Electrochemical sensor with controlled variation of working electrode

• US 8,529,742 B2
• Filed: 02/24/2010
• Issued: 09/10/2013
• Est. Priority Date: 02/24/2010
• Status: Active Grant

• Current Assignee: Conductive Technologies
• Original Assignee: Conductive Technologies
• Inventors: Musho, Matthew K., Szabo, Nicholas F.
• Primary Examiner(s): Ball, J. Christopher
• Application Number:
  US12/711,806
• Publication Number:
  US 20110203926A1
• Time in Patent Office: 1,294 Days
• Field of Search: 204/400, 20440301-40315, 204/412, 204/434, 204/290.01, 422/68.1, 422 8201- 8203, 422/98, 435/5
• US Class Current: 204/412
• CPC Class Codes: G01N 27/3272 Test elements therefor, i.e. disposable laminated substrates with electrodes, reagent and channels optical biosensors G01N33/52

Abstract

An electrochemical sensor includes a dielectric substrate and a conductive layer formed on a surface of the substrate. The conductive layer includes a working electrode, an electrode lead and a connecting arm connecting the working electrode to the electrode lead. A dielectric layer is positioned over the conductive layer. The dielectric layer has an aperture exposing the working electrode and a portion of the connecting arm. The working electrode, electrode lead and connecting arm may be formed by laser ablation technique to provide precise working electrode sensor parameters.

Claims

1. An electrochemical sensor comprising:

a dielectric substrate;

a conductive layer formed on a surface of the substrate, the conductive layer comprising at least one working electrode, an electrode lead and a connecting arm connecting the working electrode to the electrode lead; and

a dielectric layer disposed over at least a portion of the conductive layer, the dielectric layer including an aperture exposing the working electrode and at least a portion of the connecting arm;

wherein at least one of the width or length of the connecting arm does not exceed 0.0254 mm.

2. The sensor of claim 1, wherein a variation in the working electrode area associated with a movement of ±

0.250 mm of the dielectric layer results in a variation in a total working electrode area of about 0.003 mm², the variation in the total working electrode area equaling about 1% of the total working electrode area.

3. The sensor of claim 1, wherein the working electrode, the connecting arm and the electrode lead are formed using laser ablation.

4. The sensor of claim 1, wherein the working electrode, the connecting arm and the electrode lead are formed using a process that can produce elements with features that are less than 0.0254 mm.

5. The sensor of claim 1, the working electrode, connecting arm and electrode lead comprising metalized films, the metalized films being imaged using laser ablation.

6. The sensor of claim 5, wherein the metalized films are selected from the group consisting of Au, Pd, Pt or any metal that is interest in an electrochemical sense which can be sputtered or coated.

7. The sensor of claim 6, wherein the substrate is selected from the group consisting of PET, polycarbonate, and other plastic materials.

8. The sensor of claim 1, wherein the working electrode, the electrode lead and the connecting arm are formed by laser-ablating a thin metal film carried on the substrate.

9. The sensor of claim 1 wherein the connecting arm is less than 0.02 mm.

10. The sensor of claim 1, further comprising a reference/counter electrode disposed adjacent to the working electrode, the reference/counter electrode electrically connected to an electrode lead by a second connecting arm.

11. The sensor of claim 1, wherein the aperture defines an area of working electrode that is exposed to a test fluid.

12. The sensor of claim 1, wherein the working electrode further comprises a circular area of approximately 0.320 square millimeters, the circular area being approximately equal to about 1.2% of the total area of the working electrode.

13. The sensor of claim 1 wherein a variation in the working electrode area associated with a movement of ±

0.250 mm of the dielectric layer aperture results in a variation in the total working electrode area of about 0.003 mm², and the variation is about 1% of the total working electrode area.

14. The sensor of claim 1, further comprising a pair of fill detect electrodes with a vent disposed on the sensor between the fill detect electrodes, the vent arranged to allow air to escape from a capillary channel formed by a spacer layer and a cover lid portion, when a test fluid displaces air when entering the capillary channel.

15. The sensor of claim 14 wherein the fill detect electrodes detect the presence of fluid in the capillary channel.

16. The sensor of claim 1, further comprising a capillary lid applied over a spacer layer, the spacer layer applied over dielectric layer and further comprising an aperture defining a capillary channel for receiving a fluid.

17. The sensor of claim 1, wherein the dielectric layer is screen-printed, patterned, or laminated over the conductive layer.

18. The sensor of claim 1, wherein the electrode lead further comprises a lead trace extending from the lead to the connecting arm to form a electrically conductive path between the connecting arm and the electrode lead.