Titanium-based alloy

• US 8,492,002 B2
• Filed: 09/23/2009
• Issued: 07/23/2013
• Est. Priority Date: 09/23/2008
• Status: Expired due to Fees

• Current Assignee: Sandvik Intellectual Property AB (Sandvik AB)
• Original Assignee: Sandvik Intellectual Property AB (Sandvik AB)
• Inventors: Norgren, Susanne
• Primary Examiner(s): Zimmerman, John J
• Application Number:
  US12/585,744
• Publication Number:
  US 20100086794A1
• Time in Patent Office: 1,399 Days
• Field of Search: None
• US Class Current: 428/472.1
• CPC Class Codes: A61L 27/06 Titanium or titanium alloys
• CPC Class Codes: A61L 31/022 Metals or alloys
• CPC Class Codes: C22C 14/00 Alloys based on titanium
• CPC Class Codes: C22F 1/183 of titanium or alloys based thereon

Abstract

An alloy having from about 5 to about 15 wt % Ta, from 0 to about 5 wt % Nb, from about 0.5 to about 15 wt % Zr, and the balance Ti is disclosed. The alloy is particularly intended for medical devices, such as implants for the body.

Claims

1. A titanium-based alloy comprising:

from 5 to 15 wt % Ta;

from 0.1 to 4 wt % Nb;

from 7 to 8 wt % Zr,

at least 65 wt % Ti; and

incidental impurities,

wherein the alloy is free of vanadium and aluminum,

wherein the alloy is an alpha+beta alloy,

wherein the content of beta-phase in the alloy is from 10 to 60 vol %, and

wherein the weight ratio Nb/Ta in the alloy is from 0.05 to 1.

2. Alloy according to claim 1, wherein the alloy comprises from 7 to 13 wt % Ta, and from 0.5 to 3 wt % Nb.

3. Alloy according to claim 1, wherein Ta is present in an amount of 10.3 wt % and Nb is present in an amount of 1.6 wt %.

4. Alloy according to claim 1, wherein the content of Ti in the alloy is at least 75 wt %.

5. Alloy according to claim 1, wherein the content of Ti in the alloy is at least 85 at %.

6. Alloy according to claim 1, wherein the hardness of the alloy, according to Vickers hardness test, is at least 250 HV3.

7. Alloy according to claim 1, wherein the surface of the alloy comprises a crystalline oxide layer.

8. Medical device composed of the alloy according to claim 1.

9. Medical device according to claim 8, which is an implant for the human or animal body.

10. Alloy according to claim 1, wherein a sum of Ta, Nb and Zr in the alloy is up to 25 wt %.

11. Alloy according to claim 10, wherein a sum of Ta, Nb and Zr in the alloy is up to 20 wt %.

12. Method for preparing an alloy comprising from 5 to 15 wt % Ta, from 0.1 to 4 wt % Nb, from 7 to 8 wt % Zr, at least 65 wt % Ti and incidental impurities, comprising melting together the elements Ti, Ta, Zr, and Nb, followed by cooling to solidify the alloy formed,

wherein the alloy is free of vanadium and aluminum,

wherein the alloy is an alpha+beta alloy,

wherein the content of beta-phase in the alloy is from 10 to 60 vol %, and

wherein the weight ratio Nb/Ta in the alloy is from 0.05 to 1.

13. Method according to claim 12, wherein the alloy comprises about 10.3 wt % Ta, and about 1.6 wt % Nb.

14. Method according to claim 12, wherein the content of Ti in the alloy is at least 75 wt %.

15. Method according to claim 12, wherein the content of Ti in the alloy is at least 85 at %.

16. Method according to claim 12, wherein the hardness of the alloy, according to Vickers hardness test, is at least about 250 HV3.

17. Method according to claim 12, further comprising heat treatment of the solidified alloy, comprising heating the alloy to a temperature of from about 500 to about 1000°

C., the duration of the heat treatment is at least about 0.25 hour, whereafter the alloy is rapidly cooled down at a rate of at least about 5°

C./min until room temperature is reached.

18. Method according to claim 12, further comprising oxidising the surface of the alloy.