Liquid crystal polyester composition and electronic circuit board using the same

• US 8,465,670 B2
• Filed: 07/23/2010
• Issued: 06/18/2013
• Est. Priority Date: 07/30/2009
• Status: Active Grant

• Current Assignee: Sumitomo Chemical Company Limited
• Original Assignee: Sumitomo Chemical Company Limited
• Inventors: Iwase, Sadanobu, Iyama, Hironobu, Kondo, Takeshi
• Primary Examiner(s): Visconti, Geraldina
• Application Number:
  US13/387,236
• Publication Number:
  US 20120125673A1
• Time in Patent Office: 1,061 Days
• Field of Search: 252/299.01, 252/299.6, 428/1.1, 428/1.3, 174/250, 174/256, 174/258
• US Class Current: 252/299.01
• CPC Class Codes: C08L 67/03 the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
• CPC Class Codes: C09D 167/03 the dicarboxylic acids and dihydroxy compounds having the carboxyl - and the hydroxy groups directly linked to aromatic rings
• CPC Class Codes: C09K 19/3809 Polyesters; Polyester derivatives, e.g. polyamides
• CPC Class Codes: C09K 2323/00 Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
• CPC Class Codes: C09K 2323/03 Viewing layer characterised by chemical composition
• CPC Class Codes: H05K 1/056 the metal substrate being covered by an organic insulating layer
• CPC Class Codes: H05K 2201/0141 Liquid crystal polymer [LCP]
• CPC Class Codes: H05K 2201/0209 Inorganic, non-metallic particles
• CPC Class Codes: H05K 2201/0266 Size distribution

Abstract

To provide a liquid crystal polyester composition which is suited for use as a material for forming a liquid crystal polyester film having excellent thermal conductivity. Also, an excellent electronic circuit board is provided by using an insulating film obtained from the liquid crystal polyester composition. The liquid crystal polyester composition of the present invention is composed of a liquid crystal polyester, a solvent and a thermally conductive filler. The thermally conductive filler is contained in the amount of 50 to 90 volume % based on the total amount of the liquid crystal polyester and the thermally conductive filler, and the thermally conductive filler contains 0 to 20 volume % of a first thermally conductive filler having a volume average particle diameter of 0.1 μm or more and less than 1.0 μm, 5 to 40 volume % of a second thermally conductive filler having a volume average particle diameter of 1.0 μm or more and less than 5.0 μm and 40 to 90 volume % of a third thermally conductive filler having a volume average particle diameter of 5.0 μm or more and 30.0 μm or less.

Claims

1. A liquid crystal polyester composition comprising a liquid crystal polyester, a solvent and a thermally conductive filler, wherein

the content of the thermally conductive filler is from 50 to 90 volume % based on the total amount of the liquid crystal polyester and the thermally conductive filler, and

the liquid crystal polyester composition contains, as the thermally conductive filler, 0 to 20 volume % of a first thermally conductive filler having a volume average particle diameter of 0.1 μ

m or more and less than 1.0 μ

m, 5 to 40 volume % of a second thermally conductive filler having a volume average particle diameter of 1.0 μ

m or more and less than 5.0 μ

m, and 40 to 90 volume % of a third thermally conductive filler having a volume average particle diameter of 5.0 μ

m or more and 30.0 μ

m or less.

2. The liquid crystal polyester composition according to claim 1, wherein the liquid crystal polyester includes a first structural unit represented by the following formula (1), a second structural unit represented by the following formula (2) and a third structural unit represented by the following formula (3), and

the content of the first structural unit is from 30 to 80 mol %, the content of the second structural unit is from 35 to 10 mol %, and the content of the third structural unit is from 35 to 10 mol %, based on the total structural units:

—

O—

Ar₁—

CO—

, 

 

(1)

—

CO—

Ar₂—

CO—

, and 

 

(2)

—

X—

Ar₃—

Y—

 

 

(3)

wherein

Ar₁;

1,4-phenylene, 2,6-naphthalene or 4,4′

-biphenylene,

Ar₂;

1,4-phenylene, 1,3-phenylene or 2,6-naphthalene,

Ar₃;

1,4-phenylene or 1,3-phenylene,

X;

—

NH—

, and

Y;

—

O—

or —

NH—

.

3. The liquid crystal polyester composition according to claim 1, wherein a part or all of the thermally conductive filler is an aluminum oxide powder.

4. The liquid crystal polyester composition according to claim 1, wherein a part or all of the thermally conductive filler is an aluminum nitride powder.

5. An electronic circuit board comprising a substrate for heat radiation, an insulating film provided on the substrate for heat radiation and a conductive foil for formation of a wiring pattern provided on the insulating film, wherein

the insulating film is a film formed by removing a solvent from a cast of the liquid crystal polyester composition according to claim 1.

6. The electronic circuit board according to claim 5, wherein thermal conductivity of the insulating film is from 6 to 20 W/(m·

K).