Compositions and methods for improving the compatibility of water soluble herbicide salts

• US 8,486,862 B2
• Filed: 08/23/2011
• Issued: 07/16/2013
• Est. Priority Date: 08/24/2010
• Status: Active Grant

• Current Assignee: Corteva Agriscience LLC (Corteva, Inc.)
• Original Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Inventors: Liu, Lei, Zhang, Hong, Kennedy, Alex, Tank, Holger, Li, Mei, Qin, Kuide, Ouse, David G., Wilson, Stephen L., Downer, Brandon Matthew
• Primary Examiner(s): Pryor, Alton
• Application Number:
  US13/215,748
• Publication Number:
  US 20120053056A1
• Time in Patent Office: 693 Days
• Field of Search: None
• US Class Current: 504/127
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/02 containing liquids as carriers, diluents or solvents
• CPC Class Codes: A01N 25/30 characterised by the surfactants
• CPC Class Codes: A01N 39/04 Aryloxy-acetic acids; Derivatives thereof
• CPC Class Codes: A01N 57/20 containing acyclic or cycloaliphatic radicals

Abstract

The compatibility of aqueous herbicide solutions containing water soluble salts of 2,4-D and glyphosate in the presence of inorganic cations is improved by the addition of polyethylenimine or polyvinylamine crystallization inhibitors.

Claims

1. A method of improving the compatibility of aqueous herbicide solutions containing a water soluble salt of 2,4-D and a water soluble salt of glyphosate, wherein the solutions contain one or more inorganic cations selected from the group consisting of NH₄⁺, Na⁺, K⁺, Ca²⁺, Mg²⁺, Fe²⁺, Fe³⁺, Cu²⁺, Mn²⁺ and Zn²⁺, which comprises adding to the aqueous herbicide solution one or more polyethylenimine or polyvinylamine crystallization inhibitors, wherein the pH of the aqueous herbicide solution is below or about 6.5, the weight percent ratio of 2,4-D to glyphosate on an acid equivalent basis is from about 16:

1 to about 1;

16, and the crystallization inhibitor is added in an amount sufficient to improve compatibility and reduce the amount of solids formed.

2. An aqueous herbicide solution of improved compatibility containing one or more inorganic cations selected from the group consisting of NH₄⁺, Na⁺, K⁺, Ca²⁺, Mg²⁺, Fe²⁺, Fe³⁺, Cu²⁺, Mn²⁺ and Zn²⁺ comprising water soluble salts of both 2,4-D and glyphosate, and one or more polyethylenimine or polyvinylamine crystallization inhibitor, wherein the pH of the aqueous herbicide solution is below or about 6.5, the weight percent ratio of 2,4-D to glyphosate on an acid equivalent basis is from about 16:

1 to about 1;

16, and the crystallization inhibitor is added in an amount sufficient to improve compatibility and reduce the amount of solids formed.

3. The aqueous herbicide solution of claim 2 which is a concentrate.

4. The aqueous herbicide concentrate of claim 3 in which the polyethylenimine or polyvinylamine crystallization inhibitor is from about 0.05 to about 10 weight percent of the concentrate.

5. The aqueous herbicide solution of claim 2 which is a spray solution.

6. The aqueous herbicide spray solution of claim 5 in which the polyethylenimine or polyvinylamine crystal inhibitor is from about 0.001 to about 5 weight percent of the spray isolation.

7. The aqueous herbicide solution of claim 2 in which the weight percent ratio of 2,4-D to glyphosate on an acid equivalent basis is from about 10:

1 to about 1;

1.

8. The aqueous herbicide solution of claim 2 in which the weight percent ratio of 2,4-D to glyphosate on an acid equivalent basis is from about 1:

1 to about 1;

16.

9. A dry herbicide composition comprising one or more polyethylenimine or polyvinylamine crystallization inhibitors, a water soluble salt of 2,4-D or glyphosate, or and a mixture of water soluble salts of 2,4-D and glyphosate, wherein the dry herbicide composition is added to an aqueous herbicidal solution with a pH below or about 6.5, the weight percent ratio of 2,4-D to glyphosate on an acid equivalent basis in the aqueous herbicidal solution is from about 16:

1 to about 1;

16, and the one or more crystallization inhibitors are added in an amount sufficient to improve compatibility and reduce the amount of solids formed in the aqueous herbicidal solution.

10. The dry herbicide composition of claim 9 in which the polyethylenimine or polyvinylamine crystallization inhibitor is from about 0.05 to about 10 weight percent of the composition.