Metal fine particles and manufacturing method therefor

• US 8,512,436 B2
• Filed: 08/22/2005
• Issued: 08/20/2013
• Est. Priority Date: 09/15/2004
• Status: Expired due to Fees

• Current Assignee: Fukuda Metal Foil & Powder Co., Ltd., Kyoto University, Hitachi Chemical Company Limited (Resonac Holdings Corp.)
• Original Assignee: Fukuda Metal Foil & Powder Co., Ltd., Kyoto University, Hitachi Chemical Company Limited (Resonac Holdings Corp.)
• Inventors: Kawasaki, Mitsuo, Kajita, Osamu, Onishi, Ayu, Masuoka, Sachiko, Iwamoto, Takafumi, Yasuda, Eitaro
• Primary Examiner(s): WYSZOMIERSKI, GEORGE P
• Application Number:
  US11/575,360
• Publication Number:
  US 20090053523A1
• Time in Patent Office: 2,920 Days
• Field of Search: 753/45
• US Class Current: 75/345
• CPC Class Codes: B22F 1/054 Nanosized particles
• CPC Class Codes: B22F 1/056 Submicron particles having a size above 100 nm up to 300 nm
• CPC Class Codes: B22F 2202/11 Use of irradiation
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: B22F 9/02 using physical processes
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: Y10T 428/2982 Particulate matter [e.g., sphere, flake, etc.]

Abstract

There is provided a method for efficiently manufacturing metal nano particles without condensing laser beams by using a lens etc. In this method, first, metallic foil pieces, which are a starting material, are dispersed in a dispersion liquid. Next, laser beams are irradiated directly to the metallic foil pieces without providing a condensing means, by which many metal fine particles are yielded. The particle diameters of the metal fine particles obtained can be controlled to sizes from nano particles to submicron particles by utilizing the relationship between the shape (especially thickness) of the metallic foil piece which is a starting material and the absorbed energy of the laser beam.

Claims

1. A manufacturing method for metal fine particles each having a particle diameter of several tens nanometers, characterized in that laser beams having at least an energy density not lower than an energy density E_th2[J/cm²] necessary for allowing metallic particles to reach the vicinity of the boiling point are irradiated to the metallic particles, each having a particle diameter of several hundred nanometers, the metallic particles being dispersed in a dispersion liquid during the irradiating with the laser beams, wherein the dispersion liquid does not additionally contain a surface active agent or other protecting agent that restrains aggregation of the metal fine particles.

2. The manufacturing method for metal fine particles according to claim 1, wherein the metal fine particles formed have a substantially spherical shape.

3. The manufacturing method for metal fine particles according to claim 1, wherein the method further comprises manufacturing the metal fine particles, using, as a starting material, metallic foil pieces, the metallic foil pieces having a thickness not larger than 1 μ

m, and wherein the manufacturing of the metal fine particles includes irradiating laser beams directly to the metallic foil pieces, dispersed in the dispersion liquid to form the metal fine particles.

4. The manufacturing method for metal fine particles according to claim 3, wherein the metallic foil pieces are foil piece-shaped metal flakes.

5. The manufacturing method for metal fine particles according to claim 3, wherein an energy density of the laser beams irradiated directly to the metallic foil pieces, in forming the metal fine particles, is E_th1[J/cm²] necessary for allowing the metallic foil pieces to reach the vicinity of the melting point.

6. A manufacturing method for metal fine particles by using metallic foil pieces as a starting material, comprising a step of dispersing the metallic foil pieces in a dispersion liquid;

and a step of subsequently irradiating laser beams directly to the metallic foil pieces, characterized in that the dispersion liquid is a solvent consisting of chain or cyclic ketone.

7. A manufacturing method for metal fine particles by using metallic thin films as a starting material, comprising a step of immersing a substrate the top surface of which is formed with a metallic thin film in a solvent, wherein the metallic thin film has a thickness not larger than 1 μ

m, and wherein the solvent is a dispersion liquid that does not additionally contain a surface active agent or other protecting agent that restrains aggregation of the metal fine particles; and

a step of subsequently irradiating laser beams directly to the metallic thin film from the top surface or the back surface of the substrate.

8. The manufacturing method for metal fine particles according to claim 7, wherein the metal fine particles formed have a substantially spherical shape.

9. A manufacturing method for metal fine particles each having a particle diameter of several tens nanometers, characterized in that laser beams, having at least an energy density not lower than an energy density E_th2[J/cm²] necessary for allowing metallic foil pieces, having a thickness not larger than 1 μ

m, to reach the vicinity of the boiling point, are irradiated to the metallic foil pieces, the metallic foil pieces being dispersed in a dispersion liquid during the irradiating, wherein the dispersing liquid does not additionally contain a surface active agent or other protecting agent that restrains aggregation of the metal fine particles.

10. The manufacturing method for metal fine particles according to claim 9, wherein said metallic foil pieces are foil piece-shaped metal flakes having the thickness not larger than 1 μ

m.

11. A manufacturing method for metal fine particles by using metallic thin films as a starting material, comprising a step of immersing a substrate, the top surface of which is formed with a metallic thin film, in a solvent, wherein the metallic thin film has a thickness not larger than 1 μ

m, and wherein the solvent is a dispersion liquid that does not contain sodium dodecyl sulfate; and

a step of subsequently irradiating laser beams directly to the metallic thin film from the top surface or the back surface of the substrate.