In situ recovery from a hydrocarbon containing formation

• US 8,485,252 B2
• Filed: 07/11/2012
• Issued: 07/16/2013
• Est. Priority Date: 04/24/2000
• Status: Expired due to Fees

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: de Rouffignac, Eric Pierre, Berchenko, Ilya Emil, Fowler, Thomas David, Ryan, Robert Charles, Shahin, Gordon Thomas Jr., Stegemeier, George Leo, Vinegar, Harold J., Wellington, Scott Lee, Zhang, Etuan
• Primary Examiner(s): SUCHFIELD, GEORGE A
• Application Number:
  US13/546,404
• Publication Number:
  US 20130008660A1
• Time in Patent Office: 370 Days
• Field of Search: None
• US Class Current: 166/250.01
• CPC Class Codes: C09K 8/592 Compositions used in combination with generated heat, e.g. by steam injection
• CPC Class Codes: E21B 36/001 Cooling arrangements
• CPC Class Codes: E21B 36/04 using electrical heaters
• CPC Class Codes: E21B 41/0057 Disposal of a fluid by injection into a subterranean formation
• CPC Class Codes: E21B 43/24 using heat, e.g. steam injection
• CPC Class Codes: E21B 43/2401 by means of electricity
• CPC Class Codes: E21B 43/243 Combustion in situ
• CPC Class Codes: E21B 43/247 in association with fracturing processes or crevice forming processes
• CPC Class Codes: E21B 43/30 Specific pattern of wells, e.g. optimising the spacing of wells
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02P 20/582 Recycling of unreacted starting or intermediate materials
• CPC Class Codes: Y10S 48/06 Underground gasification of coal

Abstract

An oil shale formation may be treated using an in situ thermal process. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. Heat input into the formation may be controlled to raise the temperature of portion at a selected rate during pyrolysis of hydrocarbons within the formation. A mixture of hydrocarbons, H₂, and/or other formation fluids may be produced from the formation.

Claims

1. A method of treating a hydrocarbon containing formation in situ, comprising:

providing heat from one or more heaters to at least a portion of the formation;

allowing the heat to transfer from the one or more heaters to a part of the formation, wherein one or more of the heaters comprise at least two heaters, and wherein superposition of heat from at least the two heaters mobilizes at least some hydrocarbons within the part of the formation;

maintaining a pressure within at least a majority of the part of the formation above about 2.0 bar absolute; and

producing a fluid from the formation comprising condensable hydrocarbons, wherein the condensable hydrocarbons within the fluid comprise an atomic hydrogen to atomic carbon ratio of greater than about 1.75.

2. The method of claim 1, wherein the superposition of heat from at least the two heaters pyrolyzes at least some hydrocarbons within the part of the formation.

3. The method of claim 1, further comprising maintaining a temperature within the part within a pyrolysis temperature range.

4. The method of claim 1, further comprising controlling the pressure and a temperature within at least a majority of the part of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.

5. The method of claim 1, further comprising controlling the heat such that an average heating rate of the part is less than about 1°

C. per day during pyrolysis.

6. The method of claim 1, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.

7. The method of claim 1, wherein providing heat from one or more of the heaters comprises heating the part of the formation such that a thermal conductivity of at least a portion of the part of the formation is greater than about 0.5 W/(m °

C.).

8. The method of claim 1, wherein at least a portion of the fluid comprises pyrolyzed hydrocarbons.

9. The method of claim 1, wherein the condensable hydrocarbons have an API gravity of at least about 25°

.

10. The method of claim 1, wherein about 0.1% by weight to about 15% by weight of the condensable hydrocarbons are olefins.

11. The method of claim 1, wherein the produced fluid comprises non-condensable hydrocarbons, and wherein about 0.1% by weight to about 15% by weight of the non-condensable hydrocarbons are olefins.

12. The method of claim 1, wherein greater than about 20% by weight of the condensable hydrocarbons are aromatic compounds.

13. The method of claim 1, wherein less than about 0.3% by weight of the condensable hydrocarbons are asphaltenes.

14. The method of claim 1, wherein the produced fluid comprises a non-condensable component, wherein the non-condensable component comprises molecular hydrogen, wherein the molecular hydrogen is greater than about 10% by volume of the non-condensable component, and wherein the molecular hydrogen is less than about 80% by volume of the non-condensable component.

15. The method of claim 1, wherein the pressure is maintained below about 100 bar absolute.

16. The method of claim 1, further comprising controlling formation conditions to produce the fluid with a mixture of condensable hydrocarbons and H₂, wherein a partial pressure of H₂ within the mixture is greater than about 0.5 bar.

17. The method of claim 1, further comprising controlling the pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.

18. The method of claim 1, further comprising controlling the heat to yield greater than about 60% by weight of condensable hydrocarbons, as measured by the Fischer Assay.

19. A method of treating a hydrocarbon containing formation in situ, comprising:

providing heat from one or more heaters to at least a portion of the formation;

allowing the heat to transfer from the one or more heaters to a part of the formation, wherein one or more of the heaters comprise at least two heaters, and wherein superposition of heat from at least the two heaters pyrolyzes at least some hydrocarbons within the part of the formation;

maintaining a pressure within at least a majority of the part of the formation above about 2.0 bar absolute; and

producing a fluid from the formation comprising condensable hydrocarbons, wherein the condensable hydrocarbons within the fluid comprise an atomic hydrogen to atomic carbon ratio of greater than about 1.75.

20. A method of treating a hydrocarbon containing formation in situ, comprising:

providing heat from one or more heaters to at least a portion of the formation;

allowing the heat to transfer from the one or more heaters to a part of the formation;

controlling the heat such that an average heating rate of the part is less than about 1°

C. per day during pyrolysis;

maintaining a pressure within at least a majority of the part of the formation above about 2.0 bar absolute; and

producing a fluid from the formation comprising condensable hydrocarbons, wherein the condensable hydrocarbons within the fluid comprise an atomic hydrogen to atomic carbon ratio of greater than about 1.75.