Method and apparatus for pyrolysis of a biomass

• US 8,557,193 B2
• Filed: 10/11/2011
• Issued: 10/15/2013
• Est. Priority Date: 07/19/2010
• Status: Active Grant

• Current Assignee: MARD Incorporated
• Original Assignee: Kior Inc.
• Inventors: Bartek, Robert, Cordle, Ronald Lee
• Primary Examiner(s): Griffin, Walter D
• Assistant Examiner(s): NGUYEN, HUY TRAM
• Application Number:
  US13/270,913
• Publication Number:
  US 20120045371A1
• Time in Patent Office: 735 Days
• Field of Search: 422/214
• US Class Current: 422/214
• CPC Class Codes: C10B 49/22 according to the "fluidised bed" technique
• CPC Class Codes: C10B 53/02 of cellulose-containing material production of pyroligneous acid C10C5/00
• CPC Class Codes: C10C 5/00 Production of pyroligneous acid distillation of wood, dry distillation of organic wastecarbonisation of wood C10B
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel
• CPC Class Codes: Y02P 20/145 the feedstock being materials of biological origin
• CPC Class Codes: Y02P 30/20 using bio-feedstock

Abstract

A method and apparatus for effective pyrolysis of a biomass utilizing rapid heat transfer from a solid heat carrier or catalyst. Particularly, various embodiments of the present invention provide methods and apparatuses which incorporate progressive temperature quenching and rapid disengagement of the heat carrier material and reaction product.

Claims

1. An apparatus for biomass conversion comprising:

a) a riser reactor having a mixing zone, an intermediate zone located above said mixing zone and forming interface with said mixing zone, and an upper zone located above said intermediate zone, wherein a biomass feed is mixed with a heat carrier material to produce a reaction mixture comprising said heat carrier material and a reaction product, which comprises oxygenated hydrocarbons;

b) a biomass feed conduit connected in fluid flow communication with said mixing zone for introducing said biomass feed to said riser reactor;

c) a lift gas conduit connected in fluid flow communication with said mixing zone for introducing a lift gas to said riser reactor to assist in producing a general upward flow in said riser reactor;

d) a heat carrier material conduit connected in fluid flow communication with said mixing zone for introducing said heat carrier material into said riser reactor;

e) a first quench stream conduit connected in fluid flow communication with said riser reactor at a location just above said interface of said mixing zone and said intermediate zone, resulting in a lower temperature in said intermediate zone as compared to said mixing zone; and

f) a disengager connected in fluid flow communication with said upper zone such that said reaction mixture is received in said disengager and at least a portion of said reaction product is separated from said heat carrier material within said disengager.

2. The apparatus of claim 1 further comprising at least one other quench stream conduit connected in fluid flow communication with said riser reactor at a location within:

i) said intermediate zone, ii) said upper zone, or iii) both said intermediate zone and said upper zone.

3. The apparatus of claim 2 wherein there are at least two other quench stream conduits with at least one being connected at a location within said intermediate zone and at least one being connected at a location within said upper zone.

4. The apparatus of claim 1 further comprising:

g) a product conduit connected in fluid flow communication with said disengager for receiving reaction product;

h) a stripper connected in fluid flow communication with said disengager such that heat carrier material from said disengager is introduced into said stripper; and

i) a regenerator connected in fluid flow communication with said stripper and said heat carrier material conduit such that heat carrier material from said stripper is introduced into said regenerator and heat carrier material from said regenerator is introduced into said heat carrier material conduit.

5. The apparatus of claim 1 wherein said lift gas conduit is connected to said mixing zone below the locations where said biomass feed conduit and said heat carrier material conduit are each connected to said mixing zone.

6. The apparatus according to claim 1, wherein said first quench stream conduit is configured to receive a quench stream comprising a fluid produced in said biomass conversion apparatus.

7. The apparatus according to claim 6, wherein said fluid comprises water produced in said biomass conversion apparatus.

8. The apparatus according to claim 1, wherein said apparatus is configured such that the contact time between said biomass feed and said heat carrier material is less than 1 second.

9. The apparatus according to claim 1, wherein said disengager comprises a cyclone, wherein said cyclone is closely coupled to said riser reactor.

10. The apparatus according to claim 1, wherein said heat carrier material comprises a material selected from the group consisting of an inorganic inert material, an inorganic catalyst, and combinations thereof, wherein said biomass feed comprises lignocellulose.

11. An apparatus for the conversion of biomass material comprising:

a) a riser reactor comprising a mixing zone, an intermediate zone, an upper zone, and an interface between said mixing zone and said intermediate zone;

b) a biomass feed conduit in fluid flow communication with said mixing zone and operable to deliver a biomass feed to said mixing zone;

c) a heat carrier material conduit connected in fluid flow communication with said mixing zone and operable to deliver a heat carrier material to said mixing zone;

d) a lift gas conduit connected in fluid flow communication with said mixing zone and operable to provide a lift gas into said mixing zone at a rate sufficient to maintain less than 1 second of contact time between said biomass feed and said heat carrier material in said apparatus;

e) a quench stream conduit connected in fluid flow communication with said riser reactor and operable to deliver a temperature-lowering quench stream inside said riser reactor at a location above said interface,

wherein said riser reactor is operable to release a reaction mixture from said upper zone, wherein said reaction mixture comprises a reaction product and a heat carrier material.

12. The apparatus according to claim 11, further comprising a disengager connected in fluid flow communication with said riser reactor and operable to separate at least of portion of said heat carrier material from said reaction mixture.

13. The apparatus according to claim 12, wherein said disengager comprises a cyclone closely coupled to said riser reactor.

14. The apparatus of claim 12 further comprising:

g) a product conduit connected in fluid flow communication with said disengager for receiving reaction product;

h) a stripper connected in fluid flow communication with said disengager such that heat carrier material from said disengager is introduced into said stripper; and

i) a regenerator connected in fluid flow communication with said stripper and said heat carrier material conduit such that heat carrier material from said stripper is introduced into said regenerator and heat carrier material from said regenerator is introduced into said heat carrier material conduit.

15. The apparatus according to claim 11, wherein said quench stream comprises a fluid produced in said biomass conversion apparatus.

16. The apparatus according to claim 15, wherein said fluid comprises water produced in said biomass conversion apparatus.

17. The apparatus according to claim 11, wherein said lift gas is provided to said mixing zone at a rate sufficient to maintain less than 0.7 seconds of contact time between said biomass feed and said heat carrier material in said apparatus.

18. The apparatus of claim 11 further comprising at least one other quench stream conduit connected in fluid flow communication with said riser reactor at a location within:

i) said intermediate zone, ii) said upper zone, or iii) both said intermediate zone and said upper zone.

19. The apparatus of claim 18 wherein there are at least two other quench stream conduits with at least one being connected at a location within said intermediate zone and at least one being connected at a location within said upper zone.