Corrosion inhibition of hypochlorite solutions

• US 8,496,853 B2
• Filed: 06/12/2012
• Issued: 07/30/2013
• Est. Priority Date: 12/21/2010
• Status: Active Grant

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Inventors: Olson, Erik C., Smith, Kim R., Lentsch, Steven E.
• Primary Examiner(s): ANTHONY, JOSEPH DAVID
• Application Number:
  US13/494,105
• Publication Number:
  US 20120241679A1
• Time in Patent Office: 413 Days
• Field of Search: 422/7, 252/389.52, 252/389.61, 252/389.62, 252/396, 252/400.52, 252/400.61, 252/400.62, 252/407, 252/187.24, 252/187.25, 252/187.26, 252/187.27, 252/187.28, 252/187.29, 252/187.3
• US Class Current: 252/389.52
• CPC Class Codes: C01B 11/06 Hypochlorites
• CPC Class Codes: C23F 11/124 Carboxylic acids
• CPC Class Codes: C23F 11/18 using inorganic inhibitors

Abstract

Corrosion inhibitor compositions and methods of use are disclosed. Zinc and calcium corrosion inhibitors combined with hypochlorite sources provide use solutions for effective corrosion inhibition for metal surfaces.

Claims

1. A corrosion inhibitor composition comprising:

a hypochlorite source, which is free of carbonate and bicarbonate anions;

a corrosion inhibitor comprising a water soluble zinc compound and a water soluble calcium compound;

wherein said corrosion inhibitor does not contain bromide, iodide, aluminum or magnesium;

wherein the ratio of said hypochlorite source to corrosion inhibitor is from about 10;

1 to about 600;

1; and

wherein the pH of said composition is at least about 7.

2. The composition according to claim 1, wherein said hypochlorite source is a solution of members selected from the group consisting of sodium hypochlorite, sodium chloride, sodium hydroxide and combinations thereof.

3. The composition according to claim 1, wherein said corrosion inhibitor is a water soluble zinc salt and a water soluble calcium salt, wherein said salts have a chloride or non-halide anion.

4. The composition according to claim 1, wherein the ratio of said zinc salt to said calcium salt is from about 6:

1 to about 1;

6.

5. The composition according to claim 3, wherein said zinc salt is zinc chloride or zinc sulfate and said calcium salt is calcium chloride or calcium sulfate.

6. The composition according to claim 1, wherein said corrosion inhibitor is an EPA approved inert material for antimicrobial formulations and does not adversely impact the stability of the hypochlorite source.

7. The composition according to claim 1, wherein said corrosion inhibitor composition has a neutral or alkaline pH.

8. A corrosion inhibitor composition comprising:

a hypochlorite source comprising sodium hypochlorite, sodium chloride and sodium hydroxide, wherein said hypochlorite source is free of carbonate and bicarbonate anions; and

about 0.01 to about 2 wt-% corrosion inhibitor comprising a water soluble zinc salt and a water soluble calcium salt, wherein said corrosion inhibitor does not contain bromide, iodide, aluminum or magnesium, the pH of said composition is at least about 7, the ratio of said hypochlorite source to corrosion inhibitor is from about 50;

1 to about 200;

1 and the ratio of said zinc salt to said calcium salt is from about 6;

1 to about 1;

6.

9. The composition according to claim 8, wherein the ratio of said zinc salt to said calcium salt is from about 4:

1 to about 1;

4.

10. The composition according to claim 8, wherein said corrosion inhibitor is an EPA approved inert material for antimicrobial formulations and does not adversely impact the stability of the hypochlorite source.

11. The composition according to claim 8, wherein said corrosion inhibitor composition has a pH of at least 9.