Polymeric acid catalysts and uses thereof

• US 8,476,388 B2
• Filed: 10/22/2012
• Issued: 07/02/2013
• Est. Priority Date: 02/28/2011
• Status: Active Grant

• Current Assignee: DSM Nutritional Products LLC (DSM-Firmenich AG)
• Original Assignee: Midori Renewables Inc. (DSM-Firmenich AG)
• Inventors: Geremia, John M., Baynes, Brian M., Dhawan, Ashish
• Primary Examiner(s): Choi, Ling
• Assistant Examiner(s): WANG, CHUN CHENG
• Application Number:
  US13/657,724
• Publication Number:
  US 20130042859A1
• Time in Patent Office: 253 Days
• Field of Search: 526/274, 526/259, 526/260, 526/263, 526/287, 526/310, 526/347, 502/159, 536/1.11, 536/127
• US Class Current: 526/274
• CPC Class Codes: B01J 31/06 containing polymers organometallic polymers B01J31/123; polymer-bound organometallic complexes B01J31/165; coordination polymers B01J31/1691
• CPC Class Codes: C08F 12/18 Chlorine
• CPC Class Codes: C08F 212/08 Styrene
• CPC Class Codes: C08F 212/18 Chlorine
• CPC Class Codes: C08F 212/22 Oxygen
• CPC Class Codes: C08F 212/30 Sulfur
• CPC Class Codes: C08F 212/36 Divinylbenzene
• CPC Class Codes: C08F 226/06 by a heterocyclic ring containing nitrogen
• CPC Class Codes: C08F 226/08 N-Vinyl-pyrrolidine
• CPC Class Codes: C08F 8/24 Haloalkylation
• CPC Class Codes: C08F 8/30 Introducing nitrogen atoms or nitrogen-containing groups
• CPC Class Codes: C08F 8/32 by reaction with amines
• CPC Class Codes: C08F 8/36 Sulfonation; Sulfation
• CPC Class Codes: C08F 8/40 Introducing phosphorus atoms or phosphorus-containing groups
• CPC Class Codes: C08F 8/42 Introducing metal atoms or metal-containing groups
• CPC Class Codes: C08F 8/44 Preparation of metal salts or ammonium salts
• CPC Class Codes: C08G 8/28 Chemically modified polycondensates
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

Polymers useful as catalysts in non-enzymatic saccharification processes are provided. Provided are also methods for hydrolyzing cellulosic materials into monosaccharides and/or oligosaccharides using these polymeric acid catalysts.

Claims

1. A method for degrading biomass into one or more sugars, comprising:

a) providing biomass;

b) contacting the biomass with a polymer and a solvent to form a reaction mixture,

wherein the polymer comprises acidic monomers and ionic monomers connected to form a polymeric backbone, wherein each acidic monomer comprises at least one Bronsted-Lowry acid, and wherein each ionic monomer independently comprises at least one nitrogen-containing cationic group or at least one phosphorous-containing cationic group; and

c) degrading the biomass in the reaction mixture to produce a liquid phase and a solid phase, wherein the liquid phrase comprises one or more sugars, and wherein the solid phase comprises residual biomass.

2. The method of claim 1, further comprising the step of:

d) isolating at least a portion of the liquid phase from the solid phase.

3. The method of claim 2, further comprising the step of:

e) recovering the one or more sugars from the isolated liquid phase.

4. The method of claim 2, wherein the isolating of at least a portion of the liquid phase from the solid phase in step (d) produces a residual biomass mixture, and wherein the method further comprises:

i) providing additional biomass;

ii) contacting the additional biomass with the residual biomass mixture;

iii) degrading the additional biomass and the residual biomass mixture to produce a second liquid phase and a second solid phase, wherein the second liquid phase comprises one or more additional sugars, and wherein the second solid phase comprises additional residual biomass.

5. The method of claim 4, further comprising the step of:

iv) isolating at least a portion of the second liquid phase from the second solid phase.

6. The method of claim 5, further comprising the step of:

v) recovering the one or more additional sugars from the isolated second liquid phase.

7. The method of claim 4, further comprising contacting the additional biomass and the residual biomass mixture in step (ii) with additional polymer,

wherein the additional polymer comprises acidic monomers and ionic monomers connected to form a polymeric backbone, wherein each acidic monomer comprises at least one Bronsted-Lowry acid, and wherein each ionic monomer independently comprises at least one nitrogen-containing cationic group or phosphorous-containing cationic group.

8. The method of claim 7, wherein the polymer contacted with the biomass in step (ii) and the additional polymer are the same or different types of polymer.

9. The method of claim 4, further comprising contacting the additional biomass and the residual biomass mixture in step (ii) with additional solvent.

10. The method of claim 9, wherein the solvent in step (ii) and the additional solvent are the same or different types of solvent.

11. The method of claim 5, further comprising recovering the polymer after isolating at least a portion of the second liquid phase from the second solid phase.

12. The method of claim 1, wherein the solvent comprises water.

13. The method of claim 1, wherein the Bronsted-Lowry acid at each occurrence in the polymer is independently selected from the group consisting of sulfonic acid, phosphonic acid, acetic acid, isophthalic acid, boronic acid, and perfluorinated acid.

14. The method of claim 1, wherein one or more of the acidic monomers in the polymer each further comprise a linker connecting the Bronsted-Lowry acid to the polymeric backbone, wherein the linker at each occurrence is independently selected from the group consisting of unsubstituted or substituted alkylene, unsubstituted or substituted cycloalkylene, unsubstituted or substituted alkenylene, unsubstituted or substituted arylene, unsubstituted or substituted heteroarylene, unsubstituted or substituted alkylene ether, unsubstituted or substituted alkylene ester, and unsubstituted or substituted alkylene carbamate.

15. The method of claim 1, wherein the nitrogen-containing cationic group in the polymer at each occurrence is independently selected from the group consisting of pyrrolium, imidazolium, pyrazolium, oxazolium, thiazolium, pyridinium, pyrimidinium, pyrazinium, pyradizimium, thiazinium, morpholinium, piperidinium, piperizinium, and pyrollizinium.

16. The method of claim 1, wherein the phosphorous-containing cationic group in the polymer at each occurrence is independently selected from the group consisting of triphenyl phosphonium, trimethyl phosphonium, triethyl phosphonium, tripropyl phosphonium, tributyl phosphonium, trichloro phosphonium, and trifluoro phosphonium.

17. The method of claim 1, wherein one or more of the ionic monomers in the polymer each further comprise a linker connecting the nitrogen-containing cationic group or the phosphorous-containing cationic group to the polymeric backbone, wherein the linker at each occurrence is independently selected from the group consisting of unsubstituted or substituted alkylene, unsubstituted or substituted cycloalkylene, unsubstituted or substituted alkenylene, unsubstituted or substituted arylene, unsubstituted or substituted heteroarylene, unsubstituted or substituted alkylene ether, unsubstituted or substituted alkylene ester, and unsubstituted or substituted alkylene carbamate.

18. The method of claim 1, wherein the polymeric backbone in the polymer is selected from the group consisting of polyethylene, polypropylene, polyvinyl alcohol, polystyrene, polyurethane, polyvinyl chloride, polyphenol-aldehyde, polytetrafluoroethylene, polybutylene terephthalate, polycaprolactam, poly(acrylonitrile butadiene styrene), polyalkyleneammonium, polyalkylenediammonium, polyalkylenepyrrolium, polyalkyleneimidazolium, polyalkylenepyrazolium, polyalkyleneoxazolium, polyalkylenethiazolium, polyalkylenepyridinium, polyalkylenepyrimidinium, polyalkylenepyrazinium, polyalkylenepyradizimium, polyalkylenethiazinium, polyalkylenemorpholinium, polyalkylenepiperidinium, polyalkylenepiperizinium, polyalkylenepyrollizinium, polyalkylenetriphenylphosphonium, polyalkylenetrimethylphosphonium, polyalkylenetriethylphosphonium, polyalkylenetripropylphosphonium, polyalkylenetributylphosphonium, polyalkylenetrichlorophosphonium, polyalkylenetrifluorophosphonium, and polyalkylenediazolium.

19. The method of claim 1, wherein the polymer further comprises hydrophobic monomers connected to form the polymeric backbone, wherein each hydrophobic monomer comprises a hydrophobic group, wherein the hydrophobic group at each occurrence is independently selected from the group consisting of an unsubstituted or substituted alkyl, an unsubstituted or substituted cycloalkyl, an unsubstituted or substituted aryl, and an unsubstituted or substituted heteroaryl.

20. The method of claim 1, further comprising pretreating the biomass before contacting the biomass with the polymer.

21. The method of claim 20, wherein the pretreatment of the biomass is selected from the group consisting of washing, solvent-extraction, solvent-swelling, comminution, milling, steam pretreatment, explosive steam pretreatment, dilute acid pretreatment, hot water pretreatment, alkaline pretreatment, lime pretreatment, wet oxidation, wet explosion, ammonia fiber explosion, organosolvent pretreatment, biological pretreatment, ammonia percolation, ultrasound, electroporation, microwave, supercritical CO₂, supercritical H₂O, ozone, gamma irradiation, and any combination thereof.

22. The method of claim 1, wherein the one or more sugars are one or more monosaccharides, one or more oligosaccharides, or a mixture thereof.

23. The method of claim 22, wherein the one or more sugars are selected from the group consisting of glucose, galactose, fructose, xylose, and arabinose.

24. The method of claim 1, wherein the residual biomass has a degree of polymerization of less than 300.

25. The method of claim 1, wherein the degrading of the biomass to produce the sugars occurs at a first-order rate constant of at least 0.001 per hour.