Cleaning in membrane filtration systems

• US 8,496,828 B2
• Filed: 12/19/2005
• Issued: 07/30/2013
• Est. Priority Date: 12/24/2004
• Status: Expired due to Fees

• Current Assignee: Evoqua Water Technologies LLC (Xylem, Inc.)
• Original Assignee: Siemens Industry Incorporated (Siemens AG)
• Inventors: Johnson, Warren Thomas, Beck, Thomas William, Yeo, Rebecca
• Primary Examiner(s): ZALASKY, KATHERINE M
• Application Number:
  US11/722,411
• Publication Number:
  US 20080203016A1
• Time in Patent Office: 2,780 Days
• Field of Search: 210/636
• US Class Current: 210/636
• CPC Class Codes: B01D 2315/06 Submerged-type; Immersion type
• CPC Class Codes: B01D 2321/16 Use of chemical agents
• CPC Class Codes: B01D 2321/162 Use of acids
• CPC Class Codes: B01D 2321/164 Use of bases
• CPC Class Codes: B01D 2321/168 Use of other chemical agents
• CPC Class Codes: B01D 63/02 Hollow fibre modules
• CPC Class Codes: B01D 65/02 Membrane cleaning or sterilisation ; Membrane regeneration
• CPC Class Codes: C02F 1/444 by ultrafiltration or microfiltration

Abstract

A method of cleaning permeable, hollow membranes is disclosed. In one embodiment, the membranes are immersed in a liquid suspension. A pressure differential is applied across the walls of the membranes. During filtration, liquid suspension passes through the walls of the membranes to be drawn off as permeate, and at least some solids are retained on or in the membranes. The steps of cleaning include: applying a cleaning solution to one side of the membrane walls; applying a pressure differential across the membrane walls to cause flow of the cleaning solution through the walls from the one side of the membrane walls to the other side of the membrane walls; and, applying a reverse pressure differential across the membrane walls to cause flow of the cleaning solution through the wall from the other side of the membrane walls back to the one side of the membrane walls.

Claims

1. A method of cleaning a permeable, hollow membrane, the permeable, hollow membrane comprising a wall, a filtrate side, and an outer side, the method comprising:

removing liquid from the filtrate side of the membrane;

removing liquid from the outer side of the membrane;

applying a chemical cleaning solution to the outer side of the membrane;

creating a pressure differential across the membrane wall to flow the chemical cleaning solution through the membrane wall from the outer side of the membrane into the filtrate side to at least partially fill the filtrate side with the chemical cleaning solution;

isolating the outer side of the membrane;

applying a pressurized gas to the filtrate side to flow the chemical cleaning solution back to the outer side through the membrane wall;

accumulating an increased pressure developed on the outer side of the membrane as a result of the flow of the chemical cleaning solution; and

venting the pressurized gas applied from the filtrate side of the membrane to atmosphere to flow the chemical cleaning solution through the membrane wall from the outer side to the filtrate side under the effect of the accumulated pressure on the outer side of the membrane.

2. The method according to claim 1, wherein applying the pressurized gas to the filtrate side comprises substantially draining the filtrate side of the chemical cleaning solution.

3. The method of claim 1, wherein accumulating the increased pressure comprises accumulating the increased pressure in a gas space provided on the outer side of the membrane.

4. The method of claim 1, wherein accumulating the increased pressure comprises accumulating the increased pressure in a bladder arrangement.

5. The method of claim 1, wherein creating the pressure differential comprises applying gas pressure to the outer side of the membrane.

6. The method of claim 1, wherein creating the pressure differential comprises applying a vacuum to the filtrate side.

7. The method of claim 1, wherein the chemical cleaning solution comprises an oxidizing solution.

8. The method of claim 7, wherein the chemical cleaning solution comprises chlorine.

9. A method of cleaning a permeable, hollow membrane, the permeable, hollow membrane comprising a wall, a one side, and an other side, the method comprising:

applying a chemical cleaning solution comprising at least one of an acid, a caustic solution, and an oxidizing solution to the one side of the membrane;

creating a pressure differential across the membrane wall to flow the chemical cleaning solution though the membrane wall from the one side of the membrane to the other side of the membrane;

creating a reverse pressure differential across the membrane wall to flow the chemical cleaning solution through the membrane wall from the other side of the membrane back to the one side of the membrane;

accumulating an increased pressure developed on the one side of the membrane as a result of the flow of the chemical cleaning solution through the membrane wall from the other side of the membrane back to the one side of the membrane; and

venting the other side of the membrane to atmosphere from the other side of the membrane to flow the chemical cleaning solution through the membrane wall from the one side of the membrane back to the other side of the membrane under the effect of the accumulated pressure on the one side of the membrane.

10. The method of claim 9, wherein creating the pressure differential comprises applying gas pressure to the one side of the membrane.

11. The method of claim 9, wherein creating the pressure differential comprises applying a vacuum to the other side of the membrane.

12. The method of claim 9, wherein creating the reverse pressure differential comprises applying gas pressure to the other side of the membrane.

13. The method of claim 9, wherein creating the reverse pressure differential comprises applying a vacuum to the one side of the membrane.

14. The method of claim 9, wherein the chemical cleaning solution comprises citric acid.

15. The method of claim 9, wherein the chemical cleaning solution comprises chlorine.

16. A method of cleaning a permeable, hollow membrane, the permeable, hollow membrane comprising a wall, a filtrate side, and an outer side, the method comprising:

removing liquid from the filtrate side of the membrane;

removing liquid from the outer side of the membrane;

applying a chemical cleaning solution comprising at least one of an acid, a caustic solution, and an oxidizing solution to the outer side of the membrane;

creating a pressure differential across the membrane wall to flow the chemical cleaning solution though the wall from the outer side of the membrane into the filtrate side of the membrane to at least partially fill the filtrate side with the chemical cleaning solution;

creating a reverse pressure differential across the membrane wall to flow the chemical cleaning solution through the wall from the filtrate side of the membrane back to the outer side of the membrane;

accumulating an increased pressure developed on the outer side of the membrane as a result of the flow of the chemical cleaning solution through the membrane wall from the filtrate side of the membrane back to the outer side of the membrane; and

venting the filtrate side of the membrane to atmosphere from the filtrate side of the membrane to flow the chemical cleaning solution through the membrane wall from the outer side back to the filtrate side under the effect of the accumulated pressure on the outer side of the membrane.

17. The method of claim 16, wherein creating the reverse pressure differential comprises applying a pressurized gas to the filtrate side of the membrane.

18. The method of claim 16, wherein the steps of the cleaning method are repeated in cycles such that the chemical cleaning solution is alternately moved from a first side of the membrane to a second side of the membrane through the membrane wall.

19. The method of claim 16, wherein the chemical cleaning solution comprises citric acid.

20. The method of claim 16, wherein the chemical cleaning solution comprises chlorine.