Process for fractionating sugarcane bagasse into high α-cellulose pulp, xylan and lignin

• US 8,529,731 B2
• Filed: 09/05/2008
• Issued: 09/10/2013
• Est. Priority Date: 09/07/2007
• Status: Active Grant

• Current Assignee: Council of Scientific & Industrial Research
• Original Assignee: Council of Scientific & Industrial Research
• Inventors: Varma, Anjanikumar Jyotiprasad
• Primary Examiner(s): CALANDRA, ANTHONY J
• Application Number:
  US12/677,031
• Publication Number:
  US 20100276093A1
• Time in Patent Office: 1,831 Days
• Field of Search: 162/55, 162/68, 162/96
• US Class Current: 162/96
• CPC Class Codes: C08B 37/0003 General processes for their isolation or fractionation, e.g. purification or extraction from biomass
• CPC Class Codes: C08B 37/0057 beta-D-Xylans, i.e. xylosaccharide, e.g. arabinoxylan, arabinofuronan, pentosans; (beta-1,3)(beta-1,4)-D-Xylans, e.g. rhodymenans; Hemicellulose; Derivatives thereof
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: D21C 1/02 with water or steam
• CPC Class Codes: D21C 1/08 with oxygen-generating compounds
• CPC Class Codes: D21C 9/14 with ClO2 or chlorites
• CPC Class Codes: D21H 11/12 Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse

Abstract

Sugarcane bagasse consists of mainly three polymeric components, namely cellulose (40-45%), hemicellulose (xylan) (28-30%), and lignin (19-21%). A process is herein disclosed for fractionating sugarcane bagasse into cellulose, hemicellulose and lignin with high purity α-cellulose, which is a useful raw material for preparing cellulose esters like cellulose triacetate and other high value-added cellulose plastics. Co-production and recovery of hemicellulose (xylan) and lignin in high yields and high purities, along with α-cellulose, is another important feature of this process. Sugarcane bagasse consists of a material known as pith which constitutes 30-35% by weight of bagasse. Pith contains cellulose, hemicellulose, and lignin, in addition to various other ingredients and cell mass. The process described herein discloses the use of partially depithed bagasse as a preferred raw material for fractionation. Use of sugarcane bagasse containing pith leads to a product which is lower in yield as well as poorer in color.

Claims

1. A process for the fractionation and isolation of high α

-cellulose pulp, hemicellulose (xylan) and lignin from-fibrous organic biomass wherein the organic biomass is sugarcane bagasse, said process consisting essentially of;

a) saturating the organic biomass with water;

b) then contacting the saturated organic biomass from step (a) with steam in a steam explosion reactor at a temperature in the range 140°

C.-230°

C., for period of 0.5 minute to 60 minutes, hydrolyzing and solubilizing the hemicellulose component to an extent of 70%-90%, followed by exploding the saturated biomass into fine particles of biomass by instant release of pressure, followed by evaporation of condensed water to obtain hemicellulose,

c) separating and washing the fine particles of biomass with water and treating the fine particles of biomass with 10%-24% sodium hydroxide, at a temperatures in the range 80°

C.-180°

C. to solubilize lignin component to an extent of 90%-95% as well as solubilizing residual hemicellulose to obtain an undissolved fibrous organic biomass and a soluble fraction containing lignin, followed by precipitation of lignin out of the soluble fraction with mineral acid,

d) separating and washing the undissolved fibrous organic biomass and bleaching the undissolved fibrous organic biomass with 1-10% by weight of sodium chlorite or chlorine dioxide, at a temperature of 20°

C.-90°

C., for a period of 1-18 hrs, at a pH of 3.5-4.0 to form a bleached fibrous organic residue,

e) separating, washing and drying the bleached fibrous organic residue to obtain a pulp containing 90%-94% α

-cellulose.

2. A process according to claim 1, wherein the mineral acid used for the precipitation of lignin in step (c) is selected from hydrochloric acid, sulfuric acid and nitric acid.

3. A process according to claim 1, wherein the reaction time used for bleaching in step (d) is in the range of 4-6 hours.

4. A process according to claim 1, wherein the yield of 90-94% α

-cellulose content of the pulp is 30-37% by weight of the bagasse raw material used.

5. A process according to claim 1, wherein the yield of isolated hemicellulose is 19-26% by weight of the bagasse raw material used.

6. A process according to claim 1, wherein the yield of isolated lignin is in the range of 15-16% by weight of the bagasse raw material used.