Electrochemical cell, and particularly a cell with electrodeposited fuel

• US 8,546,028 B2
• Filed: 10/24/2012
• Issued: 10/01/2013
• Est. Priority Date: 05/19/2008
• Status: Active Grant

• Current Assignee: Arizona Board of Regents (University of Arizona)
• Original Assignee: Arizona Board of Regents (University of Arizona)
• Inventors: Friesen, Cody A., Hayes, Joel
• Primary Examiner(s): Ryan, Patrick
• Assistant Examiner(s): GRESO, AARON J
• Application Number:
  US13/659,830
• Publication Number:
  US 20130049694A1
• Time in Patent Office: 342 Days
• Field of Search: 429/400, 429/402, 429/404, 429/405, 429/415, 429/428, 429/476, 429/477, 429/498, 429/502, 429/49, 429/101, 429/122, 205/799
• US Class Current: 429/402
• CPC Class Codes: H01M 12/065 with plate-like electrodes or stacks of plate-like electrodes
• CPC Class Codes: H01M 4/12 of consumable metal or alloy electrodes use of alloy compositions as active materials H01M4/38
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

The present invention relates to a method for charging the cell by electrodeposition of metal fuel on the anode thereof.

Claims

1. An electrochemical cell comprising:

a first electrode comprising a series of permeable electrode bodies arranged in a spaced apart relation for holding an electrodeposited fuel;

a second electrode spaced apart from the first electrode;

a charging electrode;

an ionically conductive medium communicating the electrodes, the ionically conductive medium comprising reducible fuel ions of the electrodeposited fuel;

wherein the ionically conductive medium flows through the permeable electrode bodies; and

wherein the spaced apart relation of said permeable electrode bodies of the first electrode enables an electrical current to be applied between the charging electrode and at least one of the permeable anode bodies during charging with the charging electrode functioning as an anode and the at least one permeable electrode body functioning as a cathode, such that the reducible fuel ions are reduced and electrodeposited as the fuel in oxidizable form on the at least one permeable electrode body, wherein the electrodeposition causes growth of the fuel among the permeable electrode bodies and within the spacing therebetween such that the electrodeposited fuel establishes an electrical connection between the permeable electrode bodies.

2. The electrochemical cell of claim 1, further comprising a first terminal connected to at least one of the permeable electrode bodies.

3. The electrochemical cell of claim 2, wherein the permeable electrode bodies of the first electrode are connected in parallel to the first terminal.

11. The electrochemical cell of claim 1, wherein the permeable electrode bodies of the first electrode are selectively connected in parallel for selective connection of each to a load during discharging and a power supply during charging.

13. The electrochemical cell of claim 1, wherein the charging electrode is spaced apart from the first electrode, the charging electrode being selected from the group consisting of (a) the second electrode, and (b) a third electrode.

14. The electrochemical cell of claim 3, wherein the charging electrode is spaced apart from the first electrode, the charging electrode being selected from the group consisting of (a) the second electrode, and (b) a third electrode.

18. The electrochemical cell of claim 11, wherein the charging electrode is spaced apart from the first electrode, the charging electrode being selected from the group consisting of (a) the second electrode, and (b) a third electrode.

20. The electrochemical cell of claim 13, wherein the charging electrode is spaced apart from the first electrode, the charging electrode being selected from the group consisting of (a) the second electrode, and (b) a third electrode.

21. The electrochemical cell according to claim 1, wherein the second electrode is an air electrode for reducing oxygen during discharge.

22. The electrochemical cell according to claim 1, wherein the first electrode has the electrodeposited fuel thereon and the fuel is a metal for oxidation during discharge.

23. The electrochemical cell according to claim 22, wherein the metal is selected from the group consisting of zinc, iron, aluminum and magnesium.

24. The electrochemical cell according to claim 1, wherein the ionically conductive medium is an aqueous solution.

25. The electrochemical cell according to claim 24, wherein the aqueous solution is alkaline.

26. The electrochemical cell according to claim 1, further comprising inert, non-conductive separators to maintain separation and electrical isolation between the permeable electrode bodies.

27. The electrochemical cell according to claim 3, wherein the second electrode is an air electrode for reducing oxygen during discharge.

28. The electrochemical cell according to claim 3, wherein the first electrode has the electrodeposited fuel thereon and the fuel is a metal for oxidation during discharge.

29. The electrochemical cell according to claim 28, wherein the metal is selected from the group consisting of zinc, iron, aluminum and magnesium.

30. The electrochemical cell according to claim 3, wherein the ionically conductive medium is an aqueous solution.

31. The electrochemical cell according to claim 30, wherein the aqueous solution is alkaline.

32. The electrochemical cell according to claim 3, further comprising inert, non-conductive separators to maintain separation and electrical isolation between the permeable electrode bodies.

4. An electrochemical cell comprising:

a first electrode comprising a series of permeable electrode bodies arranged in spaced apart relation for holding an electrodeposited fuel;

a second electrode spaced apart from the first electrode;

a charging electrode;

an ionically conductive medium communicating the electrodes, the ionically conductive medium for comprising reducible fuel ions of the electrodeposited fuel; and

a first terminal connected to at least one of the permeable electrode bodies;

wherein the spaced apart relation of said permeable electrode bodies of the first electrode enables an electrical current to be applied between the charging electrode and at least one of the permeable anode bodies during charging with the charging electrode functioning as an anode and the at least one permeable electrode body functioning as a cathode, such that the reducible fuel ions are reduced and electrodeposited as the fuel in oxidizable form on the at least one permeable electrode body wherein the electrodeposition causes growth of the fuel among the permeable electrode bodies and within the spacing therebetween such that the electrodeposited fuel establishes an electrical connection between the permeable electrode bodies; and

wherein the at least one permeable electrode body to which the electrical current is applied and functioning as a cathode during charging is a single terminal electrode body connected to the first terminal, and wherein each other permeable electrode body is electrically isolated from the first terminal except by electrical connection of the electrodeposited fuel and the ionically conductive medium.

15. The electrochemical cell of claim 4, wherein the charging electrode is spaced apart from the first electrode, the charging electrode being selected from the group consisting of (a) the second electrode, and (b) a third electrode.

5. An electrochemical cell comprising:

a first electrode comprising a series of permeable electrode bodies arranged in spaced apart relation for holding an electrodeposited fuel;

a second electrode spaced apart from the first electrode;

a charging electrode;

an ionically conductive medium communicating the electrodes, the ionically conductive medium for comprising reducible fuel ions of the electrodeposited fuel; and

a first terminal connected to at least one of the permeable electrode bodies;

wherein the permeable electrode bodies of the first electrode are connected in parallel to the first terminal;

wherein the spaced apart relation of said permeable electrode bodies of the first electrode enables an electrical current to be applied between the charging electrode and at least one of the permeable anode bodies during charging with the charging electrode functioning as an anode and the at least one permeable electrode body functioning as a cathode, such that the reducible fuel ions are reduced and electrodeposited as the fuel in oxidizable form on the at least one permeable electrode body, wherein the electrodeposition causes growth of the fuel among the permeable electrode bodies and within the spacing therebetween such that the electrodeposited fuel establishes an electrical connection between the permeable electrode bodies;

wherein the at least one permeable electrode body to which the electrical current is applied and functioning as a cathode during charging is a single terminal electrode body connected to the first terminal, and

wherein the cell further comprises a current isolator between each other permeable electrode body and the first terminal, the each current isolator being configured to electrically isolate each other permeable electrode body from the first terminal except by electrical connection of the electrodeposited fuel at least during charging.

6. The electrochemical cell of claim 5, wherein each current isolator is a switch moveable between open and closed positions.

7. The electrochemical cell of claim 5, wherein each current isolator is a one-way diode.

8. The electrochemical cell of claim 5, wherein each current isolator is also configured to permit current to flow from each other electrode body to a load during discharge when the first electrode is functioning as an anode.

9. The electrochemical cell of claim 8, wherein each current isolator is a switch moveable between open and closed positions.

10. The electrochemical cell of claim 8, wherein each current isolator is a one-way diode.

16. The electrochemical cell of claim 5, wherein the charging electrode is spaced apart from the first electrode, the charging electrode being selected from the group consisting of (a) the second electrode, and (b) a third electrode.

17. The electrochemical cell of claim 8, wherein the charging electrode is spaced apart from the first electrode, the charging electrode being selected from the group consisting of (a) the second electrode, and (b) a third electrode.

12. An electrochemical cell comprising:

a first electrode comprising a series of permeable electrode bodies arranged in spaced apart relation for holding an electrodeposited fuel;

a second electrode spaced apart from the first electrode;

a charging electrode;

an ionically conductive medium communicating the electrodes, the ionically conductive medium for comprising reducible fuel ions of the electrodeposited fuel;

wherein the spaced apart relation of said permeable electrode bodies of the first electrode enables an electrical current to be applied between the charging electrode and at least one of the permeable anode bodies during charging with the charging electrode functioning as an anode and the at least one permeable electrode body functioning as a cathode, such that the reducible fuel ions are reduced and electrodeposited as the fuel in oxidizable form on the at least one permeable electrode body, wherein the electrodeposition causes growth of the fuel among the permeable electrode bodies and within the spacing therebetween such that the electrodeposited fuel establishes an electrical connection between the permeable electrode bodies;

wherein the permeable electrode bodies of the first electrode are connected in parallel for selective connection to a load during discharging and a power supply during charging

wherein the permeable electrode bodies includes a terminal electrode body and one or more other electrode bodies,

wherein the cell further comprises a current isolator between each other permeable electrode body for electrically isolating each other permeable electrode body except by communication of ions through the ionically conductive medium and by electrical connection of the electrodeposited fuel from the power supply during charging, and permitting current to flow from each other electrode body to the load during discharging when the first electrode is functioning as an anode.

19. The electrochemical cell of claim 12, wherein the charging electrode is spaced apart from the first electrode, the charging electrode being selected from the group consisting of (a) the second electrode, and (b) a third electrode.

33. The electrochemical cell according to claim 12, wherein the second electrode is an air electrode for reducing oxygen during discharge.

34. The electrochemical cell according to claim 12, wherein the first electrode has the electrodeposited fuel thereon and the fuel is a metal for oxidation during discharge.

35. The electrochemical cell according to claim 34, wherein the metal is selected from the group consisting of zinc, iron, aluminum and magnesium.

36. The electrochemical cell according to claim 12, wherein the ionically conductive medium is an aqueous solution.

37. The electrochemical cell according to claim 36, wherein the aqueous solution is alkaline.

38. The electrochemical cell according to claim 12, further comprising inert, non-conductive separators to maintain separation and electrical isolation between the permeable electrode bodies.