Cure rebond binder

• US 8,501,828 B2
• Filed: 08/11/2005
• Issued: 08/06/2013
• Est. Priority Date: 08/11/2004
• Status: Active Grant

• Current Assignee: Huntsman Petrochemical LLC (Huntsman Corporation)
• Original Assignee: Huntsman Petrochemical LLC (Huntsman Corporation)
• Inventors: Hennington, Roger, Ridgway, Donald H., Grigsby, Robert A. Jr., Sawitski, Robert G. Jr., Pratt, Jennifer K.
• Primary Examiner(s): COONEY, JOHN M
• Application Number:
  US11/201,886
• Publication Number:
  US 20060035990A1
• Time in Patent Office: 2,917 Days
• Field of Search: 521/54, 521/129, 521/130, 521/137, 521/159, 521/170, 521/174
• US Class Current: 521/129
• CPC Class Codes: C08G 18/10 Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
• CPC Class Codes: C08G 18/2018 having one nitrogen atom in the ring
• CPC Class Codes: C08G 18/2081 containing at least two non-condensed heterocyclic rings
• CPC Class Codes: C08G 18/302 Water
• CPC Class Codes: C08G 2110/0008 flexible
• CPC Class Codes: C08G 2110/0083 prepared using water as the sole blowing agent
• CPC Class Codes: C08G 2350/00 Acoustic or vibration damping material
• CPC Class Codes: C08J 2205/06 Flexible foams
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 2475/00 Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
• CPC Class Codes: C08J 9/35 Composite foams, i.e. continuous macromolecular foams containing discontinuous cellular particles or fragments

Abstract

The present invention provides processes for producing re-bonded polyurethane foam constructs that are useful in applications such as carpet underlayments. According to the invention, a tertiary amine is employed as a catalyst either alone, or preferably in combination with other catalysts in a binder which comprises an organic isocyanate and a polyol. Inclusion of a tertiary amine as a catalyst dramatically increases production throughput.

Claims

1. A process for producing a cured polyurethane foam article that comprises particles of one or more polyurethane foams bonded together with a binder, which process consisting of:

a) forming a mixture consisting of;

i) a plurality of particles of polyurethane foam;

ii) a prepolymer made from an organic isocyanate and a polyol;

iii) a catalyst of 2,2′

- dimorpholinodiethylether; and

iv) optionally a surfactant, an organic or silicon based extender oil, an ester, a solvent or a blowing agent; and

b) curing said mixture by contacting it with steam.

2. The process according to claim 1 which is carried out at any temperature in the range of about 0°

C. to about 400°

C.

3. The process according to claim 1 which is carried out at any pressure in the range of about 0 psi to about 1000 psi.

4. The process according to claim 1 wherein the catalyst is present in an amount in the range of about 0.01% to about 2.00% by weight based on the total weight of the finished foam article.

5. The process according to claim 1 wherein the average size of said particles is such that their average longest length diameter is any value in the range of about 0.5 cm to about 15 cm.

6. The process according to claim 1 wherein said mixture contains at least one surfactant.

7. The process according to claim 1 wherein said mixture contains at least one silicone surfactant.

8. A method consisting of:

coating a plurality of polyurethane foam particles with a binder system, said binder system consisting of an organic isocyanate, a polyol, a catalyst of 2,2′

- dimorpholinodiethylether and optionally a surfactant, an organic or silicon based extender oil, an ester, a solvent or a blowing agent;

compressing the coated polyurethane particles; and

curing the coated polyurethane particles with steam.

9. The method of claim 8 wherein the coating includes coating the plurality of polyurethane foam particles with the binder in a mixing apparatus.

10. The method of claim 8 wherein said coating includes adding said binder system to said polyurethane foam particles as a single mixture of binder components.

11. The method of claim 8 wherein coating includes forming a prepolymer with the organic isocyanate and the polyol and adding the resultant prepolymer to the polyurethane foam particles in one stream, and adding the catalyst to the polyurethane foam particles in another, different stream, both streams added to a same mixing apparatus.

12. The method of claim 8 wherein compressing includes transferring the coated polyurethane foam particles to a pressing apparatus and applying a force to compress the coated polyurethane foam particles.

13. The method of claim 12 wherein curing includes, during compression, allowing the steam to treat the coated polyurethane foam particles.

14. A process for producing a cured polyurethane foam article comprising:

a) forming a mixture consisting of;

i) a plurality of particles of polyurethane foam;

ii) a prepolymer made from an organic isocyanate and a polyol;

iii) a catalyst of 2,2′

- dimorpholinodiethylether; and

iv) optionally a surfactant, an organic or silicon based extender oil, an ester, a solvent or a blowing agent; and

b) curing said mixture by contacting it with steam; and

wherein the cured polyurethane foam article consists of the cured mixture.

15. The process according to claim 14 which is carried out at any temperature in the range of about 0°

C. to about 400°

C.

16. The process according to claim 14 which is carried out at any pressure in the range of about 0 psi to about 1000 psi.

17. The process according to claim 14 wherein the catalyst is present in an amount in the range of about 0.01% to about 2.00% by weight based on the total weight of the finished foam article.