Heat transfer compositions

• US 8,512,591 B2
• Filed: 01/12/2011
• Issued: 08/20/2013
• Est. Priority Date: 10/12/2007
• Status: Active Grant

• Current Assignee: Mexichem, S.A.B. De C.V. (Orbia Advance Corporation, S.A.B. de C.V.)
• Original Assignee: Mexichem, S.A.B. De C.V. (Orbia Advance Corporation, S.A.B. de C.V.)
• Inventors: Low, Robert E
• Primary Examiner(s): MC GINTY, DOUGLAS J
• Application Number:
  US13/005,373
• Publication Number:
  US 20110184890A1
• Time in Patent Office: 951 Days
• Field of Search: 252/67, 252/68, 252/69, 252/364, 521/121, 621/14, 605/31, 134/36
• US Class Current: 252/67
• CPC Class Codes: C08J 2207/04 Aerosol, e.g. polyurethane foam spray
• CPC Class Codes: C08J 9/146 only fluorine as halogen atoms
• CPC Class Codes: C09K 2205/126 Unsaturated fluorinated hydrocarbons
• CPC Class Codes: C09K 2205/22 All components of a mixture being fluoro compounds
• CPC Class Codes: C09K 3/30 for aerosols aerosol containers B65D83/14
• CPC Class Codes: C09K 5/045 containing only fluorine as halogen
• CPC Class Codes: C11D 7/5018 Halogenated solvents
• CPC Class Codes: G06Q 99/00 Subject matter not provided for in other groups of this subclass

Abstract

A heat transfer composition comprising trans-1,3,3,3-tetrafluoropropene (R-1234ze(E)), difluoromethane (R-32) and 1,1-difluoroethane (R-152a).

Claims

1. A heat transfer composition comprising from about 5-89 wt % trans-1,3,3,3-tetrafluoropropene (R-1234ze(E)), from about 4-40 wt % difluoromethane (R-32) and from about 5-53 wt % 1,1-difluoroethane (R-152a).

2. A composition according to claim 1 comprising up to about 25% by weight R-32.

3. A composition according to claim 1 comprising up to about 45% by weight R-152a.

4. A composition according to claim 1 comprising from about 5 to about 12% by weight R-32, from about 10 to about 45% by weight of R-152a and from about 43 to about 85% by weight R-1234ze(E).

5. A composition according to claim 1 comprising from about 8 to about 12% by weight R-32, from about 5 to about 10% by weight R-152a, and from about 78 to about 87% by weight R-1234ze(E).

6. A composition according to claim 1 consisting essentially of R-32, R-152a and R-1234ze(E).

7. A composition according to claim 1 further comprising 1,1,1,2-tetrafluoroethane (R-134a).

8. A composition according to claim 7 comprising up to about 50% by weight of R-134a.

9. A composition according to claim 8 comprising from about 2 to about 15% by weight R-32, from about 5 to about 45% by weight R-152a, from about 25 to about 50% R-134a, and from about 5 to about 70% by weight R-1234ze(E).

10. A composition according to claim 7, consisting essentially of R-32, R-152a, R-1234ze(E) and R-134a.

11. A composition according to claim 1, wherein the composition has a GWP of less than 1000, preferably less than 150.

12. A composition according claim 1, wherein the temperature glide is less than about 10K, preferably less than about 5K.

13. A composition according claim 1, wherein the composition has a volumetric refrigeration capacity within about 15%, preferably within about 10% of the existing refrigerant that it is intended to replace.

14. A composition according to claim 1, wherein the composition is less flammable than R-32 alone, R-152a alone or R-1234yf alone.

15. A composition according to claim 14 wherein the composition has:

(a) a higher flammable limit;

(b) a higher ignition energy; and

/or

(c) a lower flame velocity compared to R-32 alone, R-152a alone or R-1234yf alone.

16. A composition according to claim 1 which has a fluorine ratio (F/(F+H)) of from about 0.42 to about 0.7, preferably from about 0.44 to about 0.67.

17. A composition according to claim 1 which is non-flammable.

18. A composition according to claim 1, wherein the composition has a cycle efficiency within about 5% of the existing refrigerant that it is intended to replace.

19. A composition according to claim 1, wherein the composition has a compressor discharge temperature within about 15K, preferably within about 10K, of the existing refrigerant that it is intended to replace.

20. A composition comprising a lubricant and a composition according to claim 1.

21. A composition according to claim 20, wherein the lubricant is selected from mineral oil, silicone oil, polyalkyl benzenes (PABs), polyol esters (POEs), polyalkylene glycols (PAGs), polyalkylene glycol esters (PAG esters), polyvinyl ethers (PVEs), poly (alpha-olefins) and combinations thereof.

22. A composition according to claim 20 further comprising a stabilizer.

23. A composition according to claim 22, wherein the stabilizer is selected from diene-based compounds, phosphates, phenol compounds and epoxides, and mixtures thereof.

24. A composition comprising a flame retardant and a composition according to claim 1.

25. A composition according to claim 24, wherein the flame retardant is selected from the group consisting of tri-(2-chloroethyl)-phosphate, (chloropropyl) phosphate, tri-(2,3-dibromopropyl)-phosphate, tri-(1,3-dichloropropyl)-phosphate, diammonium phosphate, various halogenated aromatic compounds, antimony oxide, aluminum trihydrate, polyvinyl chloride, a fluorinated iodocarbon, a fluorinated bromocarbon, trifluoro iodomethane, perfluoroalkyl amines, bromo-fluoroalkyl amines and mixtures thereof.

26. A composition according to claim 1 which is a refrigerant composition.

27. A heat transfer device containing a composition as defined in claim 1.

28. A method for generating greenhouse gas emission credit comprising (i) replacing an existing compound or composition with a composition as defined in claim 1, wherein the composition as defined in claim 1 has a lower GWP than the existing compound or composition;

and (ii) obtaining greenhouse gas emission credit for said replacing step.

29. A heat transfer device according to claim 27 which is a refrigeration device.

30. A heat transfer device according to claim 29 which is selected from group consisting of automotive air conditioning systems, residential air conditioning systems, commercial air conditioning systems, residential refrigerator systems, residential freezer systems, commercial refrigerator systems, commercial freezer systems, chiller air conditioning systems, chiller refrigeration systems, and commercial or residential heat pump systems.

31. A heat transfer device according to claim 29 which contains a compressor.

32. A blowing agent comprising a composition as defined in claim 1.

33. A foamable composition comprising one or more components capable of forming foam and a composition as defined in claim 1, wherein the one or more components capable of forming foam are selected from polyurethanes, thermoplastic polymers and resins, such as polystyrene, and epoxy resins, and mixtures thereof.

34. A foam obtainable from the foamable composition as defined in claim 33.

35. A method according to claim 28 wherein the existing compound or composition is a heat transfer composition.

36. A sprayable composition comprising material to be sprayed and a propellant comprising a composition as defined in claim 1.

37. A method for cooling an article which comprises condensing a composition as defined in claim 1 and thereafter evaporating the composition in the vicinity of the article to be cooled.

38. A method for heating an article which comprises condensing a composition as defined in claim 1 in the vicinity of the article to be heated and thereafter evaporating the composition.

39. A method for extracting a substance from biomass comprising contacting biomass with a solvent comprising a composition as defined in claim 1, and separating the substance from the solvent.

40. A method of cleaning an article comprising contacting the article with a solvent comprising a composition as defined in claim 1.

41. A method of extracting a material from an aqueous solution comprising contacting the aqueous solution with a solvent comprising a composition as defined in claim 1, and separating the substance from the solvent.

42. A method for extracting a material from a particulate solid matrix comprising contacting the particulate solid matrix with a solvent comprising a composition as defined in claim 1, and separating the material from the solvent.

43. A mechanical power generation device containing a composition as defined in claim 1.

44. A mechanical power generating device according to claim 43 which is adapted to use a Rankine Cycle or modification thereof to generate work from heat.

45. A method of retrofitting a heat transfer device comprising the step of removing an existing heat transfer fluid, and introducing a composition as defined in claim 1.

46. A method of claim 45 wherein the heat transfer device is a refrigeration device.

47. A method according to claim 46 wherein the heat transfer device is an air conditioning system.

48. A method for reducing the environmental impact arising from the operation of a product comprising an existing compound or composition, the method comprising replacing at least partially the existing compound or composition with a composition as defined in claim 1.

49. A method for preparing a composition as defined in claim 1, the method comprising introducing R-1243ze(E), R-32, and R-152a, and optionally a lubricant, a stabilizer and/or a flame retardant, into a heat transfer device containing an existing heat transfer fluid which is R-134a.

50. A method according to claim 49 comprising the step of removing at least some of the existing R-134a from the heat transfer device before introducing the R-1243ze(E), R-32, and R-152a, and optionally the lubricant, the stabilizer and/or the flame retardant.

51. A method according to claim 35 wherein the heat transfer composition is a refrigerant selected from R-134a, R-1234yf and R-152a.

52. A method of claim 28 wherein the use of the composition of the invention results in a lower Total Equivalent Warming Impact, and/or a lower Life-Cycle Carbon Production than is be attained by use of the existing compound or composition.

53. A method of claim 28 carried out on a product from the fields of air-conditioning, refrigeration, heat transfer, blowing agents, aerosols or sprayable propellants, gaseous dielectrics, cryosurgery, veterinary procedures, dental procedures, fire extinguishing, flame suppression, solvents, cleaners, air horns, pellet guns, topical anesthetics, and expansion applications.

54. A method according to claim 53 wherein the product is selected from a heat transfer device, a blowing agent, a foamable composition, a sprayable composition, a solvent or a mechanical power generation device.

55. A method according to claim 54 wherein the product is a heat transfer device.