Retention of amines in the removal of acid gases by means of amine absorption media

• US 8,529,857 B2
• Filed: 03/30/2012
• Issued: 09/10/2013
• Est. Priority Date: 03/31/2011
• Status: Active Grant

• Current Assignee: BASF SE
• Original Assignee: BASF SE
• Inventors: Sieder, Georg, Notz, Ralf, Garcia Andarcia, Hugo Rafael, Schmidt, Sandra, Moser, Peter
• Primary Examiner(s): VANOY, TIMOTHY C
• Application Number:
  US13/436,113
• Publication Number:
  US 20120251418A1
• Time in Patent Office: 529 Days
• Field of Search: 423/228, 423/229
• US Class Current: 423/228
• CPC Class Codes: B01D 2252/20436 Cyclic amines
• CPC Class Codes: B01D 2252/20478 Alkanolamines
• CPC Class Codes: B01D 2256/245 Methane
• CPC Class Codes: B01D 2257/302 Sulfur oxides
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/308 Carbonoxysulfide COS
• CPC Class Codes: B01D 2257/408 Cyanides, e.g. hydrogen cyanide (HCH)
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 53/1406 Multiple stage absorption
• CPC Class Codes: B01D 53/1418 Recovery of products
• CPC Class Codes: B01D 53/1456 Removing acid components
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A method for removing acid gases from a fluid stream comprises a) treating the fluid stream in an absorption zone with an absorption medium which comprises an aqueous solution of at least one amine, conducting the treated fluid stream through at least two scrubbing zones and treating it with a non-acidic aqueous phase in order to transfer entrained amine and/or entrained amine decomposition products at least in part to the aqueous phase, wherein aqueous phase is recycled via at least one scrubbing zone and aqueous phase is conducted through at least one scrubbing zone without recycling. The method permits efficient retention of amines from the treated fluid streams.

Claims

1. A method for removing acid gases from a fluid stream, which comprises

a) treating the fluid stream in an absorption zone with an absorption medium which comprises an aqueous solution of at least one amine,

b) conducting the treated fluid stream through at least two scrubbing zones and treating it with a non-acidic aqueous phase in order to transfer entrained amine and/or entrained amine decomposition products at least in part to the aqueous phase, wherein aqueous phase is recycled via at least one scrubbing zone and aqueous phase is conducted through at least one scrubbing zone without recycling.

2. The method according to claim 1, wherein the at least two scrubbing zones have packed beds, ordered packings and/or trays.

3. The method according to claim 1, wherein the absorption zone is arranged in an absorption column and at least one scrubbing zone is formed as a section of the absorption column arranged above the absorption zone.

4. The method according to claim 1, wherein the absorption zone is arranged in an absorption column and at least one scrubbing zone is arranged in a scrubbing column different from the absorption column.

5. The method according to claim 1, wherein a first scrubbing zone is arranged above the absorption zone and a second scrubbing zone is arranged above the first scrubbing zone, wherein aqueous phase is recycled via the second scrubbing zone, a substream of the aqueous phase recycled via the second scrubbing zone is conducted through the first scrubbing zone and aqueous phase draining from the first scrubbing zone is combined with the absorption medium in the absorption zone.

6. The method according to claim 5, wherein the aqueous phase recycled via the second scrubbing zone is cooled.

7. The method according to claim 5, wherein feed water is fed into the second scrubbing zone.

8. The method according to claim 7, wherein the loaded absorption medium is regenerated in a stripper by warming with partial evaporation of the absorption medium, wherein the acid gases are at least in part released, and the released acid gases are cooled in order to at least partially condense out entrained water vapor, and the condensate is used at least in part as feed water.

9. The method according to claim 7, wherein the feed water comprises at least in part fresh water.

10. The method according to claim 9, wherein the amount of fresh water substantially corresponds to the amount of water lost from the absorption medium circuit.

11. The method according to claim 1, wherein the loaded absorption medium is regenerated in a stripper by warming with partial evaporation of the absorption medium, wherein the acid gases are at least in part released.

12. The method according to claim 1, wherein the treated fluid stream is then scrubbed with an acidic aqueous solution.

13. The method according to claim 12, wherein the treated fluid stream is conducted through a scrubbing zone via which the acidic aqueous solution is recycled.

14. The method according to claim 12, wherein, as acidic aqueous solution, an acidic process water from the treatment of sulfur dioxide-comprising gases is used.

15. The method according to claim 1, wherein the amine comprises at least one primary or secondary amine.

16. The method according to claim 1, wherein the amine comprises at least one alkanolamine and/or at least piperizine derivative.