Measuring seawater capacitance in three dimensions as well as time

• US 8,463,568 B1
• Filed: 04/21/2011
• Issued: 06/11/2013
• Est. Priority Date: 04/21/2011
• Status: Active Grant

• Current Assignee: The United States Of America As Represented By The Secretary Of The Department Of The Interior
• Original Assignee: The United States of America as represented by the Secretary of the Interior
• Inventors: Wynn, Jeffrey C.
• Primary Examiner(s): LE, TOAN M
• Application Number:
  US13/091,314
• Time in Patent Office: 782 Days
• Field of Search: 702/65, 702 1- 2, 702/57, 702/64, 702/72, 702/127, 702/189, 324/358, 324/362, 324364-365
• US Class Current: 702/65
• CPC Class Codes: G01N 27/226 Construction of measuring vessels; Electrodes therefor
• CPC Class Codes: G01N 33/1833 Oil in water
• CPC Class Codes: G01N 33/1886 using probes, e.g. submersible probes, buoys

Abstract

A system for mapping and characterizing a hydrocarbon plume in seawater by measuring seawater capacitance. Multiple streamer cables are towed in the sea behind a ship, each at a different depth, simultaneously. Each streamer cable includes transmitters and receivers at the free end thereof. The free ends of the streamer cables pass through the plume and the transmitters transmit an electrical current into the plume. The receivers detect any secondary signals produced by capacitive effects of the hydrocarbon or hydrocarbon and dispersant surrounded by conductive seawater in response to the inducing electrical current. Pre-amplifiers connected to the receivers and a two-step calibration procedure and various grounding and shielding steps provide noise rejection. An electronics system on board the ship processes the secondary signals to provide immediate development of detailed maps of plume location, and to provide tracking and characterization of how the plume changes shape and character over time.

Claims

1. A seawater capacitance detection method for rapidly mapping and characterizing hydrocarbon plumes in seawater, the method comprising:

towing a streamer array having three or more vertically stacked streamer cables at three or more depths, respectively, through a seawater column containing a hydrocarbon plume;

energizing two or more transmitter electrodes on each streamer cable with an electrical current signal, the transmitter electrodes injecting electrical current into the seawater column;

episodically turning off transmission of the electrical current signal;

arranging a plurality of receiver electrodes on each streamer cable into one or more receiver sets, each receiver set sampling a volume of seawater surrounding it and detecting any returned secondary signals produced by a capacitive effect resulting from injecting the electrical current into the seawater column and turning off the transmission of the electrical current signal, and each receiver set successively sampling a larger volume of water as the receiver sets are positioned further away from the transmitter electrodes;

processing the returned secondary signals, for each adjacent pair of receiver sets, by subtracting the smallest volume of seawater from the next smallest volume of seawater to yield a capacitance value of a donut-shaped sampling volume of seawater outside the smallest volume, the receiver sets positioned further away from the transmitter electrodes providing increasingly larger donut-shaped sampling volumes of sampling data of the capacitance of the seawater column through which the streamer cables are towed;

processing and geometrically correcting the capacitance values of the donut-shaped sampling volumes of seawater to yield a frequency-varying final seawater capacitance value for the volume of seawater sampled by each receiver set; and

mapping and characterizing the hydrocarbon plume using the final seawater capacitance values of the receiver sets.

2. The seawater capacitance detection method of claim 1, wherein said arranging a plurality of receiver electrodes on each streamer cable into one or more receiver sets comprises arranging eight or more receiver electrodes in groups of three to form six or more triplets, each adjacent pair of triplets sharing two receiver electrodes.

3. The seawater capacitance detection method of claim 1, wherein said processing and geometrically correcting the capacitance values of the donut-shaped sampling volumes of seawater to yield a frequency-varying final seawater capacitance value for the volume of seawater sampled by each receiver set comprises measuring a phase shift between the transmitted electrical current signal and the processed returned secondary signals detected by each receiver set.

4. The seawater capacitance detection method of claim 1, further comprising optimizing vertical separation between the vertically stacked streamer cables by providing overlap of the donut-shaped sampling volumes of seawater sampled by the receiver sets of each streamer cable to provide continuous vertical volume sampling for the vertically stacked array of streamer cables as a whole.

5. The seawater capacitance detection method of claim 1, wherein said towing a streamer array having three or more vertically stacked streamer cables at three or more depths, respectively, through a seawater column further comprises maintaining each streamer cable at a specific depth so that a sampling field of each streamer cable overlaps a sampling field of adjacent overlying and underlying streamer cables by about 5 percent to about 10 percent to remove any unmeasured gaps in a vertical sampling plane.

6. The seawater capacitance detection method of claim 1, wherein said energizing two or more transmitter electrodes on each streamer cable with an electrical current signal further comprises energizing the transmitter electrodes with a square wave current signal and optimizing a waveform of the square wave current signal to include constituent frequencies in the range of about 1 Hz to about 100 Hz, and using the constituent frequencies to detect the frequency-varying final seawater capacitance values of discrete parts of the hydrocarbon plume in the seawater.

7. The seawater capacitance detection method of claim 1, wherein said mapping and characterizing the hydrocarbon plume using the final seawater capacitance values of the receiver sets further comprises:

obtaining spatial data by obtaining depth and location data for each streamer cable to precisely locate each sampling point on each streamer cable and provide an image of the hydrocarbon plume in three dimensions including latitude, longitude, and depth;

measuring movement of the hydrocarbon plume over time;

comparing characteristics of known hydrocarbons and hydrocarbon-saltwater mixes to measured characteristics of the hydrocarbon plume to precisely characterize the hydrocarbon plume; and

using the spatial, time, and characterization data and a frequency distribution of the capacitance values over a plurality of frequency decades to assemble a four-dimensional seawater capacitance map that includes hydrocarbon plume density and droplet-size distribution of oil droplets that form the hydrocarbon plume, the four-dimensional seawater capacitance map providing the ability to predict future hydrocarbon plume location and state.

8. The seawater capacitance detection method of claim 1, wherein said towing a streamer array having three or more vertically stacked streamer cables at three or more depths, respectively, through a seawater column further comprises towing the streamer cables by a ship across a region of interest by making keyhole turns to create a tow-path that is offset and folded over and parallel to itself, back and forth, and each towed path forming a sampling plane that is parallel to previous sampling planes.

9. A seawater capacitance detection method for rapidly mapping and characterizing hydrocarbon plumes in seawater, the method comprising:

towing a streamer array having three or more vertically stacked streamer cables at three or more depths, respectively, through a seawater column;

placing two or more transmitter electrodes and a plurality of receiver electrodes on each streamer cable;

transmitting, by the transmitter electrodes, an electrical current into the seawater;

episodically terminating transmission of the electrical current signal;

measuring, by the receiver electrodes, returned secondary signals produced in response to terminating transmission of the electrical current signal, a non-zero capacitance value of the returned secondary signals indicating the presence of a hydrocarbon plume in the seawater;

calculating, based on the returned secondary signals, a capacitance value for discrete volume points within the hydrocarbon plume and seawater mixture sampled by the receiver electrodes; and

mapping and characterizing the hydrocarbon plume using the capacitance values.

10. The seawater capacitance detection method of claim 9, wherein said transmitting, by the transmitter electrodes, an electrical current into the seawater comprises transmitting a square wave current signal into the seawater.

11. The seawater capacitance detection method of claim 10, wherein said transmitting a square wave current signal into the seawater comprises optimizing a waveform of the square wave current signal to include constituent frequencies in the range of about 1 Hz to about 100 Hz, and using the amplitudes of each constituent frequency extracted by Fourier transform to detect the frequency-varying final seawater capacitance values of the hydrocarbon plume and seawater mixture sampled by the receiver electrodes.

12. The seawater capacitance detection method of claim 9, where said placing two or more transmitter electrodes and a plurality of receiver electrodes on each streamer cable comprises arranging the receiver electrodes on each streamer cable into one or more receiver sets, each receiver set sampling a volume of seawater surrounding it, and each receiver set successively sampling a larger volume of water as the receiver sets are positioned further away from the transmitter electrodes.

13. The seawater capacitance detection method of claim 12, wherein said arranging the receiver electrodes on each streamer cable into one or more receiver sets comprises arranging eight or more receiver electrodes in groups of three to form six or more triplets, each adjacent pair of triplets sharing two receiver electrodes.

14. The seawater capacitance detection method of claim 12, wherein said measuring, by the receiver electrodes, returned secondary signals produced in response to terminating transmission of the electrical current signal comprises processing the returned secondary signals, for each adjacent pair of receiver sets, by subtracting the smallest volume of seawater sampled by the nearest triplet from the next smallest volume of seawater to yield a capacitance value of a donut-shaped sampling volume of seawater outside the smallest volume, the receiver sets positioned further away from the transmitter electrodes providing increasingly larger donut-shaped sampling volumes of sampling data of the capacitance of the seawater column through which the streamer cables are towed.

15. The seawater capacitance detection method of claim 14, wherein said calculating, based on the returned secondary signals, a capacitance value for discrete volume points within the hydrocarbon plume and seawater mixture sampled by the receiver electrodes comprises geometrically correcting the capacitance value by measuring a phase shift between the transmitted electrical current signal and the processed returned secondary signals.

16. The seawater capacitance detection method of claim 15, wherein said measuring a phase shift between the transmitted electrical current signal and the processed returned secondary signals comprises:

performing a calibration measurement of ship-board instrumentation on a ship towing the streamer array to permanently remove a phase contribution from the ship-board instrumentation, the calibration measurement yielding a first measured calibration signal;

performing a calibration measurement of a phase contribution of the ship and the streamer array in a hydrocarbon-free ocean to yield a second measured calibration signal;

performing a Fast Fourier Transform on the first and the second measured calibration signals to yield a system measured calibration signal;

performing a Fast Fourier Transform on the processed returned secondary signals;

deconvolving the Fourier-transformed returned secondary signals against the system measured calibration signal; and

deconvolving the frequency domain results of the transmitted electrical current signals frequency-by-frequency from the Fourier-transformed returned secondary signals to yield the capacitance values between the hydrocarbon plume and the seawater for each receiver electrode triplet.

17. The seawater capacitance detection method of claim 14, further comprising optimizing vertical separation between the vertically stacked streamer cables by providing overlap of the donut-shaped sampling volumes of seawater sampled by the receiver sets of each streamer cable to provide a continuous vertical volume sampling for the vertically stacked array of streamer cables as a whole.

18. The seawater capacitance detection method of claim 9, wherein said transmitting an electrical current into the seawater polarizes a mixture of the hydrocarbon plume and the seawater.

19. The seawater capacitance detection method of claim 14, wherein said mapping and characterizing the hydrocarbon plume in the seawater column using the capacitance values further comprises:

obtaining spatial data by obtaining depth and location data for each streamer cable to precisely locate each sampling point on each streamer cable and provide an image of the hydrocarbon plume in three dimensions including latitude, longitude, and depth;

measuring movement of the hydrocarbon plume over time;

using the spatial and time data to assemble a four-dimensional seawater capacitance map that includes hydrocarbon plume density and droplet-size distribution of oil droplets that form the hydrocarbon plume, the four-dimensional seawater capacitance map providing the ability to predict future hydrocarbon plume location and state; and

characterizing the hydrocarbon plume according to droplet size from discrete capacitance frequency distributions for each sampling volume as the hydrocarbon plume evolves over time.

20. The seawater capacitance detection method of claim 9, wherein said towing a streamer array having three or more vertically stacked streamer cables at three or more depths, respectively, through seawater further comprises controlling vertical placement of each streamer cable to maintain each streamer cable at a specific depth so that a sampling field of each streamer cable overlaps a sampling field of adjacent overlying and underlying streamer cables by about 5 percent to about 10 percent to remove any unmeasured gaps in a vertical sampling plane.

21. The seawater capacitance detection method of claim 9, wherein said towing a streamer array having three or more vertically stacked streamer cables at three or more depths, respectively, through seawater further comprises towing the streamer cables by a ship across a region of interest by making keyhole turns to create a tow-path that is offset and folded over and parallel to itself, back and forth, and each towed path forming a sampling plane that is parallel to previous sampling planes.

22. A seawater capacitance detection method for rapidly mapping and characterizing hydrocarbon plumes in seawater, the method comprising:

towing a master streamer cable through a seawater column;

attaching a sled to an end of the master streamer cable to maintain it substantially vertical in the seawater column;

attaching a plurality of parasitic streamer cables to the master streamer cable, each parasitic streamer cable extending from the master streamer cable and sampling different depths simultaneously;

placing two or more transmitter electrodes and a plurality of receiver electrodes on each parasitic streamer cable;

transmitting, by the transmitter electrodes, an electrical current into the seawater;

episodically terminating transmission of the electrical current signal;

measuring, by the receiver electrodes, returned secondary signals produced in response to terminating transmission of the electrical current signal, a non-zero capacitance value of the returned secondary signals indicating the presence of a hydrocarbon plume in the seawater;

calculating, based on the returned secondary signals, a capacitance value for discrete volume points within the hydrocarbon plume and seawater mixture sampled by the receiver electrodes; and

mapping and characterizing the hydrocarbon plume using the capacitance values.