Ionic probe

• US 8,551,311 B2
• Filed: 10/10/2008
• Issued: 10/08/2013
• Est. Priority Date: 09/06/2006
• Status: Active Grant

• Current Assignee: Hach Company (Veralto Corp.)
• Original Assignee: Hach Company (Veralto Corp.)
• Inventors: Woodward, John Robert, Livrozet, Pierre Antoine Robert, Schvan, Jean-Francois Maurice Rene, Young, Russell Martin, West, Kevin James
• Primary Examiner(s): Hendricks, Keith
• Assistant Examiner(s): DINH, BACH T
• Application Number:
  US12/249,727
• Publication Number:
  US 20090101524A1
• Time in Patent Office: 1,824 Days
• Field of Search: 204416-420, 204/433, 204/435, 324/438
• US Class Current: 204/433
• CPC Class Codes: G01N 27/302 pH sensitive, e.g. quinhydron, antimony or hydrogen electrodes ion selective electrodes G01N27/333, glass electrodes G01N27/36
• CPC Class Codes: G01N 27/36 Glass electrodes
• CPC Class Codes: G01N 27/4035 Combination of a single ion-sensing electrode and a single reference electrode G01N27/406 and G01N27/413 take precedence

Abstract

An ionic probe is provided according to the invention. The ionic probe includes an active electrode configured to generate a measurement signal for an external test fluid, a first reference electrode configured to generate a first reference signal, and an at least second reference electrode configured to generate at least a second reference signal. The measurement signal is compared to the first reference signal and the at least second reference signal in order to determine an ionic measurement of the external test fluid.

Claims

1. An ionic probe, comprising:

an inner shell, an outer shell, and a middle shell configured to house one or more electrodes, wherein an outer surface of the inner shell is contiguous material that includes a first pH-sensitive material and a second pH-sensitive material;

wherein the inner shell is disposed within the middle shell and the middle shell is disposed within the outer shell;

an active electrode disposed in the inner shell that generates a measurement signal for an external test fluid;

a first reference electrode disposed in the inner shell in a first reference chamber formed by an inner divider in the inner shell, the first reference electrode generating a first reference signal;

a second reference electrode disposed in a second reference chamber formed by the inner shell and the middle shell, the second reference chamber generating a second reference signal;

wherein the measurement signal is provided by the ionic probe for comparison to the first reference signal and the second reference signal in order to determine an ionic measurement of the external test fluid.

2. The ionic probe of claim 1, with the active electrode being located in an active electrolyte that ionically interacts with the external test fluid, with the first reference electrode being located in a first reference solution that ionically interacts with a middle solution, and with the second reference electrode being located in a second reference solution that ionically interacts with an outer solution, wherein the middle solution and the second reference solution ionically interact with the external test fluid.

3. The ionic probe of claim 1, wherein the inner shell forms an active chamber and including an active electrolyte solution and an active ion sensitive region that protrudes from the ionic probe and is adapted to contact the external test fluid, with the active ion sensitive region allowing ion interaction between the active electrolyte solution and the external test fluid;

the active electrode located in the active chamber and configured to generate a measurement signal related to an ionic potential between the external test fluid and the active electrolyte solution;

the first reference chamber holding a first reference solution and including at least one first ion sensitive region formed in the inner shell, with the at least one first ion sensitive region allowing ion interaction between the first reference solution and a middle solution that is external to the inner shell at the first ion sensitive region;

the first reference electrode located within the first reference chamber and configured to generate a first reference signal related to an ionic potential between the first reference solution and the middle solution;

the middle shell forming a second reference chamber and holding a second reference solution and including at least one second ion sensitive region formed in the middle shell, with the at least one second ion sensitive region completing a circuit between the second reference solution and an outer solution that is external to the middle shell at the second ion sensitive region; and

the second reference electrode being located in the second reference chamber and configured to generate a second reference signal related to an ionic potential between the second reference solution and the outer solution.

4. The ionic probe of claim 3, wherein one or more of the active ion sensitive region, the at least one first ion sensitive region, or the at least one second ion sensitive region comprise patches of ion sensitive material bonded to the inner shell and the middle shell.

5. The ionic probe of claim 3, where the inner shell, the inner divider, and the middle shell are substantially mono-axial/coaxial.

6. The ionic probe of claim 3, wherein the outer shell holds at least an outer solution, with the outer solution being configured to ionically interact with the second reference solution through the at least second ion sensitive region.

7. The ionic probe of claim 3, wherein the outer shell, the inner shell, the middle shell, and the inner divider are substantially mono-axial/coaxial.

8. The ionic probe of claim 1, wherein the first reference signal is compared to the second reference signal in order to determine a correction value to be applied to the ionic measurement.

9. The ionic probe of claim 1, wherein the first reference signal is compared to the second reference signal in order to detect a single reference drift in one of the first reference signal or the second reference signal.

10. The ionic probe of claim 1, wherein the first reference signal and the second reference signal are compared to a predetermined reference voltage in order to detect a dual reference drift in both the first reference signal and the second reference signal.

11. An ionic probe, comprising:

an inner shell, an outer shell, and a middle shell, wherein the inner shell the middle shell house one or more electrodes and at least one of the inner shell and the middle shell has an outer surface that is contiguous material that includes a first pH-sensitive material and a second pH-sensitive material;

wherein the inner shell is disposed within the middle shell and the middle shell is disposed within the outer shell;

the inner shell forming an active chamber and including an active electrolyte solution and an active ion sensitive region that protrudes from the ionic probe and is adapted to contact an external test fluid, with the active ion sensitive region allowing ion interaction between the active electrolyte solution and the external test fluid;

an active electrode located in the active chamber and configured to generate a measurement signal related to an ionic potential between the external test fluid and the active electrolyte solution;

a middle divider located inside the inner shell and forming a first reference chamber, with the first reference chamber holding a first reference solution and including at least one first ion sensitive region formed in the inner shell, with the at least one first ion sensitive region allowing ion interaction between the first reference solution and a middle solution that is external to the inner shell at the first ion sensitive region;

a first reference electrode located within the first reference chamber that generates a first reference signal related to an ionic potential between the first reference solution and the middle solution;

the middle shell and the inner shell forming a second reference chamber and holding a second reference solution and including at least one second ion sensitive region formed in the middle shell, with the at least one second ion sensitive region allowing ion interaction between the second reference solution and an outer solution that is external to the middle shell at the second ion sensitive region;

a second reference electrode located in the second reference chamber that generates a second reference signal related to an ionic potential between the second reference solution and the outer solution;

wherein the measurement signal is provided by comparison to the first reference signal and the second reference signal in order to determine an ionic measurement of the external test fluid.

12. The ionic probe of claim 11, wherein one or more of the active ion sensitive region, the at least one first ion sensitive region, or the at least one second ion sensitive region comprise patches of ion sensitive material bonded to the inner shell and the middle shell.

13. The ionic probe of claim 11, wherein the first reference signal is compared to the at least second reference signal in order to determine a correction value to be applied to the ionic measurement.

14. The ionic probe of claim 11, wherein the first reference signal is compared to the at least second reference signal in order to detect a single reference drift in one of the first reference signal or the at least second reference signal.

15. The ionic probe of claim 11, wherein the first reference signal and the at least second reference signal are compared to a predetermined reference voltage in order to detect a dual reference drift in both the first reference signal and the at least second reference signal.

16. The ionic probe of claim 11, where the inner shell, the middle shell, and the outer shell are substantially mono-axial/coaxial.

17. The ionic probe of claim 11, wherein the outer shell holds at least an outer solution, with the outer solution being configured to ionically interact with the second reference solution through the at least second ion sensitive region.

18. The ionic probe of claim 11, wherein the outer shell, the inner shell, the middle shell, and the inner divider, are substantially mono-axial/coaxial.

19. An ionic meter, comprising:

an ionic probe comprising;

at least an outer shell, an inner shell and a middle shell configured to house one or more electrodes, wherein an outer surface of the inner shell is contiguous material that includes a first pH-sensitive material and a second pH-sensitive material;

wherein the inner shell is disposed within the middle shell and the middle shell is disposed within the outer shell;

an active electrode disposed in the inner shell that generates a measurement signal for an external test fluid;

a first reference electrode disposed in the inner shell in a first reference chamber formed by an inner divider in the inner shell, the first reference electrode generating a first reference signal; and

a second reference electrode disposed within a second reference chamber formed by the inner shell and the middle shell, the second reference electrode generating a second reference signal; and

a processor configured to receive the measurement signal, the first reference signal and the second reference signal and compare the measurement signal to the first reference signal and the second reference signal in order to determine an ionic measurement of the external test fluid.

20. The ionic meter of claim 19, with the active electrode being located in an active electrolyte that ionically interacts with the external test fluid, with the first reference electrode being located in a first reference solution that ionically interacts with a middle solution, and with the second reference electrode being located in a second reference solution that ionically interacts with an outer solution, wherein the middle solution and the outer solution ionically interact with the external test fluid.

21. The ionic meter of claim 19, with the processor being further configured to compare the first reference signal to the second reference signal in order to determine a correction value to be applied to the ionic measurement.

22. The ionic meter of claim 19, with the processor being further configured to compare the first reference signal to the second reference signal in order to detect a single reference drift in one of the first reference signal or the second reference signal.

23. The ionic meter of claim 19, with the processor being further configured compare the first reference signal and the second reference signal to a predetermined reference voltage in order to detect a dual reference drift in both the first reference signal and the second reference signal.

24. The meter of claim 19, where the inner shell, the middle shell, and the outer shell are substantially mono-axial/coaxial.

25. The meter of claim 20, wherein the outer shell holds at least an outer solution, with the outer solution being configured to ionically interact with the second reference solution through the at least second ion sensitive region.

26. The meter of claim 19, wherein the outer shell, the inner shell, the middle shell, and the inner divider are substantially mono-axial/coaxial.