Ink composition for continuous inkjet printing

• US 8,455,570 B2
• Filed: 09/16/2011
• Issued: 06/04/2013
• Est. Priority Date: 09/16/2011
• Status: Active Grant

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Bermel, Alexandra DiLauro, Nelson, David John, Sowinski, Allan Francis, Jeanmaire, David Louis, Griffin, Todd Russell, Lindstrom, Brian L
• Primary Examiner(s): NGUYEN, VU ANH
• Application Number:
  US13/234,662
• Publication Number:
  US 20130072614A1
• Time in Patent Office: 627 Days
• Field of Search: 524/556, 523/160
• US Class Current: 523/160
• CPC Class Codes: C09D 11/324 containing carbon black
• CPC Class Codes: C09D 11/40 Ink-sets specially adapted for multi-colour inkjet printing
• CPC Class Codes: Y02P 20/582 Recycling of unreacted starting or intermediate materials

Abstract

An aqueous inkjet black ink composition for use in continuous ink jet printing is provided comprising black pigment particles dispersed with a polymeric dispersant or self dispersing pigment particles without the need for a dispersant; and at least one surfactant, wherein the at least one surfactant is selected to provide the ink composition with a 10-ms dynamic surface tension of less than 54 mN/m. The invention relates to continuous ink jet printing of an aqueous pigmented ink composition recycled from a main ink supply reservoir, employing a printer with a drop ejector and a drop deflector and a non-printing drop catcher capable of returning unprinted ink to the fluid delivery system following the capture of non-printing drops. The pigmented ink jet ink compositions provide for particularly suitable fluid properties on the drop catcher face that minimize printing defects that can occur during drop deflection during the printing of high dynamic range images at high speed.

Claims

1. An aqueous inkjet black ink composition for continuous ink jet printing comprising:

black pigment particles dispersed with a polymeric dispersant; and

at least one surfactant;

wherein the ink composition has a 10-ms dynamic surface tension of less than 54 mN/m, wherein the ink is comprised of less than 10 wt % of humectant and co-solvent, and wherein the black pigment particles have a 95^th percentile particle size diameter of less than about 150 nm.

2. The inkjet ink composition of claim 1 wherein the ink composition has a 10-ms dynamic surface tension of less than or equal to about 53 mN/m.

3. The inkjet ink composition of claim 1 wherein the ink composition has a 10-ms dynamic surface tension of less than or equal to about 50 mN/m.

4. The inkjet ink composition of claim 1 wherein the ink has a static surface tension of at least 30 mN/m.

5. The inkjet ink composition of claim 1 wherein the ink has a static surface tension of at least 35 mN/m.

6. The inkjet ink composition of claim 1 wherein the ink composition has a 10-ms dynamic surface tension of less than or equal to about 50 mN/m.

7. The inkjet ink composition of claim 1 wherein the ink is comprised of less than or equal to 8 wt % of humectant and co-solvent.

8. The inkjet ink composition of claim 7 wherein the ink composition has about a 10-ms dynamic surface tension of less than or equal to about 50 mN/m.

9. The inkjet ink composition of claim 1 wherein the black pigment particles have a median volume-weighted particle size of less than about 90 nm.

10. The inkjet ink composition of claim 1 wherein the ink has a dynamic viscosity of less than about 3.0 mPa-s.

11. The inkjet ink composition of claim 1 wherein the ink has a dynamic viscosity of less than about 2.0 mPa-s.

12. The inkjet ink composition of claim 1 wherein the ink has a dynamic viscosity of less than about 1.5 mPa-s.

13. The inkjet ink composition of claim 1 wherein the black pigment particles are dispersed with a polymeric, amphiphilic dispersant.

14. The inkjet ink set of claim 13, wherein polymeric dispersant comprises at least one hydrophilic monomer that is an acrylic acid or methacrylic acid monomer, and at least one monomer comprised of a hydrophobic methacrylate or acrylate monomer containing an aliphatic chain having greater than or equal to 12 carbons.

15. The inkjet ink composition of claim 1 wherein the ink comprises a water soluble homopolymer or co-polymer additive distinct from any dispersant used to disperse the pigment particles, and wherein the polymer additive is present in an amount of from 0.05% to 5% by weight.

16. The inkjet ink composition of claim 1 wherein the ink composition has a 10-ms dynamic surface tension of at least about 30 mN/m.

17. The inkjet ink composition of claim 1, comprising one or more acetylenic diol surface active compounds to modify fluid dynamic surface tension.