Diamond microelectrodes

• US 8,491,765 B2
• Filed: 07/25/2011
• Issued: 07/23/2013
• Est. Priority Date: 08/04/2003
• Status: Expired due to Term

• Current Assignee: Element Six (Holdings) Ltd. (Anglo American PLC)
• Original Assignee: Element Six (Holdings) Ltd. (Anglo American PLC)
• Inventors: Pickles, Charles Simon James, Hall, Clive Edward, Jiang, Li, Perkins, Neil, Kleijhorst, Richard Antonius
• Primary Examiner(s): Ball, J. Christopher
• Assistant Examiner(s): DIETERLE, JENNIFER M
• Application Number:
  US13/190,090
• Publication Number:
  US 20120037505A1
• Time in Patent Office: 729 Days
• Field of Search: 204/400, 204/415, 204/416, 204/418, 204/294, 204/409, 204/433, 204/412, 204/280
• US Class Current: 204/400
• CPC Class Codes: G01N 27/308 at least partially made of carbon

Abstract

A microlectrode comprising a diamond layer formed from electrically non-conducting diamond and containing one or more pins or projections of electrically conducting diamond extending at least partially through the layer of non-conducting diamond presenting areas of electrically conducting diamond.

Claims

1. A microelectrode comprising:

a non-conducting layer formed from electrically non-conducting material presenting a planar surface;

one or more projections of electrically conducting diamond extending at least partially through the non-conducting layer, the one or more projections presenting one or more planar areas of electrically conducting diamond;

the one or more projections extend to the planar surface of the non-conducting layer presenting one or more planar areas of electrically conducting diamond co-planar with the planar surface of the electrically non-conducting material; and

an electrical contact or contacts positioned directly on a back side of the one or more projections of electrically conducting diamond for connection to an external circuit,

wherein the surface roughness of the one or more planar areas of the electrically conducting diamond is less than 15 nm.

2. A microelectrode according to claim 1, wherein the one or more projections of electrically conducting diamond present circular areas of electrically conducting diamond.

3. A microelectrode according to claim 1, wherein the one or more projections of electrically conducting diamond present elongate areas of electrically conducting diamond.

4. A microelectrode according to claim 1, wherein a plurality of projections of electrically conducting diamond are provided, each projection having a contact surface on its back side to provide individual connections between each of the projections and the external circuit.

5. A microelectrode according to claim 1, wherein the one or more projections extend to a rear surface of the non-conducting layer to provide the contact surface or surfaces for connection to the external circuit.

6. A microelectrode according to claim 1, wherein the one or more projections extend only part-way towards a rear surface of the non-conducting layer and holes are formed in the rear surface of the non-conducting layer to reveal the contact surface or surfaces on the back side of the one or more projections for connection to the external circuit.

7. A microelectrode according to claim 1, wherein the one or more projections extend to a rear surface of the non-conducting layer to provide the contact surface or surfaces for connection to the external circuit and an electrically conducting layer is provided on the rear surface of the non-conducting layer for providing an electrical connection to the one or more projections.

8. A microelectrode according to claim 1, wherein the electrically conducting diamond is boron doped diamond.

9. A microelectrode according to claim 1, wherein the one or more planar areas of electrically conducting diamond and co-planar surfaces are smooth.

10. A microelectrode according to claim 1, wherein the electrically conducting diamond is synthetic single crystal or polycrystalline diamond.

11. A microelectrode according to claim 1, wherein the non-conducting material is synthetic single crystal or polycrystalline diamond.

12. A microelectrode according to claim 1, wherein the one or more projections have one projection that has a width in a range 2 to 200 μ

m.

13. A microelectrode according to claim 1, wherein a plurality of projections of electrically conducting diamond are provided and a ratio of a separation between projections and a width of the projections exceeds 2.5, 5, or 10.

14. A microelectrode according to claim 1, wherein the one or more projections extend completely through the non-conducting layer.

15. A microelectrode according to claim 1, wherein a plurality of projections of electrically conducting diamond are provided, the projections providing two or more types for the electrode.

16. A microelectrode according to claim 15, wherein the two or more types are differentiated by one or more of:

voltage applied;

the use made of the voltage applied by the external circuit;

concentration or type of dopant in the electrically conducting diamond;

geometry or size of the types of the electrode.

17. A microelectrode comprising:

a non-conducting layer formed from electrically non-conducting material presenting a planar surface;

one or more projections of electrically conducting diamond extending at least partially through the non-conducting layer, the one or more projections presenting one or more planar areas of electrically conducting diamond;

the one or more projections extend to the planar surface of the non-conducting layer presenting one or more planar areas of electrically conducting diamond co-planar with the planar surface of the electrically non-conducting material; and

an electrical contact or contacts positioned directly on a back side of the one or more projections of electrically conducting diamond for connection to an external circuit,

wherein the one or more planar areas of electrically conducting diamond comprise polished surfaces having a surface roughness of less than 100 nm.