Manufacturing process for polyester film exhibiting low thermal shrinkage

• US 8,591,998 B2
• Filed: 02/09/2007
• Issued: 11/26/2013
• Est. Priority Date: 02/09/2006
• Status: Expired due to Fees

• Current Assignee: DuPont Performance Elastomers L (Bristol-Myers Squibb Company)
• Original Assignee: DuPont Performance Elastomers L (Bristol-Myers Squibb Company)
• Inventors: MacKerron, Duncan Henry, Hashimoto, Katsuyuki
• Primary Examiner(s): Chen, Vivian
• Application Number:
  US12/278,820
• Publication Number:
  US 20100189998A1
• Time in Patent Office: 2,482 Days
• Field of Search: None
• US Class Current: 427/387
• CPC Class Codes: B29C 2071/022 Annealing
• CPC Class Codes: B29C 71/02 Thermal after-treatment B29C71/0063 and B29C71/0072 take precedence
• CPC Class Codes: B29K 2067/00 Use of polyesters or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2995/0048 Without internal tensions
• CPC Class Codes: C08J 2367/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds; C08J2367/06 takes precedence
• CPC Class Codes: C08J 7/0423 with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
• CPC Class Codes: C08J 7/0427 with only one layer of a composition containing a polymer binder with more layers C08J7/042
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/046 Forming abrasion-resistant coatings; Forming surface-hardening coatings
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10T 428/263 Coating layer not in excess of 5 mils thick or equivalent
• CPC Class Codes: Y10T 428/264 Up to 3 mils
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/266 of base or substrate
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane
• CPC Class Codes: Y10T 428/31736 Next to polyester
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers

Abstract

A process in which a wound roll of biaxially oriented polyester film having a glass transition temperature (Tg (° C.)) is annealed at a temperature T_a (° C.) above Tg where Tg<T_a≦Tg+100 (° C.) for a time t after thermal equilibrium where 1 hour≦t≦72 hours and cooled, for the purpose of improving the shrinkage of said polyester film.

Claims

1. A method of improving the shrinkage of biaxially oriented polyester film having a glass transition temperature (Tg (°

C.)), said method comprising the steps of annealing a wound roll of said film at a temperature T_a (°

C.) above Tg where Tg<

T_a≦

Tg+100 (°

C.) for a time t after thermal equilibrium where 1 hour≦

t≦

72 hours, and then cooling, wherein the roll of film is a composite film comprising one or more coatings on one or both surfaces of a supporting polyester substrate.

2. The method according to claim 1, wherein 1 hour≦

t≦

48 hours.

3. The method according to claim 1, wherein 1 hour≦

t≦

24 hours.

4. The method according to claim 1, wherein the annealed film exhibits dimensional change in both its machine direction (MD) and its transverse direction (TD) after heating to 180°

C. for 30 minutes of less than or equal to 0.08%.

5. The method according to claim 4, wherein the dimensional change is less than or equal to 0.05%.

6. The method according to claim 4, wherein the dimensional change is less than or equal to 0.03%.

7. The method according to claim 1, wherein said polyester is poly(ethylene naphthalate) or poly(ethylene terephthalate).

8. The method according to claim 1, wherein said polyester is poly(ethylene naphthalate).

9. The method according to claim 8, wherein said polyester is derived from 2,6-naphthalenedicarboxylic acid.

10. The method according to claim 8, wherein the poly(ethylene naphthalate) has an intrinsic viscosity of 0.5-1.5.

11. The method according to claim 1, wherein said polyester film is a heat-stabilised, heat-set, biaxially oriented film.

12. The method according to claim 1, wherein a coating is derived from a composition selected from:

(i) an organic coating comprising a low molecular weight reactive diluent;

an unsaturated oligomer;

a solvent; and

a photoinitiator;

(ii) an organic/inorganic hybrid coating comprising a low molecular weight reactive component and/or an unsaturated oligomeric component;

a solvent; and

inorganic particles, and optionally further comprising a photoinitiator; and

(iii) a hardcoat comprising inorganic particles contained in a polysiloxane.

13. The method according to claim 1, wherein a coating is derived from a composition selected from:

(i) an organic coating comprising a low molecular weight reactive diluent selected from monomeric acrylates;

an unsaturated oligomer selected from acrylates, urethane acrylates, polyether acrylates, epoxy acrylates and polyester acrylates;

a solvent; and

a photoinitiator;

(ii) an organic/inorganic hybrid coating comprising a low molecular weight reactive component selected from monomeric acrylates and/or an unsaturated oligomeric component selected from acrylates, urethane acrylates, polyether acrylates, epoxy acrylates and polyester acrylates;

a solvent; and

inorganic particles selected from silica and metal oxides, and optionally further comprising a photoinitiator; and

(iii) a hardcoat comprising inorganic particles contained in a polysiloxane.

14. The method according to claim 1, wherein a coating is derived from a composition selected from:

(i) an organic coating comprising a low molecular weight reactive diluent selected from monomeric acrylates;

an unsaturated oligomer selected from urethane acrylates, polyether acrylates, epoxy acrylates and polyester acrylates;

a solvent; and

a photoinitiator;

(ii) an organic/inorganic hybrid coating comprising a low molecular weight reactive component selected from monomeric acrylates and/or an unsaturated oligomeric component selected from urethane acrylates, polyether acrylates, epoxy acrylates and polyester acrylates;

a solvent; and

inorganic particles selected from silica and metal oxides, and optionally further comprising a photoinitiator; and

(iii) a hardcoat comprising inorganic particles contained in a polysiloxane.

15. The method according to claim 1, wherein a coating is derived from a UV-curable composition comprising monomeric and oligomeric acrylates, and a photoinitiator.

16. The method according to claim 1, wherein a coating is derived from a UV-curable composition comprising monomeric acrylates, silica particles and a photoinitiator.

17. The method according to claim 1, wherein a coating is derived from a composition comprising:

(a) from about 5 to about 50 weight percent solids, the solids comprising from about 10 to about 70 weight percent silica and from about 90 to about 30 weight percent of a partially polymerized organic silanol of the formula RSi(OH)₃, wherein R is selected from methyl and up to about 40% of a group selected from the group consisting of vinyl, phenyl, gamma-glycidoxypropyl, and gamma-methacryloxypropyl, and

(b) from about 95 to about 50 weight percent solvent, the solvent comprising from about 10 to about 90 weight percent water and from about 90 to about 10 weight percent lower aliphatic alcohol,

wherein the coating composition has a pH of from about 3.0 to about 8.0.

18. The method according to claim 1, wherein a coating is derived from a thermally-curable composition comprising an epoxy resin and silica particles.

19. The method according to claim 1, wherein a coating is derived from a composition comprising a cross-linkable organic polymer selected from a polyethylene imine (PEI), polyester and polyvinylalcohol (PVOH), and further comprising a cross-linking agent.

20. The method according to claim 1, wherein said coating layer has a dry thickness of from 1 to 20 microns.