Transparent conductive articles and methods of making same

• US 8,541,942 B2
• Filed: 06/25/2012
• Issued: 09/24/2013
• Est. Priority Date: 11/02/1998
• Status: Expired due to Fees

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Bright, Clark I.
• Primary Examiner(s): Patel, Ashok
• Application Number:
  US13/532,181
• Publication Number:
  US 20120262056A1
• Time in Patent Office: 456 Days
• Field of Search: None
• US Class Current: 313/506
• CPC Class Codes: C23C 16/0272 Deposition of sub-layers, e.g. to promote the adhesion of the main coating
• CPC Class Codes: C23C 16/545 for coating elongated substrates
• CPC Class Codes: G02F 1/133305 Flexible substrates, e.g. plastics, organic film
• CPC Class Codes: G02F 1/133345 Insulating layers G02F1/1335, G02F1/1337, G02F1/135, G02F1/136 take precedence
• CPC Class Codes: H10K 2102/311 Flexible OLED
• CPC Class Codes: H10K 50/81 Anodes
• CPC Class Codes: H10K 50/816 Multilayers, e.g. transparent multilayers
• CPC Class Codes: H10K 50/8445 multilayered coatings having a repetitive structure, e.g. having multiple organic-inorganic bilayers
• CPC Class Codes: H10K 77/111 Flexible substrates
• CPC Class Codes: Y02E 10/549 Organic PV cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 428/12576 Boride, carbide or nitride component
• CPC Class Codes: Y10T 428/31667 Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product
• CPC Class Codes: Y10T 428/31678 Of metal
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
• CPC Class Codes: Y10T 428/31692 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31794 Of cross-linked polyester
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

A lightweight, flexible, plastic substrate is coated with at least one layer, such that the substrate has desired barrier and electrode characteristics useful in constructing OLED displays. The layer has both a low enough resistance to function as an electrode for the display, and low oxygen and moisture permeability. The display is thereby protected from oxygen and moisture degradation. For lower permeability and/or higher conductivity, multiple alternating layers of barrier materials and conductive materials may be applied. The barrier material includes at least one of a thin metallic film, an organic polymer, a thin transparent dielectric, a thin transparent metal nitride, and a thin transparent conductive oxide. The conductive material includes at least one of a thin transparent conductive oxide, a thin transparent metallic film, and a thin transparent metal nitride. Preferably, a multilayer polymer base coat is deposited over the substrate to exclude moisture and atmospheric gases.

Claims

1. An OLED comprising:

a flexible plastic substrate coated with one or more vacuum-deposited in-situ polymerized layers of polymer and a first layer configuration comprising;

a first transparent electrically conductive oxide layer,

a transparent electrically conductive metal layer adjacent the first transparent electrically conductive oxide layer, and

a second transparent electrically conductive oxide layer adjacent the transparent electrically conductive metal layer; and

a light emitting material;

wherein the OLED has a visible light transmittance of about 80-85%.

2. The OLED according to claim 1, wherein the flexible plastic substrate is further coated with a second layer configuration comprising a first transparent electrically conductive oxide layer, a transparent electrically conductive metal layer adjacent the first transparent electrically conductive oxide layer, and a second transparent electrically conductive oxide layer adjacent the transparent electrically conductive metal layer.

3. The OLED according to claim 2, wherein the first and second layer configurations are separated by one or more vacuum-deposited in-situ polymerized layers of polymer.

4. The OLED according to claim 1, wherein the OLED does not comprise a reflective metal layer.

5. A process for fabricating an OLED, the process comprising the steps of:

(a) providing a substrate;

(b) depositing over the substrate a first layer configuration, a second layer configuration, and one or more vacuum-deposited in-situ polymerized layers of polymer, each of the first and second layer configurations comprising a first transparent electrically conductive oxide layer, a transparent electrically conductive metal layer adjacent the first transparent electrically conductive oxide layer, and a second transparent electrically conductive oxide layer adjacent the transparent electrically conductive metal layer, wherein the first and second layer configurations are separated by one or more of the vacuum-deposited in-situ polymerized layers of polymer, and

(c) depositing over the substrate a light emitting material;

wherein the OLED has a visible light transmittance of about 80-85%.

6. A process for fabricating an OLED, the process comprising the steps of:

(a) providing a substrate;

(b) depositing over the substrate a layer of in-situ polymerized organic monomer and an optically enhanced transparent electrically conductive three layer configuration comprising a first electrically conductive oxide layer, a transparent electrically conductive metal layer adjacent the first transparent electrically conductive oxide layer, and a second transparent electrically conductive oxide layer adjacent the transparent electrically conductive metal layer;

(c) applying the substrate to an OLED to obtain a visible light transmittance of about 80-85%.

7. The method according to claim 6, further comprising applying a polymeric base coat to smooth the substrate prior to deposition of a transparent electrically conductive oxide layer.

8. The method according to claim 6, further comprising heating the substrate during or after deposition of a transparent electrically conductive oxide layer.

9. The method according to claim 6, further comprising depositing one or more of the transparent electrically conductive oxide layers in a hydrogen-containing plasma.

10. The method according to claim 6, further comprising electrically connecting all electrically conductive layers in parallel.

11. The method according to claim 6, further comprising contacting the transparent conductive oxide layers with a roller without causing cracking or crazing of the electrically conductive oxide layers sufficient to reduce electrical conductivity.