Saturated color organic light emitting devices

• US 8,476,822 B2
• Filed: 10/24/2008
• Issued: 07/02/2013
• Est. Priority Date: 11/09/2007
• Status: Active Grant

• Current Assignee: Universal Display Corporation
• Original Assignee: Universal Display Corporation
• Inventors: D'Andrade, Brian
• Primary Examiner(s): Patel, Nimeshkumar
• Assistant Examiner(s): RALEIGH, DONALD L
• Application Number:
  US12/257,648
• Publication Number:
  US 20090121621A1
• Time in Patent Office: 1,712 Days
• Field of Search: 257/40, 257/72, 257 98-100, 257642-643, 257/759, 313498-512, 313110-117, 315/169.1, 315/169.3, 427/58, 427/64, 427/66, 427532-535, 427/539, 428690-691, 428/917, 438 26- 29, 438/34, 438/82, 445 24- 25
• US Class Current: 313/504
• CPC Class Codes: H10K 2101/10 Triplet emission
• CPC Class Codes: H10K 2101/30 Highest occupied molecular orbital [HOMO], lowest unoccupied molecular orbital [LUMO] or Fermi energy values
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/18 Carrier blocking layers
• CPC Class Codes: H10K 71/10 Deposition of organic active material
• CPC Class Codes: H10K 71/311 Purifying organic semiconductor materials
• CPC Class Codes: H10K 85/342 comprising iridium
• CPC Class Codes: H10K 85/657 Polycyclic condensed heteroaromatic hydrocarbons
• CPC Class Codes: H10K 85/6572 comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole

Abstract

An organic light emitting device is provided. The device has a first electrode, a second electrode, and an emissive layer disposed between the first and second electrodes. The emissive layer includes an emissive material with an intrinsic emission spectrum having a peak emission wavelength in the visible spectrum less than 500 nm. The device includes a color saturation enhancement layer in direct contact with the first electrode. The color saturation enhancement layer consists essentially of one or more metals or conductive doped inorganic semiconductors, and has an index of refraction at least 0.2 different from that of the organic layers. The color saturation enhancement layer has a thickness of 1-10 nm. The reflectivity of the color saturation enhancement layer is in the range 5% to 30% for the peak wavelength in the intrinsic emission spectrum of the emissive material. Preferably, the color saturation enhancement layer is disposed between the first and second electrodes.

Claims

1. An organic light emitting device, comprising:

a first electrode comprising a transparent metallic oxide;

a second electrode;

at least one organic layer disposed between the first electrode and the second electrode, the at least one organic layer including an emissive layer, wherein the emissive layer includes an emissive material with an intrinsic emission spectrum having a peak emission wavelength in the visible spectrum less than 500 nm; and

a color saturation enhancement layer disposed between the first electrode and the second electrode and in direct contact with the first electrode, wherein the color saturation enhancement layer consists essentially of one or more metals or conductive doped inorganic semiconductors;

wherein the color enhancement saturation layer has an index of refraction at least 0.2 different from that of the at least one organic layer and is in direct contact with the at least one organic layer;

wherein the color saturation enhancement layer has a thickness of 1-10 nm; and

wherein the reflectivity of the color saturation enhancement layer is in the range 5% to 30% for the peak wavelength in the intrinsic emission spectrum of the emissive material.

2. The device of claim 1 wherein the first electrode is an anode and the second electrode is a cathode.

3. The device of claim 1 wherein the color enhancement saturation layer consists essentially of silver.

4. The device of claim 1 wherein the color enhancement saturation layer consists essentially of chromium.

5. The device of claim 1 wherein the color enhancement saturation layer consists essentially of aluminum.

6. The device of claim 1 wherein the color enhancement saturation layer consists essentially of cobalt.

7. The device of claim 1, wherein the second electrode comprises a transparent conductive oxide.

8. The device of claim 7, wherein the second electrode comprises indium tin oxide.

9. The device of claim 1, wherein the device has an emission spectrum with a full width half maximum that is at least 5 nm less than that of an otherwise identical device without a color saturation enhancement layer.

10. The device of claim 1, wherein the device has an emission spectrum with a full width half maximum that is at least 10 nm less than that of an otherwise identical device without a color saturation enhancement layer.

11. The device of claim 1, wherein the device has an emission spectrum with a full width half maximum that is at least 12 nm less than that of an otherwise identical device without a color saturation enhancement layer.

12. The device of claim 1, wherein the peak wavelength of the light emitted by the device at all angles between zero and sixty degrees does not deviate by more than 1.5% from the peak wavelength emitted at an angle of zero degrees.

13. The device of claim 1, wherein the peak wavelength of the light emitted by the device at all angles between zero and sixty degrees does not deviate by more than 1.0% from the peak wavelength emitted at an angle of zero degrees.

14. The device of claim 1, wherein the peak wavelength of the light emitted by the device at all angles between zero and sixty degrees does not deviate by more than 0.5% from the peak wavelength emitted at an angle of zero degrees.

15. The device of claim 9, wherein the peak wavelength of the light emitted by the device at all angles between zero and sixty degrees does not deviate by more than 1.5% from the peak wavelength emitted at an angle of zero degrees.

16. The device of claim 1, wherein the CIE coordinate of the light emitted by the emissive layer observed at an angle of zero is not more than 0.01, 0.03 different from the CIE coordinate of the emitted light at an angle of 60 degrees.

17. The device of claim 1, wherein the intensity of light emitted by the device is less than 20% different from Lambertian emission at all angles from zero to sixty degrees.

18. The device of claim 1, wherein the intensity of light emitted by the device is less than 15% different from Lambertian emission at all angles from zero to sixty degrees.

19. An organic light emitting device, comprising:

a first electrode comprising a transparent metallic oxide;

a second electrode;

an emissive layer disposed between the first electrode and the second electrode, wherein the emissive layer includes an emissive material with an intrinsic emission spectrum having a peak emission wavelength in the visible spectrum less than 500 nm; and

a color saturation enhancement layer in direct contact with the first electrode, wherein the color saturation enhancement layer consists essentially of one or more metals or conductive doped inorganic semiconductors;

wherein the color enhancement saturation layer has an index of refraction at least 0.2 different from that of the first electrode and is disposed between the first electrode and the second electrode and in direct contact with the emissive layer;

wherein the color saturation enhancement layer has a thickness of 1-10 nm; and

wherein the reflectivity of the color saturation enhancement layer is in the range 5% to 30% for the peak wavelength in the intrinsic emission spectrum of the emissive material.