Method of making transparent conductive film

• US 8,455,043 B2
• Filed: 05/13/2010
• Issued: 06/04/2013
• Est. Priority Date: 11/14/2007
• Status: Active Grant

• Current Assignee: Lotte Advanced Materials Co., Ltd. (Lotte Chemical Corporation)
• Original Assignee: Cheil Industries Incorporated (Samsung Group)
• Inventors: Chang, Young Kyu, Bae, Seung Yong, Lee, Young Sil, Lee, Young Hee, Geng, Hong Zhang
• Primary Examiner(s): Talbot, Brian K
• Application Number:
  US12/779,092
• Publication Number:
  US 20100218979A1
• Time in Patent Office: 1,118 Days
• Field of Search: 427/99.2, 427/122, 427/337
• US Class Current: 427/122
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: C08K 2201/003 Additives being defined by their diameter
• CPC Class Codes: C08K 3/041 Carbon nanotubes
• CPC Class Codes: C09D 11/30 Inkjet printing inks
• CPC Class Codes: C09D 11/52 Electrically conductive inks
• CPC Class Codes: C09D 127/12 containing fluorine atoms
• CPC Class Codes: C09D 127/18 Homopolymers or copolymers of tetrafluoroethene
• CPC Class Codes: C09D 5/24 Electrically-conducting paints conductive materials H01B1/00
• CPC Class Codes: C09D 7/61 inorganic
• CPC Class Codes: C09D 7/70 characterised by shape, e.g. fibres, flakes or microspheres
• CPC Class Codes: H01L 29/0665 the shape of the body defining a nanostructure nanotechnology per se B82B
• CPC Class Codes: H01L 29/0673 oriented parallel to a substrate
• CPC Class Codes: H05K 1/09 Use of materials for the conductive, e.g. metallic pattern
• CPC Class Codes: H10K 59/12 Active-matrix OLED [AMOLED] displays

Abstract

Disclosed herein is a method of fabricating a transparent conductive film, including preparing a carbon nanotube composite composition by blending a carbon nanotube in a solvent; coating the carbon nanotube composite composition on a base substrate to form a carbon nanotube composite film, and acid-treating the carbon nanotube composite film by dipping the carbon nanotube composite film in an acid solution, followed by washing the carbon nanotube composite film with distilled water and drying the washed carbon nanotube composite film to form a transparent electrode on the base substrate. The transparent conductive film can have excellent conductivity, transparency and bending properties following acid treatment, so that it can be used in touch screens and transparent electrodes of foldable flat panel displays. Further, the carbon nanotube composite conductive film can have improved conductivity while maintaining transparency after acid treatment.

Claims

1. A method of fabricating a transparent conductive film, comprising:

preparing a carbon nanotube composite composition by blending carbon nanotubes in a solvent, and further adding a polymer binder, wherein the carbon nanotube composite composition comprises 0.05 to 1 part by weight of the polymer binder and 0.05 to 1 part by weight of carbon nanotubes, based on 100 parts by weight of the solvent;

coating the carbon nanotube composite composition on a base substrate to form a carbon nanotube composite film; and

acid-treating the carbon nanotube composite film to form a transparent electrode on the base substrate by dipping the carbon nanotube composite film in an acid solution having a pH in the range of −

1 to 3, followed by washing the carbon nanotube composite film with distilled water and drying the washed carbon nanotube composite film.

2. The method according to claim 1, wherein the solvent comprises a mixture solution of water and isopropyl alcohol in a volume ratio of 20:

80 to 80;

20.

3. The method according to claim 1, wherein the polymer binder comprises a resin having ionic conductivity or ion exchange properties, the resin comprising fluorine atoms and at least one functional group selected from carboxyl, sulfonyl, phosphonyl, and sulfone imides.

4. The method according to claim 1, wherein the polymer binder and the carbon nanotube are mixed in a ratio of 1:

5 to 5;

1.

5. The method according to claim 1, wherein the carbon nanotube composite composition is coated on the base substrate by a spray or ink jet coating process.

6. The method according to claim 1, wherein the base substrate is a polymer film comprising a polyester, polycarbonate, polyether sulfone, or acrylate-based polymer.

7. The method according to claim 1, wherein the base substrate is a glass substrate.

8. The method according to claim 1, wherein the acid solution comprises an acid selected from the group consisting of perchloric acid, nitric acid, hydrochloric acid, sulfuric acid, and mixtures thereof.

9. The method according to claim 1, wherein the carbon nanotube composite film is dipped in the acid solution for 30 minutes to 5 hours.