Electroluminescent devices and their manufacture

• US 8,470,388 B1
• Filed: 11/15/2012
• Issued: 06/25/2013
• Est. Priority Date: 01/03/2012
• Status: Active Grant

• Current Assignee: Darkside Scientific, Inc.
• Original Assignee: Darkside Scientific, LLC
• Inventors: Zsinko, Andrew, Mastrian, Shawn J.
• Primary Examiner(s): Cleveland, Michael
• Assistant Examiner(s): VETERE, ROBERT A
• Application Number:
  US13/677,864
• Publication Number:
  US 20130171754A1
• Time in Patent Office: 222 Days
• Field of Search: 427/64
• US Class Current: 427/64
• CPC Class Codes: H05B 33/10 Apparatus or processes specially adapted to the manufacture of electroluminescent light sources

Abstract

A process for producing a conformal electroluminescent system. An electrically conductive base backplane film layer is applied upon a substrate. A dielectric film layer is applied upon the backplane film layer, then a phosphor film layer is applied upon the dielectric film layer. An electrode film layer is applied upon the phosphor film layer using a substantially transparent, electrically conductive material. An electrically conductive bus bar may be applied upon the electrode film layer. Preferably, the backplane film layer, dielectric film layer, phosphor film layer, electrode film layer and bus bar are aqueous-based and are applied by spray conformal coating. The electroluminescent phosphor is excitable by an electrical field established across the phosphor film layer such that the device emits electroluminescent light upon application of an electrical charge between the backplane film layer and at least one of the electrode film layer and the bus bar.

Claims

1. A process for producing a conformal electroluminescent system, comprising the steps of:

selecting a substrate;

applying a base backplane film layer upon the substrate using an aqueous-based, electrically conductive backplane material;

applying a dielectric film layer upon the backplane film layer using an aqueous-based dielectric material;

applying a phosphor film layer upon the dielectric film layer using an aqueous-based phosphor material, the phosphor film layer being excited by an ultraviolet radiation source during application, the ultraviolet radiation source providing visual cues while the phosphor film layer is being applied, the application of the phosphor film layer being adjusted in response to the visual cues to apply a generally uniform distribution of the phosphor material upon the dielectric film layer;

applying an electrode film layer upon the phosphor film layer using an aqueous-based, substantially transparent, electrically conductive electrode material, the backplane film layer, dielectric film layer, phosphor film layer, and electrode film layer each being applied by spray conformal coating;

and further including the step of formulating a composition for the dielectric film layer, comprising;

providing about a 2;

1 solution of co-polymer and dilute ammonium hydroxide;

pre-wetting a predetermined quantity of barium titanate in a predetermined quantity of ammonium hydroxide; and

adding the pre-wetted barium titanate to the solution of co-polymer and dilute ammonium hydroxide to form a supersaturated suspension,

wherein the phosphor film layer is excitable by an electrical field established across the phosphor film layer upon application of an electrical charge between the backplane film layer and the electrode film layer such that the phosphor film layer emits electroluminescent light.

2. The process of claim 1, further including the step of selecting a dielectric material having both electrically insulative and permittive properties, the dielectric material further comprising at least one of a titanate, an oxide, a niobate, an aluminate, a tantalate, and a zirconate material, the dielectric material further being suspended in an ammonia aqueous solvent.

3. The process of claim 1, further including the step of selecting a dielectric material having electrically insulative and permittive properties, the dielectric material further having photorefractive properties to facilitate the propagation of light through superimposed layers of the device.

4. The process of claim 1, further including the step of selecting, for the phosphor material, a semi-conductive coating composition having phosphors encapsulated within a highly electrostatically permeable polymer matrix.

5. The process of claim 1, further including the step of selecting, for the phosphor material, a coating composition containing quantum dots or zinc sulfide-based phosphors doped with at least one of copper, manganese and silver.

6. A process for producing a conformal electroluminescent system, comprising the steps of:

selecting a generally transparent substrate;

applying an electrode film layer upon the substrate using an aqueous-based, substantially transparent electrically conductive electrode material;

applying a phosphor film layer upon the electrode film layer using an aqueous-based phosphor material, the phosphor film layer being excited by an ultraviolet radiation source during application, the ultraviolet radiation source providing visual cues while the phosphor film layer is being applied, the application of the phosphor film layer being adjusted in response to the visual cues to apply a generally uniform distribution of the phosphor material upon the dielectric film layer;

applying a dielectric film layer upon the phosphor layer using an aqueous-based dielectric material;

applying a base backplane film layer upon the dielectric film layer using an aqueous-based, electrically conductive backplane material, the backplane film layer, dielectric film layer, phosphor film layer, and electrode film layer each being applied by spray conformal coating; and

further including the step of formulating a composition for the dielectric film layer, comprising;

providing about a 2;

1 solution of co-polymer and dilute ammonium hydroxide;

pre-wetting a predetermined quantity of barium titanate in a predetermined quantity of ammonium hydroxide; and

adding the pre-wetted barium titanate to the solution of co-polymer and dilute ammonium hydroxide to form a supersaturated suspension,

wherein the phosphor film layer is excitable by an electrical field established across the phosphor film layer upon application of an electrical charge between the backplane film layer and the electrode film layer such that the phosphor film layer emits electroluminescent light.

7. The process of claim 6, further including the step of selecting a dielectric material having both electrically insulative and permittive properties, the dielectric material further comprising at least one of a titanate, an oxide, a niobate, an aluminate, a tantalate, and a zirconate material, the dielectric material further being suspended in an ammonia aqueous solvent.

8. The process of claim 6, further including the step of selecting a dielectric material having electrically insulative and permittive properties, the dielectric material further having photorefractive properties to facilitate the propagation of light through superimposed layers of the device.

9. The process of claim 6, further including the step of selecting, for the phosphor material, a semi-conductive coating composition having phosphors encapsulated within a highly electrostatically permeable polymer matrix.

10. The process of claim 6, further including the step of selecting, for the phosphor material, a coating composition containing quantum dots or zinc sulfide-based phosphors doped with at least one of copper, manganese and silver.

11. A process for producing a conformal electroluminescent system, comprising the steps of:

selecting a generally transparent substrate;

applying a first electrode film layer upon the substrate using an aqueous-based, substantially transparent, electrically conductive electrode material;

applying a first phosphor film layer upon the electrode film layer using an aqueous-based phosphor material, the first phosphor film layer being excited by an ultraviolet radiation source during application, the ultraviolet radiation source providing visual cues while the first phosphor film layer is being applied, the application of the first phosphor film layer being adjusted in response to the visual cues to apply a generally uniform distribution of the phosphor material upon the dielectric film layer;

applying a dielectric film layer upon the phosphor film layer using an aqueous-based dielectric material;

applying a second phosphor film layer upon the electrode film layer using the phosphor material, the second phosphor film layer being excited by an ultraviolet radiation source during application, the ultraviolet radiation source providing visual cues while the second phosphor film layer is being applied, the application of the second phosphor film layer being adjusted in response to the visual cues to apply a generally uniform distribution of the phosphor material upon the dielectric film layer;

applying a second electrode film layer upon the second phosphor layer using the electrode material; and

further including the step of formulating a composition for the dielectric film layer, comprising;

providing about a 2;

1 solution of co-polymer and dilute ammonium hydroxide;

pre-wetting a predetermined quantity of barium titanate in a predetermined quantity of ammonium hydroxide; and

adding the pre-wetted barium titanate to the solution of co-polymer and dilute ammonium hydroxide to form a supersaturated suspension,

the first electrode film layer, first phosphor film layer, dielectric film layer, second phosphor film layer, and second electrode film layer each being applied by spray conformal coating,

wherein the first and second phosphor film layers are excitable by an electrical field established across the first and second phosphor film layers upon application of an electrical charge between the first electrode film layer and the second electrode film layer such that the device emits electroluminescent light, the electroluminescent light being emitted on opposing sides of the substrate.

12. The process of claim 11, further including the step of selecting a dielectric material having both electrically insulative and permittive properties, the dielectric material further comprising at least one of a titanate, an oxide, a niobate, an aluminate, a tantalate, and a zirconate material, the dielectric material further being suspended in an ammonia aqueous solvent.

13. The process of claim 11, further including the step of selecting a dielectric material having electrically insulative and permittive properties, the dielectric material further having photorefractive properties to facilitate the propagation of light through superimposed layers of the device.

14. The process of claim 11, further including the step of selecting, for the phosphor material, a semi-conductive coating composition having phosphors encapsulated within a highly electrostatically permeable polymer matrix.

15. The process of claim 11, further including the step of selecting, for the phosphor material, a coating composition containing quantum dots or zinc sulfide-based phosphors doped with at least one of copper, manganese and silver.