Liquefaction method and system

• US 8,464,551 B2
• Filed: 11/18/2008
• Issued: 06/18/2013
• Est. Priority Date: 11/18/2008
• Status: Active Grant

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Roberts, Mark Julian, Brostow, Adam Adrian
• Primary Examiner(s): Ciric, Ljiljana
• Assistant Examiner(s): COX, ALEXIS K
• Application Number:
  US12/272,909
• Publication Number:
  US 20100122551A1
• Time in Patent Office: 1,673 Days
• Field of Search: 626/11, 626/12, 626/06, 626/14, 626/23
• US Class Current: 62/611
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/004 by flash gas recovery F25J1/0267 takes precedence
• CPC Class Codes: F25J 1/005 by expansion of a gaseous refrigerant stream with extraction of work
• CPC Class Codes: F25J 1/0052 by vaporising a liquid refrigerant stream
• CPC Class Codes: F25J 1/0072 Nitrogen
• CPC Class Codes: F25J 1/0087 Propane; Propylene
• CPC Class Codes: F25J 1/009 Hydrocarbons with four or more carbon atoms
• CPC Class Codes: F25J 1/0095 Oxides of carbon, e.g. CO2
• CPC Class Codes: F25J 1/0097 Others, e.g. F-, Cl-, HF-, HClF-, HCl-hydrocarbons etc. or mixtures thereof
• CPC Class Codes: F25J 1/0204 as a single flow SCR cycle
• CPC Class Codes: F25J 1/0205 as a dual level SCR refrigeration cascade
• CPC Class Codes: F25J 1/0254 controlling particular process parameter, e.g. pressure, temperature
• CPC Class Codes: F25J 1/0263 using different types of heat exchangers
• CPC Class Codes: F25J 1/0265 comprising cores associated exclusively with the cooling of a refrigerant stream, e.g. for auto-refrigeration or economizer
• CPC Class Codes: F25J 1/0267 using flash gas as heat sink
• CPC Class Codes: F25J 1/0268 using a dedicated refrigeration means F25J1/0296 takes precedence
• CPC Class Codes: F25J 1/0283 Gas turbine as the prime mechanical driver
• CPC Class Codes: F25J 1/0284 Electrical motor as the prime mechanical driver
• CPC Class Codes: F25J 1/0288 using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
• CPC Class Codes: F25J 1/0292 Refrigerant compression by cold or cryogenic suction of the refrigerant gas
• CPC Class Codes: F25J 1/0294 : Multiple compressor casings/strings in parallel, e.g. split arrangement
• CPC Class Codes: F25J 2220/62 : Separating low boiling components, e.g. He, H2, N2, Air
• CPC Class Codes: F25J 2230/08 : Cold compressor, i.e. suction of the gas at cryogenic temperature and generally without afterstage-cooler
• CPC Class Codes: F25J 2230/32 : Compression of the product stream
• CPC Class Codes: F25J 2270/16 : with mutliple gas expansion loops of the same refrigerant
• CPC Class Codes: F25J 2290/62 : Details of storing a fluid in a tank

Abstract

A method for liquefaction using a closed loop refrigeration system, the method comprising the steps of (a) compressing a gaseous refrigerant stream in at least one compressor; (b) cooling the compressed gaseous refrigerant stream in a first heat exchanger; (c) expanding at least a first portion of the cooled, compressed gaseous refrigerant stream from the first heat exchanger in a first expander to provide a first expanded gaseous refrigerant stream; and (d) cooling and substantially liquefying a feed gas stream to form a substantially liquefied feed gas stream in a second heat exchanger through indirect heat exchange against at least a first portion of the first expanded gaseous refrigerant stream from the first expander, wherein the first expanded gaseous refrigerant stream exiting the first expander is substantially vapor.

Claims

1. A method of liquefaction using a closed loop refrigeration system utilizing substantially isentropic expansion of a gaseous refrigerant, the method comprising the steps of:

(a) compressing a gaseous refrigerant stream in at least one compressor;

b) cooling at least a portion of the compressed gaseous refrigerant stream in a first heat exchanger to below ambient temperature, thereby creating a compressed, cooled refrigerant stream;

c) expanding at least a portion of the compressed, cooled refrigerant stream in a first expander to provide a first expanded gaseous refrigerant stream, wherein the first expanded gaseous refrigerant stream exiting the first expander is substantially vapor;

d) cooling and substantially liquefying a feed gas stream to form a substantially liquefied feed gas stream in a second heat exchanger through indirect heat exchange against at least a first portion of the first expanded gaseous refrigerant stream;

e) extracting a second portion of the first expanded gaseous refrigerant stream from the first portion of the first expanded gaseous refrigerant stream from an intermediate location of the second heat exchanger to balance a precooling section of the second heat exchanger; and

,

f) extracting at least a third portion of the first expanded gaseous refrigerant stream from the first portion of the first expanded gaseous refrigerant stream at the warm end of the second heat exchanger.

2. The method of claim 1, wherein the gaseous refrigerant stream is a nitrogen stream.

3. The method of claim 1, further comprising storing the cooled and substantially liquefied feed gas stream in a high-pressure storage tank.

4. The method of claim 1, further comprising providing supplemental cooling to the first heat exchanger through indirect heat exchange with a supplemental refrigeration system comprising at least one stage of a vaporizing liquid refrigerant.

5. The method of claim 4, wherein the vaporizing liquid refrigerant comprises CO₂, methane, propane, butane, iso-butane, propylene, ethane, ethylene, R22, HFC refrigerants including R410A, R134A, R507, R23, or combinations thereof.

6. The method of claim 1, wherein the feed gas stream for liquefaction is a natural gas stream.

7. The method of claim 6, wherein the natural gas liquefaction occurs on a Floating Production Storage and Offloading (FPSO) vessel.

8. The method of claim 1, wherein a first portion of the first expanded gaseous refrigerant stream from the first expander cools the feed gas stream through indirect heat exchange in the second heat exchanger in step (d) of claim 1 and wherein a second portion of the first expanded gaseous refrigerant stream from the first expander cools a second portion of the cooled, compressed gaseous refrigerant stream from the first heat exchanger in a third heat exchanger.

9. The method of claim 8, wherein a third portion of the first expanded gaseous refrigerant stream exiting the first expander is heated in the third heat exchanger prior to expansion in a second expander.

10. The method of claim 8, wherein the first heat exchanger and the third heat exchanger are plate-and-fin brazed aluminum (core) type heat exchangers.

11. The method of claim 1, further comprising subcooling the cooled and substantially liquefied feed gas stream through indirect heat exchange in a subcooler exchanger against a second expanded gaseous refrigerant stream exiting a second expander, wherein the second expanded gaseous refrigerant stream exiting the second expander is substantially vapor.

12. The method of claim 11, further comprising throttling the subcooled liquefied feed gas stream, separating the throttled subcooled liquefied feed gas stream in a phase separator into a liquid product and a flash vapor, wherein the flash vapor can be further compressed, warmed, and used as fuel for energy production.

13. The method of claim 11, wherein the second heat exchanger and the subcooler exchanger are wound-coil heat exchangers.

14. The method of claim 11, wherein the compressing of the gaseous refrigerant stream of step (a) of claim 1 occurs by:

(a)(1) compressing the gaseous refrigerant stream in a low pressure compressor; and

(a)(2) further compressing the gaseous refrigerant stream a high pressure compressor.

15. The method of claim 14, further comprising warming a second portion of the first expanded gaseous refrigerant stream exiting the first expander in a third heat exchanger and the first heat exchanger to form a warmed gaseous refrigerant stream and combining the warmed gaseous refrigerant stream with the compressed gaseous refrigerant stream exiting the low pressure compressor between steps (a)(1) and (a)(2) of claim 14.

16. The method of claim 14, further comprising heating, in the first heat exchanger, the second portion of the first expanded gaseous refrigerant stream, which is extracted from the intermediate location of the second heat exchanger, and combining the warmed gaseous refrigerant stream with the compressed gaseous refrigerant stream exiting the low pressure compressor between steps (a)(1) and (a)(2) of claim 14.

17. The method of claim 14, further comprising splitting the compressed gaseous refrigerant stream exiting the high pressure compressor, expanding a first portion of the compressed gaseous refrigerant stream exiting the at least one compressor in a third expander, warming the expanded first portion of the compressed gaseous refrigerant stream in the first heat exchanger, and then combining the warmed, expanded first portion of the compressed gaseous refrigerant stream with the compressed gaseous refrigerant stream exiting the low pressure compressor between steps (a)(1) and (a)(2) of claim 14, and cooling the second portion of the compressed gaseous refrigerant stream exiting the high pressure compressor in the first heat exchanger in step (b) of claim 1.

18. The method of claim 14, wherein the pressure of the second expanded gaseous refrigerant stream exiting the second expander is lower than the pressure of the first expanded gaseous refrigerant stream exiting the first expander.

19. The method of claim 18, further comprising splitting the compressed gaseous refrigerant stream exiting the high pressure compressor, expanding a first portion of the compressed gaseous refrigerant stream exiting the high pressure compressor in a third expander, warming the expanded first portion of the compressed gaseous refrigerant stream in the first heat exchanger, and then combining the warmed, expanded first portion of the compressed gaseous refrigerant stream with the compressed gaseous refrigerant stream exiting the low pressure compressor between steps (a)(1) and (a)(2) of claim 14, and cooling the second portion of the compressed gaseous refrigerant stream exiting the high pressure compressor in the first heat exchanger in step (b) of claim 1.

20. The method of claim 14, further comprising splitting the compressed gaseous refrigerant stream exiting the high pressure compressor, cooling a first portion of the compressed gaseous refrigerant stream exiting the high pressure compressor in a supplemental refrigeration system that comprises at least one stage of a vaporizing liquid refrigerant, and combining the cooled first portion of the compressed gaseous refrigerant stream with the first portion of the cooled, compressed gaseous refrigerant stream from the first heat exchanger for expansion in the first expander in step (c) of claim 1, and wherein a second portion of the compressed gaseous refrigerant stream exiting the high pressure compressor is cooled in the first heat exchanger in step (b) of claim 1.

21. The method of claim 20, further comprising precooling the feed gas stream in a supplemental refrigeration system that comprises at least one stage of a vaporizing liquid refrigerant prior to step (d) of claim 1.

22. The method of claim 21, wherein the supplemental refrigeration system for precooling the feed gas stream and the supplemental refrigeration system for cooling the first portion of the compressed gaseous refrigerant stream exiting the high pressure compressor is a single supplemental refrigeration system.

23. A closed loop system for liquefaction utilizing substantially isentropic expansion of a gaseous refrigerant, comprising:

A refrigerant compressor;

A first heat exchanger fluidly coupled to the low pressure refrigerant compressor and adapted to receive at least a portion of a compressed gaseous refrigerant stream from the refrigerant compressor;

A first expander fluidly coupled to the first heat exchanger and adapted to receive at least a portion of the cooled, compressed refrigerant stream from the first heat exchanger;

A second heat exchanger fluidly coupled to the first expander and adapted to receive at least a portion of an expanded gaseous refrigerant stream from the first expander, wherein the at least a portion of the expanded gaseous refrigerant stream is substantially vapor;

A first conduit for extracting a first portion of the expanded gaseous refrigerant stream from the second heat exchanger from an intermediate location of the second heat exchanger to balance a precooling section of the second heat exchanger;

A second conduit for extracting at least a second portion of the expanded gaseous refrigerant stream from the second heat exchanger from the warm end of the second heat exchanger; and

A third conduit for introducing a feed gas stream in the second heat exchanger to form a substantially liquefied feed gas stream through indirect heat exchange against at least a portion of an expanded gaseous refrigerant stream from the first expander.

24. The system of claim 23, wherein the stream of refrigerant is a nitrogen stream.

25. The system of claim 23, wherein the first heat exchanger and the second heat exchanger are plate-and-fin brazed aluminum (core) type heat exchangers.

26. The system of claim 23, further comprising:

a first low pressure refrigerant compressor fluidly coupled to the first heat exchanger; and

a second low pressure refrigerant compressor fluidly coupled to the third heat exchanger.

27. The system of claim 23, wherein the feed gas stream is a natural gas stream.

28. The system of claim 27, wherein the system is used on a Floating Production Storage and Offloading (FPSO) vessel.

29. The system of claim 23, further comprising a third heat exchanger and a subcooler heat exchanger;

wherein the subcooler exchanger is fluidly coupled to the third heat exchanger and the second expander and adapted for acceptance of the feed gas stream from the third heat exchanger.

30. The system of claim 29, wherein the third heat exchanger and the subcooler exchanger are wound-coil heat exchangers.

31. The system of claim 29, further comprising:

a valve fluidly coupled to the subcooler exchanger, the valve being adapted for acceptance of the feed gas stream from the subcooler exchanger; and

a phase separator

fluidly coupled to the valve and adapted for separation of the feed gas stream into a liquid product and a flash vapor.

32. The system of claim 23, further comprising:

(a)a low pressure refrigerant compressor fluidly coupled to the first heat exchanger; and

(b)a high pressure refrigerant compressor fluidly coupled to the first heat exchanger and the low pressure refrigerant compressor adapted for acceptance of a refrigerant stream from the first heat exchanger and the low pressure refrigerant compressor.

33. The system of claim 32, further comprising a supplemental refrigeration system fluidly coupled to the high pressure refrigerant compressor and adapted for acceptance of a compressed gaseous refrigerant stream from the high pressure refrigerant compressor.

34. The system of claim 32, further comprising a third expander fluidly coupled to the high pressure refrigerant compressor and adapted for accepting a portion of a compressed gaseous refrigerant stream from the high pressure refrigerant compressor.

35. The system of claim 32, further comprising a supplemental refrigeration system adapted to provide cooling to the first heat exchanger, wherein the supplemental refrigeration system comprises at least one stage of a vaporizing liquid refrigerant.

36. The system of claim 35, wherein the vaporizing liquid refrigerant comprises CO₂, methane, propane, butane, iso-butane, propylene, ethane, ethylene, R22, HFC refrigerants including R410A, R134A, R507, R23, or combinations thereof.