Method and apparatus for separating gases

• US 8,518,155 B2
• Filed: 03/16/2007
• Issued: 08/27/2013
• Est. Priority Date: 03/16/2007
• Status: Active Grant

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Palamara, John Eugene, Fogash, Kevin Boyle
• Primary Examiner(s): Smith, Duane
• Assistant Examiner(s): SHAO, PHILLIP Y
• Application Number:
  US11/686,982
• Publication Number:
  US 20080223214A1
• Time in Patent Office: 2,356 Days
• Field of Search: 951/60, 951/63, 951/72, 951/77, 951/92, 952/08, 952/36, 952/66, 962/34, 961/93
• US Class Current: 95/163
• CPC Class Codes: B01D 19/0036 Flash degasification the other groups take precedence
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: C10J 2300/1603 with gas treatment
• CPC Class Codes: C10J 3/00 Production of combustible gases containing carbon monoxide from solid carbonaceous fuels destructive distillation processes C10B
• CPC Class Codes: C10J 3/82 Gas withdrawal means
• CPC Class Codes: C10K 1/16 with non-aqueous liquids
• CPC Class Codes: C10K 3/00 Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02P 20/151 Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

A method and apparatus for removing carbon dioxide from a synthesis gas stream containing hydrogen is disclosed. The method includes absorbing the carbon dioxide using a physical solvent under high pressure and then liberating the carbon dioxide in a series of expansion stages where the pressure on the solvent is reduced. The expansion ratio increases with each expansion stage. The apparatus includes expansion stages having throttling devices and expansion tanks operated at increasing expansion ratios. Carbon dioxide is liberated in this manner so as to minimize the energy required compress for transport via a pipe line for sequestration of the gas. Sequestration of the carbon dioxide is preferred to atmospheric venting to curb the release of greenhouse gases.

Claims

1. A method of removing a gas dissolved in a liquid under pressure, said method comprising:

combining a gas comprising at least one acidic gas with a liquid under pressure in order to form a pressurized liquid having at least one acidic gas dissolved therein;

wherein the pressurized liquid comprises a solvent and the solvent preferentially absorbs the at least one acidic gas,

reducing the pressure on said liquid at a first expansion ratio, a first portion of said gas being thereby released from said liquid;

drawing off said first portion of said gas from said liquid;

reducing the pressure on said liquid at a second expansion ratio greater than said first expansion ratio, a second portion of said gas being thereby released from said liquid;

drawing off said second portion of said gas from said liquid; and

reducing the pressure on said liquid at a third expansion ratio greater than said second expansion ratio, a third portion of said gas being thereby released from said liquid;

and wherein expansion ratio R_n is defined as P_n-1/P_n and P_n-1 is the absolute pressure of the gas at a preceding stage and P_n is the absolute pressure of the gas at a subsequent stage n.

2. A method according to claim 1, further comprising

compressing said gas portions;

transporting said gas portions; and

sequestering said gas portions in a storage facility.

22. The method according to claim 1 wherein the acidic gas comprises at least one member selected from the group consisting of carbon dioxide and hydrogen sulfide.

23. The method according to claim 22 wherein the solvent comprises at least one member selected from the group consisting of dimethyl ethers of polyethylene glycol, methanol and propylene carbonate.

24. The method according to claim 22 wherein said gas further comprises hydrogen.

3. A method of removing a gas dissolved in a liquid under pressure, said method comprising:

providing pressurized liquid having a gas comprising carbon dioxide dissolved therein;

wherein the liquid comprises a liquid physical solvent and the solvent absorbs carbon dioxide,

reducing the pressure on said liquid in a product recovery pressure reduction stage and a plurality of subsequent pressure reduction stages beginning with a first subsequent pressure reduction stage, wherein each subsequent pressure reduction stage after said first subsequent pressure reduction stage occurs at an expansion ratio, in absolute pressure, greater than the pressure reduction stage which preceded it, a portion of said gas being released from said liquid at each pressure reduction stage.

4. A method according to claim 3, comprising 3 subsequent pressure reduction stages.

5. A method according to claim 3, wherein said product recovery pressure reduction stage has an expansion ratio greater than said first subsequent pressure reduction stage.

6. A method of removing carbon dioxide gas from a gas mixture comprising hydrogen and carbon dioxide, said method comprising:

bringing said gas mixture into contact with a liquid physical solvent under pressure, said solvent preferentially absorbing carbon dioxide gas from said gas mixture into the liquid;

reducing the pressure on said solvent in a product recovery pressure reduction stage;

further reducing the pressure on said solvent in a plurality of subsequent pressure reduction stages beginning with a first subsequent pressure reduction stage, wherein each subsequent pressure reduction stage after said first subsequent pressure reduction stage occurs at an expansion ratio greater than the preceding pressure reduction stage wherein a portion of said carbon dioxide gas absorbed by said solvent being released from said solvent at each pressure reduction stage, and wherein expansion ratio R_n is defined as P_n-1/P_n and P_n-1is the absolute pressure of the gas at a preceding stage and P_n is the absolute pressure of the gas at a subsequent stage n.

7. A method according to claim 6, wherein said product recovery pressure reduction stage has an expansion ratio greater than said first subsequent pressure reduction stage.

8. A method according to claim 6, further comprising bringing said gases released from said product recovery pressure reduction stage into contact with said solvent.

9. A method according to claim 6, further comprising:

drawing off said carbon dioxide from said solvent before each subsequent pressure reduction stage after said first subsequent pressure reduction stage;

compressing said carbon dioxide; and

transporting said carbon dioxide for sequestration.

10. A method according to claim 6, comprising deriving said gas mixture from a process selected from the group consisting of steam methane reforming, water gas shift reaction, partial oxidation of natural gas, gasification of coal, gasification of coke, partial oxidation of heavy hydrocarbons and combinations thereof.

11. A method according to claim 6, comprising executing 3 subsequent pressure reduction stages.

12. A method according to claim 6, wherein said liquid physical solvent is selected from the group consisting of dimethyl ethers of polyethylene glycol, methanol, propylene carbonate and combinations thereof.

13. A method according to claim 6, further comprising stripping carbon dioxide from said solvent subsequent to said pressure reduction stages by bringing said solvent into contact with a substantially pure gas.

14. A method according to claim 13, wherein said substantially pure gas is selected from the group consisting of steam and nitrogen.

15. The method of claim 6 wherein said method is performed in an apparatus comprising:

a first expansion means adapted to receive said solvent, gases absorbed in said solvent being released from said solvent in said first expansion means;

a second expansion means adapted to receive said solvent from said first expansion means, said gases being released from said solvent in said second expansion means;

a third expansion means adapted to receive said solvent from said second expansion means, said gases being released from said solvent in said third expansion means;

wherein said second expansion means is configured to reduce the pressure on said solvent at an expansion ratio greater than the expansion ratio of said first expansion means, and said third expansion means is configured to reduce the pressure on said solvent at an expansion ratio greater than the expansion ratio of said second expansion means.

16. The method according to claim 15, further comprising a compressor facility in fluid communication with said first, second and third expansion means for receiving the gases released from said solvent, said compressor facility compressing said gases for transport away therefrom.

17. The method of claim 15 wherein said method is conducted in an apparatus comprising:

an absorption vessel adapted to bring said liquid physical solvent into contact with said gas mixture under pressure, said absorption vessel having a solvent inlet for admitting said solvent to said absorption vessel, a gas inlet for admitting said gas mixture to said absorption vessel, a gas outlet for releasing said product gas from said absorption vessel, and a solvent outlet for releasing said solvent from said absorption vessel;

a product recovery expansion means adapted to receive said solvent from said absorption vessel, carbon dioxide and other gases absorbed from said gas mixture being released from said solvent in said product recovery expansion means;

a compressor having an inlet in fluid communication with said product recovery expansion means and an outlet in fluid communication with said gas inlet of said absorption vessel, said compressor moving gases released from said solvent in said product recovery expansion means back to said absorption vessel;

a first expansion means adapted to receive said solvent from said product recovery expansion means, carbon dioxide being released from said solvent in said first expansion means;

a second expansion means adapted to receive said solvent from said first expansion means, carbon dioxide being released from said solvent in said second expansion means;

a third expansion means adapted to receive said solvent from said second expansion means, carbon dioxide being released from said solvent in said third expansion means;

a compressor facility in fluid communication with said first, second, and third expansion means for receiving the carbon dioxide released from said solvent, said compressor facility compressing said carbon dioxide for transport away therefrom;

wherein

said second expansion means is configured to reduce the pressure on said solvent at an expansion ratio greater than the expansion ratio of said first expansion means, and said third expansion means is configured to reduce the pressure on said solvent at an expansion ratio greater than the expansion ratio of said second expansion means.

18. The method according to claim 17, further comprising a plurality of additional expansion means, said additional expansion means being in fluid communication in series with each other and said third expansion means, wherein each of said additional expansion means is configured to reduce the pressure on said solvent at an expansion ratio greater than the expansion ratio of a preceding one of said expansion means.

19. The method according to claim 18, further comprising:

a stripping vessel having a solvent inlet in fluid communication with one of said expansion means for admitting solvent to said stripping vessel, and a solvent outlet in fluid communication with said solvent inlet of said absorption vessel;

a pump for pumping said solvent from said stripping vessel to said absorption vessel;

a pure gas inlet for admitting a substantially pure gas to said stripping vessel; and

a gas outlet for releasing gas from said stripping vessel.

20. The method according to claim 17, wherein at least one of said expansion means comprises a throttling means in fluid communication with an expansion tank, said solvent entering said expansion tank through said throttling means, carbon dioxide and other gases being released from said solvent and collecting in a gas space above said solvent within said expansion tank.

21. The method according to claim 20, wherein said throttling means comprises a device selected from the group consisting of an orifice, a pipe and a valve.