Process for production of polyethylene terephthalate pellets

• US 8,557,155 B2
• Filed: 08/08/2012
• Issued: 10/15/2013
• Est. Priority Date: 02/08/2010
• Status: Active Grant

• Current Assignee: Automatik Plastics Machinery Gmbh (Dover Corporation)
• Original Assignee: Automatik Plastics Machinery Gmbh (Dover Corporation)
• Inventors: Deiss, Stefan, Gloeckner, Frank, Mueller, Horst
• Primary Examiner(s): Grun, Robert J
• Application Number:
  US13/569,966
• Publication Number:
  US 20120309928A1
• Time in Patent Office: 433 Days
• Field of Search: 264/143, 528/308.2
• US Class Current: 264/143
• CPC Class Codes: B29B 9/16 Auxiliary treatment of granules

Abstract

A process for production of polyethylene terephthalate pellets includes the steps of: production of a melt of polyethylene terephthalate material; production of polyethylene terephthalate pellets from the melt by means of underwater pelletization into a process fluid; removal of the polyethylene terephthalate pellets from the site of underwater pelletization in the process fluid; crystallization of the polyethylene terephthalate pellets in the process fluid, wherein a surface of the polyethylene terephthalate pellets is crystallized and an interior of the polyethylene terephthalate pellets remains amorphous.

Claims

1. A process for production of polyethylene terephthalate pellets comprising the steps of:

a. production of a melt of polyethylene terephthalate material;

b. production of polyethylene terephthalate pellets from the melt by means of underwater pelletization into a process fluid;

c. removal of the polyethylene terephthalate pellets from a site of underwater pelletization in the process fluid;

d. crystallization of the polyethylene terephthalate pellets in the process fluid, wherein during crystallization a surface of the polyethylene terephthalate pellets is crystallized and an interior of the polyethylene terephthalate pellets remains amorphous, wherein a temperature of the process fluid is adjusted, depending on a formulation of the polyethylene terephthalate material, to a value at which, a previously experimentally determined maximum crystallization rate of the polyethylene terephthalate material of the polyethylene terephthalate pellets is reached, and wherein, after the crystallization step, opacity of the surface of the polyethylene terephthalate pellets is determined as a measure of an achieved degree of crystallization and as a measure of an achieved crystallization depth at the surface of the polyethylene terephthalate pellets, and wherein the opacity of the surface is determined online directly as part of the process;

e. extraction of the polyethylene terephthalate pellets in the process fluid; and

f. separation of the polyethylene terephthalate pellets from the process fluid.

2. The process of claim 1, wherein the opacity of the surface of the polyethylene terephthalate pellets is determined optically by refraction.

3. The process of claim 2, further comprising changing the temperature of the process fluid, a duration of the crystallization step, or both during the crystallization step upon a change in the opacity of the surface of the polyethylene terephthalate pellets.

4. The process of claim 3, wherein in the crystallization step, the temperature of the process fluid is at 180 degrees Celsius±

10 degrees Celsius.

5. The process of claim 1, further comprising changing the temperature of the process fluid, a duration of the crystallization step, or both during the crystallization step upon a change in the opacity of the surface of the polyethylene terephthalate pellets.

6. The process of claim 5, wherein in the crystallization step, the temperature of the process fluid is at 180 degrees Celsius±

10 degrees Celsius.

7. The process of claim 1, wherein in the crystallization step, the temperature of the process fluid is at 180 degrees Celsius±

10 degrees Celsius.

8. The process of claim 1, wherein in the crystallization step, the polyethylene terephthalate pellets are retained in the process fluid from 0.5 minutes to 10 minutes.

9. The process of claim 1, wherein the crystallization step is executed to provide the achieved crystallization depth at the surface of the polyethylene terephthalate pellets that is up to 10 percent of a radius of the polyethylene terephthalate pellets.

10. The process of claim 1, wherein for underwater pelletization, the removal of the polyethylene terephthalate pellets step and the crystallization step, the process fluid is at an increased pressure above ambient pressure, the increased pressure being at least 1 bar.

11. The process of claim 1, wherein after the crystallization step, the polyethylene terephthalate pellets are, up until they are used, maintained at a temperature below a temperature of the determined maximum crystallization rate.

12. The process of claim 1, wherein the process fluid is water, ambient air, or nitrogen.