Thermosetting polymer-based composite materials

• US 8,487,029 B2
• Filed: 01/22/2009
• Issued: 07/16/2013
• Est. Priority Date: 01/22/2008
• Status: Active Grant

• Current Assignee: Chemical Light Incorporated, Globe Composite Solutions LLC (ESCO Technologies, Inc.)
• Original Assignee: Globe Composite Solutions, Ltd. (ESCO Technologies, Inc.)
• Inventors: Wang, Xiujun
• Primary Examiner(s): LEE, DORIS L
• Application Number:
  US12/357,644
• Publication Number:
  US 20090198007A1
• Time in Patent Office: 1,636 Days
• Field of Search: 524/440, 524/413, 524/436, 524/423
• US Class Current: 524/423
• CPC Class Codes: C08K 2201/014 Additives containing two or more different additives of the same subgroup in C08K
• CPC Class Codes: C08K 2201/019 the composition being defined by the absence of a certain additive
• CPC Class Codes: C08K 3/08 Metals
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 3/30 Sulfur-, selenium- or tellurium-containing compounds
• CPC Class Codes: G21F 1/106 metallic dispersions

Abstract

A lead-free, non-toxic composite material including a thermosetting polymer and at least one of a heavy particulate filler, a light particulate filler or a combination thereof. The composite material may be utilized in manufacturing articles used in radiation shielding applications.

Claims

1. A lead-free, non-toxic composite material, said composite material comprising:

a thermosetting polymer;

at least one heavy particulate filler selected from a group consisting of tungsten, osmium, iridium, platinum, gold, molybdenum, tantalum, and combinations thereof, the at least one heavy particulate filler having an average particle size between 0.1 micron and 15 microns; and

at least one light particulate filler selected from the group consisting of barium sulfate, bismuth, iodine, zirconium oxide, nickel, copper, silver, titanium, titanium oxide, zinc oxide, zinc sulfide, antimony oxide, aluminum, and combinations thereof, the at least one light particulate filler having an average particle size between 0.5 micron and 15 microns

wherein the light particulate filler inhibits settling of the heavy particulate filler in the composite material, and further wherein the composite material comprises a viscosity capable of casting or liquid phase sintering.

2. A lead-free, non-toxic composite material according to claim 1, wherein said composite material comprises a heavy particulate filler and a light particulate filler, further wherein a weight ratio of said heavy particulate filler to said light particulate filler is in a range from about 1:

80 to about 99.5;

1.

3. A lead-free, non-toxic composite material according to claim 1, further comprising an additive selected from a group consisting of curatives, processing aids, functional additives, pigments and combinations thereof.

4. A lead-free, non-toxic composite material according to claim 1, wherein said thermosetting polymer is present in an amount between about 0.5% to about 50% by weight, based on the total weight of the composition.

5. A lead-free, non-toxic composite material according to claim 4, wherein said thermosetting polymer is present in an amount between about 10% to about 30% by weight, based on the total weight of the composition.

6. A lead-free, non-toxic composite material according to claim 1, wherein said heavy particulate filler is tungsten.

7. A lead-free, non-toxic composite material according to claim 6, wherein said tungsten is present in an amount between about 10% wt. to about 99.5% wt. based on the weight of the composition.

8. A lead-free, non-toxic composite material according to claim 1, wherein said light particulate filler is barium sulfate.

9. A lead-free, non-toxic composite material according to claim 8, wherein said barium sulfate is present in an amount between about 10% wt. to about 99.5% wt. based on the weight of the composition.

10. A lead-free, non-toxic composite material according to claim 1, wherein said thermosetting polymer is selected from a group consisting of epoxy resins, urethanes, silicones, un-saturated esters and combinations thereof.

11. A lead-free, non-toxic composite material according to claim 10, wherein said thermosetting polymer is an epoxy resin.

12. A lead-free, non-toxic composite material according to claim 11, wherein said epoxy resin is in a liquid form.

13. A lead-free, non-toxic composite material according claim 11, wherein said epoxy resin is in a solid form.

14. A lead-free, non-toxic material according to claim 11, wherein the epoxy resin has a viscosity between 110 poise to 150 poise at ambient temperature.

15. A lead-free, non-toxic article, said article comprising the lead-free, non-toxic composite material according to claim 1.

16. A lead-free, non-toxic article according to claim 15, wherein said article is a radiation-shielding device.

17. A lead-free, non-toxic article according to claim 15, wherein said article is a ballast article.

18. A lead-free, non-toxic article according to claim 15, wherein said article is an energy storage article.

19. A lead-free, non-toxic composite material, said composite material comprising:

a thermosetting polymer;

tungsten, having an average particle size between 0.1 micron and 15 microns; and

barium sulfate, having an average particle size between 0.5 micron and 15 microns,

wherein a weight ratio of the tungsten to the barium sulfate is 4;

1.