Combustion synthesis to bond metal inserts to C-C composite surfaces

• US 8,574,470 B2
• Filed: 10/24/2008
• Issued: 11/05/2013
• Est. Priority Date: 10/24/2008
• Status: Active Grant

• Current Assignee: Honeywell International Inc., University of Notre DAME Du Lac
• Original Assignee: Honeywell International Inc., University of Notre DAME Du Lac
• Inventors: Simpson, Allen H., La Forest, Mark L., Mukasyan, Alexander
• Primary Examiner(s): THROWER, LARRY W
• Application Number:
  US12/258,030
• Publication Number:
  US 20100104465A1
• Time in Patent Office: 1,838 Days
• Field of Search: 264/29.5, 156/273.7
• US Class Current: 264/29.5
• CPC Class Codes: C04B 2237/083 Carbide interlayers, e.g. silicon carbide interlayers
• CPC Class Codes: C04B 2237/385 Carbon or carbon composite
• CPC Class Codes: C04B 2237/403 Refractory metals
• CPC Class Codes: C04B 37/025 consisting of glass or ceramic material
• CPC Class Codes: F16D 2065/1368 with relative movement both radially and axially
• CPC Class Codes: F16D 69/02 Composition of linings ; Methods of manufacturing

Abstract

Method of joining a carbon-carbon composite piece 30 together with a metal insert 20, e.g. in the manufacture of aircraft brake discs 10. The method includes the steps of: providing a carbon-carbon composite piece 30 and a metal insert 20, wherein the metal insert 20 has a surface that is complementary to a surface of said carbon-carbon composite piece 30; providing a layer of a mixture of titanium powder and carbon powder on the first complementary mating surface; arranging the powder layer such that a second complementary mating surface is matched to the complementary mating surface, thereby forming a construct of the carbon-carbon composite piece 30, the powder layer, and the metal insert 20; placing the construct into a press and applying pressure to the construct to press together the carbon-carbon composite piece and the metal insert joined at their complementary surfaces; and applying an electrical current to the powder in the construct to initiate a metal-carbon reaction, thereby bonding the carbon-carbon composite piece 30 together the metal insert 20. The titanium powder particles may be from 25 to 100 microns in diameter, and the carbon powder (e.g., graphite particles) may be 0.1 to 1 microns in diameter.

Claims

1. A method comprising:

depositing a layer comprising titanium powder and carbon powder on at least one of a first complementary mating surface and a second complementary mating surface that is complementary to the first complementary mating surface, wherein a carbon-carbon composite piece defines the first complementary mating surface and a metal insert defines the second complementary mating surface, wherein the carbon-carbon composite piece has an annular disk shape comprising an outer axial surface defining at least one radially extending opening, the at least one radially extending opening defining at least a portion of the first complementary mating surface;

arranging the first and second complementary mating surfaces such that the powder layer is between the second complementary mating surface of the metal insert and the first complementary mating surface of the carbon-carbon composite at the at least one radially extending opening to form a construct of the carbon-carbon composite piece, the powder layer, and the metal insert;

applying pressure to the construct to press together the carbon-carbon composite piece and the metal insert joined at their complementary mating surfaces; and

applying an electrical current to the powder layer in the construct to initiate an oxidation reduction reaction to bond the carbon-carbon composite piece and the metal insert together.

2. The method of claim 1, wherein applying pressure to the construct comprises applying pressure to the construct via a press, the method further comprising removing the carbon-carbon composite piece and the metal insert, wherein the carbon-carbon composite piece and the metal insert are bonded to each other, from the press within 30 minutes of placing the unbonded carbon-carbon composite piece and metal insert into the press.

3. The method of claim 2, wherein removing the carbon-carbon composite piece and the metal insert, wherein the carbon-carbon composite piece and the metal insert are bonded to each other, from the press within 30 minutes of placing the unbonded carbon-carbon composite piece and metal insert into the press comprises removing the carbon-carbon composite piece and the metal insert, wherein the carbon-carbon composite piece and the metal insert are bonded to each other, from the press within 3 minutes of placing the unbonded carbon-carbon composite piece and the metal insert into the press.

4. The method of claim 1, wherein the carbon powder comprises powdered graphite and a mole ratio of titanium powder to powdered graphite ranges from 3:

1 to 1;

1.

5. The method of claim 4, wherein the mole ratio of titanium powder to powdered graphite is about 2:

1.

6. The method of claim 1, wherein an average particle diameter of the titanium powder ranges from 25 to 100 microns.

7. The method of claim 6, wherein the average particle diameter of the titanium powder is about 45 microns.

8. The method of claim 1, wherein the carbon powder comprises powdered graphite and an average particle diameter of the graphite ranges from 0.5 to 1 microns.

9. The method of claim 8, wherein the average particle diameter of the graphite is about 0.5 microns.

10. The method of claim 1, wherein the layer of titanium powder and carbon powder ranges from 200 to 1000 microns in thickness.

11. The method of claim 1, wherein the layer of titanium powder and carbon powder is about 100 microns in thickness.

12. The method of claim 1, wherein applying pressure to the construct comprises applying pressure ranging from 5000 lbs/in² to 10,000 lbs/in² to the construct.

13. The method of claim 12, wherein applying pressure to the construct comprises applying pressure of about 7400 lbs/in² to the construct.

14. The method of claim 1, wherein applying the electrical current to the powder layer in the construct to initiate the oxidation reduction reaction comprises applying the electrical current ranging from 400 to 1200 Amps to the powder layer in the construct to initiate the oxidation-reduction reaction.

15. The method of claim 14, wherein the electrical current is about 600 Amps.

16. The method of claim 1, wherein the metal insert is made of at least one of tungsten, tantalum, and molybdenum.

17. The method of claim 1, wherein the metal powder is different than a metal of the metal insert.

18. The method of claim 1, wherein the metal powder comprises at least one of zirconium, vanadium, and hafnium.

19. A method comprising:

applying pressure to a composite construct, the composite construct comprising;

a carbon-carbon composite piece including a first complementary mating surface, wherein the carbon-carbon composite piece has an annular disk shape with an outer axial surface including at least one radially extending opening, the at least one radially extending opening defining at least a portion of the first complementary mating surface,

a metal insert including a second complementary mating surface, and

a powder layer separating the first and second complementary mating surfaces at the at least one radially extending opening of the carbon-carbon composite, wherein the powder layer comprises titanium powder and carbon powder; and

applying an electrical current to the powder layer in the construct to initiate an oxidation reduction reaction to bond the carbon-carbon composite piece and the metal insert together.