System and method for carbon dioxide capture and sequestration

• US 8,500,855 B2
• Filed: 04/29/2011
• Issued: 08/06/2013
• Est. Priority Date: 04/30/2010
• Status: Active Grant

• Current Assignee: Global Thermostat Operations LLC
• Original Assignee: Graciela Chichilnisky
• Inventors: Eisenberger, Peter
• Primary Examiner(s): Jones, Christopher P
• Application Number:
  US13/098,370
• Publication Number:
  US 20110296872A1
• Time in Patent Office: 830 Days
• Field of Search: 951/07, 951/39, 961/26, 961/46
• US Class Current: 95/139
• CPC Class Codes: B01D 2251/304 of sodium
• CPC Class Codes: B01D 2251/604 Hydroxides
• CPC Class Codes: B01D 2252/204 Amines
• CPC Class Codes: B01D 2253/104 Alumina
• CPC Class Codes: B01D 2253/106 Silica or silicates
• CPC Class Codes: B01D 2253/20 Organic adsorbents
• CPC Class Codes: B01D 2253/25 Coated, impregnated or composite adsorbents
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2258/06 Polluted air
• CPC Class Codes: B01D 2259/4009 using hot gas
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/0462 Temperature swing adsorption
• CPC Class Codes: B01D 53/08 according to the "moving bed" method
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/81 Solid phase processes
• CPC Class Codes: B01D 53/82 with stationary reactants
• CPC Class Codes: B01D 53/83 with moving reactants
• CPC Class Codes: B01D 53/96 Regeneration, reactivation or recycling of reactants
• CPC Class Codes: B01J 20/08 comprising aluminium oxide or hydroxide; comprising bauxite
• CPC Class Codes: B01J 20/103 comprising silica
• CPC Class Codes: B01J 20/22 : comprising organic material
• CPC Class Codes: B01J 20/262 : obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds per se C08G
• CPC Class Codes: B01J 20/28016 : Particle form
• CPC Class Codes: B01J 20/28042 : Shaped bodies; Monolithic structures
• CPC Class Codes: B01J 20/28097 : being coated, filled or plugged with specific compounds
• CPC Class Codes: B01J 20/3425 : of sorbents or filter aids comprising organic materials
• CPC Class Codes: B01J 20/3466 : with steam
• CPC Class Codes: F01N 3/0857 : Carbon oxides
• CPC Class Codes: Y02A 50/20 : Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02C 20/40 : of CO2
• CPC Class Codes: Y02P 20/151 : Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

A method and a system to remove relatively pure carbon dioxide directly from ambient air. The method comprises generating process heat, to co-generate substantially saturated steam; alternately and repeatedly exposing a sorbent to a flow of ambient air, at substantially ambient conditions, to sorb, and therefore remove, carbon dioxide from said ambient air, and exposing the CO₂-laden sorbent to a flow of the co-generated steam, at a temperature in the range of not greater than about 130° C, to release the carbon dioxide, thereby regenerating the sorbent, and capturing relatively pure carbon dioxide. To render this process more efficient, admix with the air a minor amount of a pre-treated effluent gas containing a higher concentration of carbon dioxide than in the atmosphere. The captured carbon dioxide can be stored for further use, or sequestered permanently. The purified carbon dioxide is useful for agriculture or chemical processes.

Claims

1. A method of removing and concentrating carbon dioxide from carbon dioxide laden air, the method comprising

mixing ambient air with a minor proportion of a carbon dioxide-containing effluent gas,

directing a flow of carbon dioxide-laden air through a carbon dioxide capture structure comprising a sorbent capable of adsorbing, or releasably binding, carbon dioxide to remove carbon dioxide from the air, the sorbent being held on the surfaces of a porous solid mass, so that the carbon dioxide is adsorbed, or bound, to the sorbent on the surfaces of the solid mass,

directing process heat at the carbon dioxide-containing capture structure to separate carbon dioxide from the sorbent as a more concentrated form of CO2, and to regenerate the sorbent;

directing another flow of carbon dioxide-laden air through the regenerated carbon dioxide capture structure so that the regenerated sorbent can adsorb or bind additional carbon dioxide, to remove the additional carbon dioxide from the flow of additional carbon dioxide laden air,

wherein the flow of carbon dioxide-laden air is directed through a removal chamber and the process heat is directed at the carbon dioxide-containing capture structure in a regeneration chamber; and

the method further comprising alternatively moving the carbon dioxide-containing capture structure between the removal chamber and the regeneration chamber.

2. The method of claim 1, wherein the carbon dioxide-containing capture structure is moved vertically between the removal chamber and the regeneration chamber, the regeneration chamber being sealable when the carbon dioxide-containing capture structure is in the regeneration chamber.

3. The method of claim 1, wherein the air flowing into the removal chamber is at substantially ambient temperature.

4. The method of claim 1, wherein the air is mixed with not more than 25% by volume of an effluent gas.

5. The method of claim 4, wherein the air is mixed with not more than 5% by volume of an effluent gas, and where the effluent gas is a flue gas from the combustion of hydrocarbons.

6. The method of claim 1, wherein the carbon dioxide-containing capture structure in the regeneration chamber is initially purged of air before the process heat is directed at the carbon dioxide-containing capture structure.

7. The method of claim 6, wherein after regeneration of the carbon dioxide-containing capture structure, the capture structure is cooled before returning to the removal chamber.

8. The method of claim 1, wherein the process heat is directed at the carbon dioxide-containing capture structure in the form of saturated steam at a temperature in the range of up to 130°

C.

9. The method of claim 8, wherein the saturated steam is at a temperature in the range of from about 105°

C. to 120°

C.

10. The method of claim 1, wherein the concentration of CO₂ in the air exiting the removal chamber after passing through the capture structure is measured to determine when to move the capture structure out of the removal chamber and to the regeneration chamber.

11. The method of claim 10, wherein the capture structure is moved to the regeneration chamber before the sorbent is fully saturated with CO₂.

12. The method of claim 10 wherein the concentration of CO₂ in steam exiting the regeneration chamber after passing through the capture structure is measured to determine when to move the capture structure from the regeneration chamber.

13. The method of claim 12, wherein the capture structure is moved from the regeneration chamber before all of the CO₂ is stripped from the sorbent.

14. The method of claim 1, wherein CO₂ and steam, exiting the removal chamber after passing through the capture structure, is cooled and condensed to separate the water from the CO₂ to obtain high purity CO₂.

15. The method of claim 14 further comprising the steps of

providing thermal energy to a primary production process by the combustion of a carbon-containing fuel, generating usable and process heat,

said primary process emitting one or more effluent gases of carrying away the process heat,

said effluent gases being at a temperature and containing a concentration of carbon dioxide substantially higher than the ambient air,

utilizing a portion of said process heat from the effluent gases to co-generate saturated steam,

removing undesirable components from said effluent gases to produce treated effluent gases,

blending a portion of the treated effluent gases with said ambient air to create a mixture with the air containing a minor proportion of the treated effluent gases such that the concentration of carbon dioxide in said mixture is less than five percent, this method resulting in a reduction of carbon dioxide in the ambient air.

16. The method of claim 1, wherein the porous solid mass comprises a plurality of highly porous solid particles, where each particle supports the sorbent within in its pores.

17. The method of claim 16, wherein the plurality of highly porous solid particles form a moving bed, moving between a removal portion and a regeneration portion, where each particle comprises a substrate which supports the sorbent within its pores, the particle substrate comprising a ceramic material and the sorbent comprising a primary amine.

18. The method as defined in claim 17, wherein the porous solid mass comprises a monolithic polymer material formed with amine sites throughout its surfaces.

19. The method as defined in claim 1, wherein the porous solid mass comprises a highly porous monolithic substrate supporting on the surfaces of its pores the carbon dioxide sorbent to absorb or bind carbon dioxide from the fluid.

20. The method of claim 1 wherein the process heat is directed at the carbon dioxide containing capture structure in the form of superheated steam.

21. The method of claim 1 wherein the sorbent is supported on the surfaces of a porous solid mass and the process heat is directed at the carbon dioxide capture structure in the form of superheated steam at ambient pressure.