Power generator with additional hydrogen storage

• US 8,551,663 B2
• Filed: 04/25/2007
• Issued: 10/08/2013
• Est. Priority Date: 04/25/2007
• Status: Active Grant

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Eickhoff, Steven J.
• Primary Examiner(s): SAHA, BIJAY S
• Application Number:
  US11/789,520
• Publication Number:
  US 20080268303A1
• Time in Patent Office: 2,358 Days
• Field of Search: 429/19, 429/12
• US Class Current: 429/400
• CPC Class Codes: H01M 8/04201 Reactant storage and supply, e.g. means for feeding, pipes
• CPC Class Codes: H01M 8/04208 Cartridges, cryogenic media or cryogenic reservoirs
• CPC Class Codes: H01M 8/04216 characterised by the choice for a specific material, e.g. carbon, hydride, absorbent
• CPC Class Codes: H01M 8/065 by dissolution of metals or alloys; by dehydriding metallic substances
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A power generator includes a hydrogen producing fuel and a hydrogen storage element. A fuel cell having a proton exchange membrane separates the hydrogen producing fuel from ambient. A valve is positioned between the hydrogen storage element and the hydrogen producing fuel and the fuel cell. Hydrogen is provided to the fuel cell from the hydrogen storage element if demand for electricity exceeds the hydrogen producing capacity of the hydrogen producing fuel.

Claims

1. A power generator comprising:

a hydrogen producing fuel comprising a chemical hydride, an alkali intermetallic compound, or a combination thereof that generates hydrogen when exposed to water vapor;

a fuel cell having a proton exchange membrane separating the hydrogen producing fuel from ambient; and

a metal hydride hydrogen storage element, that absorbs and desorbs hydrogen;

wherein a hydrogen permeable particulate filter is disposed between the chemical hydride alkali intermetallic compound, or combination thereof hydrogen producing fuel and the metal hydride hydrogen storage element; and

wherein the electrical power generator is waterless such that the water molecules produced at the fuel cell as a byproduct of the reaction of hydrogen and oxygen are passively diffused from the fuel cell as water vapor to a fuel chamber that contains the chemical hydride, alkali intermetallic compound, or combination thereof hydrogen producing fuel where the water vapor reacts with the hydrogen producing fuel to generate hydrogen.

2. The power generator of claim 1 and further comprising a valve positioned between the hydrogen storage element and the hydrogen producing fuel and the fuel cell.

3. The power generator of claim 1 wherein the metal hydride hydrogen storage element comprises a porous metal hydride hydrogen storage element.

4. The power generator of claim 3 wherein the metal hydride hydrogen storage element has an equilibrium pressure in the range of approximately 0.01 to 10 atmospheres.

5. The power generator of claim 4 wherein the equilibrium pressure in the range of approximately 0.01 to 10 atmospheres is over an approximately −

20 to 60°

C. temperature range.

6. The power generator of claim 1 wherein the metal hydride hydrogen storage element comprises a metal hydride including at least one of an ab5 compound, ab2 compound, ab compound, complex alloys, intermetallic compounds or solid solution alloys.

7. The power generator of claim 1 wherein the metal hydride hydrogen storage element comprises a material selected from the group consisting of LaNi₅, LaNI₄.6Mn_0.4, MnNi_3.5Co_0.7Al_0.8, MnNi₄.2Co_0.2Mn_0.3Al_0.3, TiFe_0.8Ni_0.2, CaNi₅, (V_0.9Ti_0.1)_0.95Fe_0.05, (V_0.9Ti_0.1)_0.95Fe_0.05, and LaNi_4.7Al_0.3.

8. The power generator of claim 1 wherein the hydrogen producing fuel comprises a chemical hydride.

9. The power generator of claim 1 wherein the hydrogen producing fuel comprises Li3Al2, CaAl19, and Mg2Al3, LiAlH₄, NaAlH₄, CaH₂, LiBH₄, NaBH₄, LiH, alkali metals, or any combination thereof.

10. The power generator of claim 1 and further comprising a water vapor hydrogen permeable membrane between the hydrogen producing fuel and the fuel cell.

11. The power generator of claim 1 wherein the fuel cell comprises a PEM membrane with an anode and a cathode.