Process for purifying hydrogen chloride

• US 8,536,381 B2
• Filed: 09/11/2009
• Issued: 09/17/2013
• Est. Priority Date: 09/12/2008
• Status: Expired due to Fees

• Current Assignee: Solvay SA (Solvac SA)
• Original Assignee: Solvay SA (Solvac SA)
• Inventors: Krafft, Philippe, Gilbeau, Patrick
• Primary Examiner(s): Price, Elvis O
• Application Number:
  US13/063,230
• Publication Number:
  US 20110166369A1
• Time in Patent Office: 1,467 Days
• Field of Search: 568/841, 568/844
• US Class Current: 568/844
• CPC Class Codes: C01B 7/0706 of hydrogen chloride
• CPC Class Codes: C07D 301/26 Y being hydrogen
• CPC Class Codes: C08G 59/063 with epihalohydrins

Abstract

Process for purifying hydrogen chloride, comprising at least one step of bringing said hydrogen chloride into contact with a scrubbing agent containing at least one chlorohydrin.

Claims

1. A process, comprising bringing hydrogen chloride into contact with a scrubbing agent comprising a chlorohydrin to produce purified hydrogen chloride, and reacting a polyhydroxylated aliphatic hydrocarbon, an ester of a polyhydroxylated aliphatic hydrocarbon, or a mixture of the two with a chlorinating agent comprising said purified hydrogen chloride in order to obtain a chlorohydrin.

2. The process according to claim 1, wherein at least one portion of the hydrogen chloride to be purified is in the gaseous state.

3. The process according to claim 1, wherein the hydrogen chloride to be purified comprises an aromatic organic compound.

4. The process according to claim 1, wherein the hydrogen chloride to be purified is the by-product of the manufacture of an organic isocyanate.

5. The process according to claim 4, wherein the hydrogen chloride to be purified is the by-product of the manufacture of an organic isocyanate by reacting phosgene with an organic amine.

6. The process according to claim 3, wherein the aromatic organic compound is a chloroaromatic compound.

7. The process according to claim 1, wherein the chlorohydrin in the scrubbing agent is selected from the group consisting of monochloropropanediol, dichloropropanol, and mixtures thereof.

8. The process according to claim 1, wherein the scrubbing agent further comprises at least one compound selected from the group consisting of water, alcohols, aldehydes, ketones, carboxylic acids, carboxylic acid esters, ethers, halogenated hydrocarbons, epoxides, metals, and mixtures of at least two of them.

9. The process according to claim 1, wherein the scrubbing agent is substantially composed of dichloropropanol in the liquid state.

11. The process according to claim 1, wherein a flow of the scrubbing agent is between 0.5 and 50% by weight relative to a flow of hydrogen chloride to be purified.

12. A process as claimed in claim 1, further comprising subjecting said chlorohydrin produced by reacting a polyhydroxylated aliphatic hydrocarbon, an ester of a polyhydroxylated aliphatic hydrocarbon, or a mixture of the two with a chlorinating agent to a dehydrochlorination reaction to provide an epoxide.

13. A process for manufacturing an epoxy derivative selected from the group consisting of epoxy resins, glycidyl ethers, glycidyl esters, glycidyl amides, glycidyl imides, glycidyl amines, products that can be used as coagulants, wet-strength resins, cationization agents, flame retardants, ingredients for detergents, epichlorohydrin elastomers, halogenated polyethers-polyols, monochloropropanediol, and any mixture of at least two of them, comprising:

CARRYING out the process according to claim 12, wherein the epoxide is epichlorohydrin, and

subjecting the epichlorohydrin

to a reaction with at least one compound selected from the group consisting of monoalcohols, monocarboxylic acids, polyols, polyamines, amino alcohols, polyimides, polyamides, polycarboxylic acids, ammonia, amines, polyaminoamides, polyimines, amine salts, phosphoric acid, phosphoric acid salts, phosphorus oxychlorides, phosphoric acid esters, phosphonic acids, esters of phosphonic acids, salts of phosphonic acids, phosphinic acids, esters of phosphinic acids, salts of phosphinic acids, phosphine oxides, phosphines, ethoxylated alcohols, alkylene or phenylene oxides, and mixtures of at least two of them, or

to a homopolymerization reaction, or

to a reaction of oligomerisation, of co-oligomerisation, of condensation, of dehydrochlorination and of hydrolysis, with water, or with a di- or polyhydroxylated compound which may optionally be halogenated and/or have ether oxide bonds and/or double bonds capable of being halogenated in a subsequent stage, or

to a reaction with water.

14. The process according to claim 1, comprising reacting said polyhydroxylated aliphatic hydrocarbon, said ester of a polyhydroxylated aliphatic hydrocarbon, or said mixture of the two with said chlorinating agent comprising said purified hydrogen chloride in order to obtain dichloropropanol.

15. The process according to claim 14, wherein said scrubbing agent comprises dichloropropanol.

10. The process according to claim, wherein bringing hydrogen chloride into contact with the scrubbing agent is carried out at a temperature between 10 and 120°

C., and at a pressure between 1 and 20 bar absolute.