionally includes passing treated aqueous sewage solution through a filter after said treatment is completed to remove phosphorous.

26. The process of claim 18 wherein said process includes returning said aqueous sewage solution from said outlet into said tank at a level above the liquid level in said tank.

27. The process of claim 18 wherein said process includes returning aqueous sewage solution from said outlet into said tank at a level below the liquid level in said tank.

28. The process of claim 18 wherein said process includes maintaining said elevated pressure in said pressure portion of said second part by one of (a) mounting an adjustable valve upstream of said outlet;

(b) mounting a restrictor in said second part upstream of said outlet; and

(c) using an extra long conduit of pipe mounted within said tank.

29. The process of claim 18 wherein said process includes mounting a restriction within said second part downstream of said pump and upstream of said outlet, and using said restriction in conjunction with said pump to maintain said elevated pressure.

30. The process of claim 29 wherein including using a valve as said restriction.

31. The process of claim 18 wherein said process includes introducing said ozone into said pressure portion.

32. The process of claim 18 wherein the tank has a conical bottom, and the process includes drawing said aqueous sewage solution to be treated into said inlet from said bottom of said tank whereby aqueous fluid to be treated drawn in at said inlet may tend to contain sediment or other material to be treated.

33. The process of claim 18 where an oxidation-reduction potential sensor is located within said second part.

34. The process of claim 33 wherein said process continues until the oxidation reduction potential of the aqueous sewage solution to be treated exceeds +650 mV.

35. The process of claim 34 wherein said process continues until the oxidation reduction potential of the aqueous sewage solution to be treated exceeds +800 mV.

36. The process of claim 18 wherein the pump is selected and operated to pump a flow volume of at least 10 times the batch volume during treatment thereof.

37. The process of claim 18 wherein the pump is selected and operated to pump a quantity of aqueous sewage solution equal to at least 13 times the batch volume.

38. The process of claim 18 wherein the pump is selected and operated so as to pump a flow volume of at least 20 times the batch volume during treatment thereof.

39. The process of claim 18 wherein the pump can be operated to cycle the volume of the tank through said second part at a rate of 20 cycles in 30 minutes.

40. The process of claim 18 wherein said process continues for between 10 and 40 minutes.