Sprayed on superoleophobic surface formulations

• US 8,580,027 B1
• Filed: 08/11/2011
• Issued: 11/12/2013
• Est. Priority Date: 08/16/2010
• Status: Active Grant

• Current Assignee: United States Of America As Represented By The Secretary Of The Air Force
• Original Assignee: United States Of America As Represented By The Secretary Of The Air Force
• Inventors: Guenthner, Andrew J., Haddad, Timothy S., Mabry, Joseph M., Campos, Raymond
• Primary Examiner(s): Moore, Margaret
• Application Number:
  US13/207,562
• Time in Patent Office: 824 Days
• Field of Search: 523/213, 428/405, 106/287.13, 106/287, 106/27
• US Class Current: 106/287.27
• CPC Class Codes: C08K 9/06 with silicon-containing compounds
• CPC Class Codes: C08K 9/08 Ingredients agglomerated by treatment with a binding agent
• CPC Class Codes: C08L 27/18 Homopolymers or copolymers or tetrafluoroethene
• CPC Class Codes: C09D 127/18 Homopolymers or copolymers of tetrafluoroethene
• CPC Class Codes: Y10T 428/2995 Silane, siloxane or silicone coating

Abstract

Fluoroalkylsilane-treated metal oxide particles and a fluoroelastomeric binder are dispersed in a fluorinated solvent with a low boiling point and applied to a substrate via spray deposition. The spray deposition process rapidly produces a conformal coating that features low surface energy and surface topography with a large range of characteristic length scales and re-entrant curvature, thereby imparting superoleophobicity. The degree of superoleophobicity is readily adjusted by means of altering the ratio of particles to binder. The choice of particle and binder result in coatings with thermal stability for thousands of hours at temperatures up to 200 degrees Celsius as well as desirable mechanical characteristics.

Claims

1. A coating formulation comprising:

a) a first portion comprising a plurality of mesoporous fluoroalkylsilane-treated inorganic metal oxide aggregates, each of the aggregates of the plurality having at least 15 parts fluorine in the form of —

CF₂— and

—

CF₃ terminal fragments per 100 parts metal oxide by weight, and having a size distribution within the range of 0.1 μ

m to 20 μ

m,

b) a second portion comprising a fluoroelastomeric binder; and

c) a fluorinated solvent having the first portion of the plurality of mesoporous fluoroalkylsilane-treated inorganic metal oxide aggregates and the second portion of the fluoroelastomeric binder dispersed therein, wherein the fluorinated solvent has a boiling point between 30°

C. and 200°

C. and a viscosity at 20°

C. of 0.0001 Pa·

s to 10 Pa·

s;

wherein the coating formulation is configured to be sprayed on to a surface and forming a solid coating in which at least a portion of the fluoroelastomeric binder binds to at least one of the plurality of mesoporous fluoroalkylsilane-treated inorganic metal oxide aggregates, and

a ratio of the first portion to the second portion determines a resultant surface roughness of the solid coating.

2. The coating formulation of claim 1, wherein the plurality of mesoporous fluoroalkylsilane-treated inorganic metal oxide aggregates is precipitated silica or fumed silica.

3. The coating formulation of claim 2, wherein each of the plurality of mesoporous fluoroalkylsilane-treated inorganic metal oxide aggregates include at least one covalently grafted fluoroalkyl chain per square nanometer.

4. The coating formulation of claim 1, wherein the fluoroelastomer is a terpolymer of ethylene, tetrafluoroethylene, perfluoro(methylvinyl)ether, and bromotetrafluorobutene.

5. The coating formulation of claim 2, wherein the fluorinated solvent is 1,1,2,2,3-pentafluoro-1,3-dichloropropane.

7. The coating formulation of claim 1, wherein the fluoroelastomeric binder binds to at least two of the plurality of mesoporous fluoroalkylsilane-treated inorganic metal oxide aggregates.

6. A sprayed-on coating, comprising a plurality of:

a) a mesoporous aggregate of fluoroalkylsilane-treated inorganic metal oxide particles, the fluoroalkylsilane-treated inorganic metal oxide particles having at least 15 parts fluorine in the form of —

CF₂— and

—

CF₃ terminal fragments per 100 parts metal oxide by weight and having a size distribution below 50 nm; and

b) a fluoroelastomeric binder, wherein the sprayed-on coating has topographical character selected by a ratio of the mesoporous aggregate to the fluoroelastomeric binder.