Sensor including a photocatalyst

• US 8,481,987 B2
• Filed: 06/18/2010
• Issued: 07/09/2013
• Est. Priority Date: 06/18/2010
• Status: Expired due to Fees

• Current Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Original Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Inventors: Omoda, Ryo
• Primary Examiner(s): Ko, Tony
• Application Number:
  US12/993,641
• Publication Number:
  US 20110308303A1
• Time in Patent Office: 1,117 Days
• Field of Search: 250/573, 73/530.1
• US Class Current: 250/573
• CPC Class Codes: G01N 33/1806 biological or chemical oxygen demand (BOD or COD)
• CPC Class Codes: Y02W 10/37 using solar energy

Abstract

Devices and methods for degrading contaminants that may foul a sensor. A photocatalyst associated with the sensor is capable of interacting with a light source to prevent contamination of the sensor and/or to facilitate decontamination of the sensor by contaminants such as, but not limited to, organic compounds, volatile organic compounds (VOCs), organometallic compounds, soot, organic matter, bacteria, algae, eggs of aquatic organisms, planktonic larvae, and the like.

Claims

1. A water quality test device, the device comprising:

a sensor adapted for testing water quality and having a sensor body adapted for emersion in water and at least partially transparent to UV light and/or visible light;

a protective layer located on an outer surface of the sensor body and at least partially transparent to UV light and/or visible light; and

a photocatalyst located on an outer surface of the protective layer so as to be associated with the sensor.

2. The device of claim 1, wherein the sensor is adapted to detect one or more of temperature, pH, conductivity, dielectric constant, salinity, turbidity, total suspended solids (TSS), total dissolved solids (TDS), biological oxygen demand (BOD), and chemical oxygen demand (COD).

3. The device of claim 1, wherein the photocatalyst is adapted to prevent contamination of the sensor and/or to facilitate decontamination of the sensor and/or to degrade one or more of organic compounds, volatile organic compounds (VOCs), organometallic compounds, soot, organic matter, bacteria, algae, eggs of aquatic organisms, planktonic larvae, and combinations thereof.

4. The device of claim 1, wherein the photocatalyst is selected from the group consisting of TiO₂, vis-TiO₂, SnO₂/TiO₂, SnO₂/Al₂O₃, TiON, TiON/PdO, TiO₂/WO₃, Pd—

WO₃, CuO-WO₃, Pt—

WO₃, NaTaO₃, TiO_2-xN_x, and combinations thereof.

5. The device of claim 1, wherein the protective layer includes apatite.

6. The device of claim 1, wherein the photocatalyst is partially encapsulated in the protective layer.

7. The device of claim 1, further comprising a light source selected to emit UV light and/or visible light that is enclosed by the sensor body and oriented to direct light from within the sensor body to the photocatalyst outside of the sensor body.

8. The device of claim 1, wherein the sensor body includes a glass or plastic material.

9. The device of claim 1, wherein the sensor body is adapted to be submerged in water for long-term monitoring of water quality.

10. The device of claim 9, wherein the photocatalyst is adapted to prevent contamination of the sensor by one or more of organic matter, bacteria, algae, eggs of aquatic organisms, planktonic larvae, and combinations thereof.

11. A water quality test device, the device comprising:

a sensor adapted for testing water quality and having a sensor body adapted for emersion in water and at least partially transparent to UV light and/or visible light;

a protective layer located on an outer surface of the sensor body and at least partially transparent to UV light and/or visible light;

a photocatalyst located on an outer surface of the protective layer so as to be associated with the sensor; and

a light source located within the sensor and enclosed by the sensor body and oriented to emit a wavelength of light that activates the photocatalyst from within the sensor body to the photocatalyst outside of the sensor body.

12. The device of claim 11, wherein the sensor is adapted to detect one or more of temperature, pH, conductivity, salinity, turbidity, total suspended solids (TSS), total dissolved solids (TDS), biological oxygen demand (BOD), and chemical oxygen demand (COD).

13. The device of claim 11, wherein the photocatalyst is adapted to prevent contamination of the sensor and/or to facilitate decontamination of the sensor and/or to degrade one or more of organic compounds, volatile organic compounds (VOCs), organometallic compounds, soot, organic matter, bacteria, algae, eggs of aquatic organisms, planktonic larvae, and combinations thereof.

14. The device of claim 11, wherein the photocatalyst is selected from the group consisting of TiO₂, vis-TiO₂, SnO₂/TiO₂, SnO₂/Al₂O₃, TiON, TiON/PdO, TiO₂/WO₃, Pd—

WO₃, CuO-WO₃, Pt—

WO₃, NaTaO₃, TiO_2-xN_x, and combinations thereof.

15. The device of claim 11, wherein the sensor body is adapted to be submerged in water for long-term monitoring of water quality.

16. The device of claim 15, wherein the photocatalyst is adapted to prevent contamination of the sensor portion and/or to facilitate decontamination of the sensor caused by one or more of organic matter, bacteria, algae, eggs of aquatic organisms, planktonic larvae, and combinations thereof.

17. A method for water quality testing, the method comprising:

providing a sensor adapted for testing water quality, the sensor comprising;

a sensor body adapted for emersion in water and at least partially transparent to UV light and/or visible light;

a protective layer located on an outer surface of the sensor body and at least partially transparent to UV light and/or visible light; and

a photocatalyst located on an outer surface of the protective layer so as to be associated with the sensor;

inserting the sensor body, protective layer, and photocatalyst into water to be tested for water quality; and

activating the photocatalyst with a light source to prevent contamination of the sensor and/or to decontaminate the sensor.

18. The method of claim 17, comprising detecting one or more of temperature, pH, conductivity, salinity, turbidity, total suspended solids (TSS), total dissolved solids (TDS), biological oxygen demand (BOD), and chemical oxygen demand (COD).

19. The method of claim 17, further comprising the sensor having the light source enclosed by the sensor body and oriented to emit a wavelength of light that activates the photocatalyst from within the sensor body to the photocatalyst outside of the sensor body.

20. The method of claim 17, further comprising submerging the sensor body in water for long-term monitoring of water quality and inhibiting contamination of the sensor body by one or more of organic matter, bacteria, algae, eggs of aquatic organisms, planktonic larvae, and combinations thereof.