Devices for selective removal of contaminants from a composition

• US 8,585,976 B2
• Filed: 02/13/2008
• Issued: 11/19/2013
• Est. Priority Date: 02/13/2007
• Status: Active Grant

• Current Assignee: Mcneff Research Consultants, Inc.
• Original Assignee: Mcneff Research Consultants, Inc.
• Inventors: McNeff, Clayton V., McNeff, Larry C., Yan, Bingwen
• Primary Examiner(s): BHAT, NINA NMN
• Application Number:
  US12/030,801
• Publication Number:
  US 20080197052A1
• Time in Patent Office: 2,106 Days
• Field of Search: 422/211, 422/110, 422/115, 422/608, 446/05, 443/85, 554/169, 208/263, 208/226
• US Class Current: 422/110
• CPC Class Codes: B01D 15/00 Separating processes involving the treatment of liquids with solid sorbents using liquid sorbents B01D11/00; ion exchange processes or materials, sorbent materials in general B01J, e.g. sorbents for chromatography B01J20/281; for investigating or analysing materials G01N30/00; Apparatus therefor
• CPC Class Codes: B01J 20/0211 Compounds of Ti, Zr, Hf
• CPC Class Codes: B01J 20/06 comprising oxides or hydroxides of metals not provided for in group B01J20/04
• CPC Class Codes: B01J 20/08 comprising aluminium oxide or hydroxide; comprising bauxite
• CPC Class Codes: C10G 25/00 Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
• CPC Class Codes: C10L 1/026 for compression ignition
• CPC Class Codes: C11B 3/10 by adsorption
• CPC Class Codes: C11C 3/003 by esterification of fatty acids with alcohols C11C3/02 takes precedence
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

A device for selectively removing contaminants from a crude product mixture which includes a production reactor for producing a crude oil product mixture, the production reactor includes a lipid reservoir and an alcohol reservoir and a first organic acid removal reactor in fluid communication with the production reactor. The first organic acid removal reactor includes a first housing defining an interior volume the housing configured to receive the crude oil products and disposed within the interior volume of the removal reactor housing is metal oxide media selected from the group consisting of zirconia, alumina, hafnia and titania for removing organic acidic contaminants from the crude oil product to product a purified biodiesel fuel.

Claims

1. A system for producing a refined oil product comprising:

a production reactor for producing a crude oil product mixture, the reactor comprising a lipid reservoir, and an alcohol reservoir; and

a first organic acid removal reactor in fluid communication with the production reactor, the first organic acid removal reactor comprising a first housing defining an interior volume, the housing configured to receive the crude oil product mixture from the production reactor, metal oxide media disposed within the interior volume of the removal reactor housing, the metal oxide media comprising a metal oxide selected from the group consisting of zirconia, alumina, hafnia, and titania.

2. The system of claim 1, the first housing comprising an input port and an output port;

the first organic acid removal reactor further comprising a temperature control unit configured to maintain the temperature within the first housing within a first temperature range for a first period of time and within a second temperature range for a second period of time following the first period, the second range higher than the first range.

3. The system of claim 1, the metal oxide media comprising particles from 0.2 um to 2 mm.

4. The system of claim 2, further comprising further comprising a sensor in fluid communication with the output port, the sensor configured to determine the concentration of organic acids in a sample composition.

5. The system of claim 4, the sensor comprising a pH sensor.

6. The system of claim 1, further comprising a second organic acid removal reactor and control valves, wherein actuation of the control valves causes the second organic acid removal reactor to be in fluid communication with the production reactor instead of the first organic acid removal reactor.