Polymer compositions

• US 8,481,640 B2
• Filed: 04/30/2008
• Issued: 07/09/2013
• Est. Priority Date: 05/01/2007
• Status: Expired due to Fees

• Current Assignee: Dow Silicones Corporation (Dow, Inc.)
• Original Assignee: Dow, Inc.
• Inventors: Gough, Helen L., O'Hare, Sarah, MacKinnon, Iain A., Durand, Geraldine
• Primary Examiner(s): Loewe, Robert S
• Application Number:
  US12/597,788
• Publication Number:
  US 20100168325A1
• Time in Patent Office: 1,896 Days
• Field of Search: None
• US Class Current: 524/588
• CPC Class Codes: C08G 77/46 containing polyether sequences
• CPC Class Codes: C08K 5/54 Silicon-containing compounds C08K5/0091 takes precedence
• CPC Class Codes: C08L 2666/44 Silicon-containing compounds
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: C08L 83/12 containing polyether sequences

Abstract

The invention relates to a water-insoluble hydrophilic polymer network comprising polyorganosiloxane polyoxyalkylene block copolymer moieties characterized that they are linked to each other through an organosilicon cross-linking moiety, provided that the cross-linking moiety forming the links between polyorganosiloxane polyoxyalkylene block copolymer moieties result from an addition reaction between cross-linking sites present on the polyorganosiloxane polyoxyalkylene block copolymer moieties prior to formation of the hydrophilic polymer network, selected from silicon-bonded hydrogen atoms and aliphatically unsaturated groups, and reactive groups present on the cross-linking moiety prior to formation of the hydrophilic polymer network. Also disclosed is a process for making the polymer network, and a curable composition able to be reacted into such polymer network.

Claims

1. A water-insoluble hydrophilic polymer network comprising polyorganosiloxane polyoxyalkylene block copolymer moieties of the form PS-(A-PO)_m-(A-PS)_n or PS-(A-PO-A-PS)_n wherein PS represents a polyorganosiloxane block with a degree of polymerization of 10 to 30, PO represents a polyoxyethylene block with a degree of polymerization of from 4 to 40 oxyethylene units, A represents a divalent radical and m and n have a value of at least 1, wherein the sum of the degree of polymerization of the polyorgansiloxane blocks and the degree of polymerization of the polyoxyethylene block in the block copolymer are each in the range 15 to 35, wherein at least three polysiloxane polyoxyalkylene block copolymer moieties are linked to each other through an organosilicon cross-linking moiety selected from a branched siloxane comprising one or more Q units of the formula (SiO_4/2), from 0 to 250 D units of the formula R^b₂SiO_2/2 and M units of the formula R^aR^b₂SiO_1/2, wherein the R^a and R^b substituents are selected from alkyl and alkenyl groups having 1 to 6 carbon atoms, at least three R^a substituents in the branched siloxane being alkenyl units, provided that the cross-linking moiety forming the links between polyorganosiloxane polyoxyalkylene block copolymer moieties result from an addition reaction between silicon-bonded hydrogen atoms cross-linking sites present on the polyorganosiloxane polyoxyalkylene block copolymer and the alkenyl groups present on the branched siloxane prior to formation of the hydrophilic polymer network.

2. A water-insoluble hydrophilic polymer network according to claim 1 wherein the cross-linking sites of the polyorganosiloxane polyoxyalkylene block copolymer prior to formation of the network are situated on terminal silicon atoms of the terminal polyorganosiloxane blocks.

3. A water-insoluble hydrophilic polymer network according to claim 1 wherein each PS block is a polydimethylsiloxane block.

4. A water-insoluble hydrophilic polymer network according to claim 1 wherein each A group is independently selected from a divalent alkylene group and a divalent polyorganosiloxane group terminated by diorganosilylalkylene groups.

5. A water-insoluble hydrophilic polymer network according to claim 1 wherein it also contains a reinforcing filler.

6. A water-insoluble hydrophilic polymer network according to claim 1 wherein the surface becomes more hydrophilic upon wetting with water and reversibly becomes more hydrophobic on drying of the hydrophilic polymer network surface after being wetted with water, as shown by the contact angle of a water droplet on the surface of the hydrophilic polymer network decreasing with time after application of the water droplet to the surface and increasing upon drying.