Gas sensor using nanotubes

• US 8,567,232 B2
• Filed: 07/09/2010
• Issued: 10/29/2013
• Est. Priority Date: 07/09/2010
• Status: Expired due to Fees

• Current Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Original Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Inventors: Ackley, H. Sprague, Wiklof, Christopher A.
• Primary Examiner(s): Williams, Hezron E
• Assistant Examiner(s): MERCADO, ALEXANDER A
• Application Number:
  US12/997,859
• Publication Number:
  US 20120006096A1
• Time in Patent Office: 1,208 Days
• Field of Search: 73/240.1, 73/310.1, 73/240.2, 73/240.3, 73/240.4, 73/240.5, 73/240.6, 324/633
• US Class Current: 73/24.01
• CPC Class Codes: G01N 33/0055 for radionuclides

Abstract

Techniques are generally described for detecting a concentration level of at least one gas. Some example devices may include a sensor including conductive plate on a surface of dielectric including a nanotube layer formed thereon. The conductive plate and the nanotube layer form a resonator that resonates at a frequency in response to an interrogation signal. The nanotube layer may be configured to associate with one or more gas molecules. The frequency at which the resonator resonates may shift according to which gas molecules are associated with the nanotube layer to identify a particular gas. An amount of resonance may be exhibited as a resonant response signal. An amplitude of the resonant response signal may be indicative of the concentration level of the detected gas.

Claims

1. A sensor configured to detect at least first and second gases in a volume that includes a mixture of two or more gases, the sensor comprising:

a dielectric substrate;

a first resonator on the dielectric substrate, the first resonator including;

a first conductive plate on a first surface of the dielectric substrate; and

a first nanotube layer arranged on the first conductive plate;

wherein the first resonator has a first base resonant frequency selected to cause the first resonator to resonate in response to an interrogation signal when the first resonator is provided in contact with the first gas; and

a second resonator on the dielectric substrate spaced apart from the first resonator along the first surface, the second resonator including;

a second conductive plate on the first surface of the dielectric substrate; and

a second nanotube layer arranged on the second conductive plate;

wherein the second resonator has a second base resonant frequency different from the first base resonant frequency, the second base resonant frequency selected to cause the second resonator to resonate in response to the interrogation signal when the second resonator is provided in contact with the second gas.

2. The sensor of claim 1, wherein the interrogation signal is associated with an interrogation frequency, the first and second resonators configured to resonate in response to the interrogation frequency in the presence of the first and second gas, respectively.

3. The sensor of claim 1, wherein the first nanotube layer comprises a layer of nanotubes, nanotubes all having substantially a same size.

4. The sensor of claim 1, wherein the first conductive plate comprises a high aspect ratio rectangle or other polygon, the first resonator configured to generate a bi-modal resonant response.

5. The sensor of claim 1, wherein the first resonator and the second resonator have different sizes.

6. The sensor of claim 1, further comprising at least one feedline configured to provide the first interrogation signal to the first resonator and the second resonator, and wherein the interrogation signal has one or more frequencies associated therewith.

7. The sensor of claim 1, further comprising a first feedline configured to selectively provide the interrogation signal to the first resonator, and a second feedline configured to selectively provide the interrogation signal to the second resonator.

8. The sensor of claim 1, wherein at least one of the first conductive plate and the second conductive plate comprises one or more of a circular plate and/or a copper plate.

9. The sensor of claim 1, further comprising a ground plane insulated from and subjacent to the first resonator.

24. The sensor of claim 1, wherein the first nanotube layer comprises nanotubes all having substantially a same first diameter.

26. The sensor of claim 1, wherein the sensor further comprises:

first and second feed lines operatively arranged to provide the interrogation signal to the first and second resonators, respectively; and

a switch configured to decouple the interrogation signal from the first feed line when coupling the interrogation signal to the second feed line, the switch being further configured to decouple the interrogation signal from the second feed line when coupling the interrogation signal to the first feed line.

27. The sensor of claim 3, wherein the second nanotube layer comprises a layer of nanotubes having a same size different than the size of the nanotubes of the first layer.

28. The sensor of claim 24, wherein the second nanotube layer comprises nanotubes all having a same second diameter different from the first diameter.

29. The sensor of claim 1, wherein at least one of the first nanotube layer and the second nanotube layer comprises a layer of nanotubes all having a same length.

10. A system for detecting first and second gasses gases in a volume including a mixture of two or more gases, the system comprising:

a signal generator configured to provide an interrogation signal;

a sensor configured to receive the interrogation signal, wherein the sensor includes;

a dielectric substrate;

a first resonator including a first nanotube layer arranged on a first conductive plate disposed at a first location on the dielectric substrate, the first resonator configured to generate a first resonant response signal in response to the interrogation signal, the first resonant response signal being indicative of a resonance characteristic of the first resonator that changes when the sensor is in contact with the first gas in the volume such that the resonance characteristic of the first resonator identifies the first gas; and

a second resonator including a second nanotube layer arranged on a second conductive plate disposed at a second location on the dielectric substrate spaced apart from the first location, and configured to generate a second resonant response signal in response to the interrogation signal, the second resonant response signal indicative of a resonance characteristic of the second resonator that changes when the sensor is in contact with the second gas in the volume such that the resonance characteristic of the second resonator identifies the second gas; and

a detector configured to receive the first and second resonant response signals and generate a detection signal that indicates the resonance characteristic of the first resonator that identifies the first gas and/or the resonance characteristic of the second resonator that identifies the second gas.

11. The system of claim 10, wherein the signal generator and the detector are part of a sensor interface.

12. The system of claim 10, further comprising a controller that is operatively coupled to the detector and configured to receive the detection signal, wherein the controller is further configured to compare the detection signal with an expected value to determine the presence and/or absence of the first or second gas in the volume.

13. The system of claim 10, wherein the at least one sensor is wirelessly coupled to either the signal generator or the detector.

14. The system of claim 10, further comprising a control sensor including a control resonator, wherein the control sensor is located in a different volume including a known gas, wherein the control resonator is configured to generate a control response signal in response to another interrogation signal, the control response signal being indicative of a resonance characteristic of the control resonator when the control sensor is in contact with the known gas in the different volume such that the resonance characteristic of the control resonator identifies the known gas.

15. The system of claim 14, further comprising a controller configured to compare the resonance characteristics of the control resonator to the resonance characteristics of the first and/or second resonator to identify a difference indicative of the presence of the first and/or second gas about the first and/or second resonator, respectively.

16. The system of claim 15, wherein the identified difference corresponds to one or more of a difference in amplitude, a different in Q-factor, a difference in phase, a difference in resonant frequency, a shift in resonant frequency, and/or a difference in a plurality of resonant frequencies.

17. The system of claim 10, the first nanotube layer comprises a layer of first carbon nanotubes each having a first diameter and wherein the second nanotube layer comprises a layer of second carbon nanotubes each having a second diameter different from the first diameter, wherein the first resonator has a first resonant frequency when excited by the interrogation signal and the second resonator has a second resonant frequency when excited by the interrogation signal, and wherein the first resonant frequency shifts in the presence of the first gas and the second resonant frequency shifts in the presence of the second gas.

25. The system of claim 10, wherein the first interrogation signal is different from the second interrogation signal.

18. A method for identifying first and/or second gases in a volume including a mixture of two or more gases, the method comprising:

applying an interrogation signal to a first resonator, the resonator including first carbon nanotubes arranged on a first conductive plate, the first conductive plate on a first surface of a dielectric substrate, the first resonator configured to associate with the first gas to generate a first shifted resonant response in response to the interrogation signal when the first resonator is exposed to the first gas;

applying the interrogation signal to a second resonator separate from the first resonator, the second resonator including second carbon nanotubes arranged on a second conductive plate on the surface of the dielectric substrate, the second resonator configured to associate with the second gas to generate a second shifted resonant response in response to the interrogation signal when the second resonator is exposed to the second gas;

measuring two or more resonant responses of the first resonator and the second resonator when excited by the interrogation signal, the two or more resonant responses including at least the first shifted resonant response and the second shifted resonant response; and

identifying the first gas in the volume based on detecting the first shifted resonant response of the first resonator and identifying the second gas in the volume based on detecting the second shifted resonant response of the second resonator.

19. The method of claim 18, wherein

the volume is a first volume, the method further comprising applying a control interrogation signal to a control sensor in contact with a second volume different from the first volume, measuring a control resonant response of the control sensor responsive to the control interrogation signal, and

determining the identity of the first and/or second gases further based on detecting a difference between the control resonant response and at least one of the two or more resonant responses of the first resonator and the second resonator.

20. The method of claim 19, wherein the first resonator resonates at approximately the same time as the second resonator.

21. The method of claim 18, wherein the applying the interrogation signals to the first resonator comprises applying one or more first interrogation signals to a plurality of first resonators, and wherein the measuring two or more resonant responses further comprises measuring two or more first resonant responses of each first resonator of the plurality of first resonators.

30. The method of claim 18, wherein the first carbon nanotubes have a first diameter and the second carbon nanotubes have a second diameter different than the first diameter.

31. The method of claim 18, wherein the first carbon nanotubes have a first length and the second carbon nanotubes have a second length different than the first length.

22. A method for identifying a first gas and/or a second gas in a mixture including two or more gases, the method comprising:

receiving a radio based interrogation signal with an antenna that is operatively coupled to a first and second carbon nanotube resonators, the second carbon nanotube resonator havin a base resonant frequency that is different from a base resonant frequency of the first carbon nanotube resonator;

interrogating the first and second carbon nanotube resonators with the radio based interrogation signal;

generating at least one of a first resonant response and a second resonant response in response to the interrogating the first and second carbon nanotube resonators with the radio based interrogation signal, wherein the first resonant response of the first carbon nanotube resonator corresponds to a shifted resonant response of the first carbon nanotube resonator when exposed to the first gas,

and wherein the second resonant response corresponds to a shifted resonant response of the second carbon nanotube resonator when exposed to;

identifying a presence of at least one of the first gas or the second gas in the mixture based on detecting the first resonant response or the second resonant response.

23. The method of claim 22, wherein at least a portion of the antenna includes the first and/or second carbon nanotube resonator.

32. The method of claim 22, wherein the radio based interrogation signal is associated with an interrogation frequency, and wherein the generating at least one resonant response signal comprises generating the first signal and the second signal in response to interrogating the first resonator and the second resonator, respectively, at the interrogation frequency.

33. The method of claim 22, wherein the base resonant frequencies of the first and second resonators are selected such that respective ones of the first and second resonators resonate at a same shifted resonant response when the respective ones of the first and second resonators are exposed to respective ones of the first and second gas.