Biomass pretreatment

• US 8,597,431 B2
• Filed: 09/23/2010
• Issued: 12/03/2013
• Est. Priority Date: 10/05/2009
• Status: Active Grant

• Current Assignee: Andritz Incorporated
• Original Assignee: Andritz Incorporated
• Inventors: McDonald, William F., Carlson, David Charles, Bradford, Wiley D.
• Primary Examiner(s): Mayes, Melvin C
• Assistant Examiner(s): COHEN, STEFANIE J
• Application Number:
  US12/888,957
• Publication Number:
  US 20110079219A1
• Time in Patent Office: 1,167 Days
• Field of Search: None
• US Class Current: 127/1
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

A system for pre-treating biomass for the production of ethanol is provided. The system comprises a method for pre-treating biomass. The method comprises supplying biomass to a steaming bin, wherein the biomass is mixed with water, and inputting the steamed biomass to a first pretreatment reactor, wherein the steamed biomass comprises liquids and solids. The method also comprises removing a bulk of liquids from the solids and feeding the solids into a second pretreatment reactor. The method further comprises applying a pressure drop to the solids in the second pretreatment reactor, wherein the pressure drop opens up a structure of the solids, and sending the solids to a fermentation process for ethanol processing.

Claims

1. A method for pre-treating biomass, comprising:

steaming biomass in a steaming bin;

processing the steamed biomass in a first pressurized pretreatment reactor which contains the biomass, acid and liquids, wherein the process disperses sugars in the biomass to the liquids, wherein the processing of the steamed biomass is performed under pressure in the first pretreatment reactor

removing at least some portion of the liquids with the sugars from the processed biomass to generate substantial solids;

feeding the substantial solids to a second pressurized pretreatment reactor while maintaining the substantial solids under pressure from the first pretreatment reactor to the second pressurized pretreatment reactor;

processing the substantial solids in the second pretreatment reactor at a pH level in a range of 1.3 to 2.0 pH and under pressure;

applying a rapid pressure drop to the substantial solids in the second pretreatment reactor or as the processed biomass flows from the second pretreatment reactor, wherein the rapid pressure drop opens up a cellulosic structure of the substantial solids; and

sending the substantial solids with opened cellulosic structure to at least one of a saccharification process and a fermentation process for ethanol processing.

2. The method of claim 1, wherein the removing comprises releasing a maximum amount of pentose sugar from the steamed biomass.

3. The method of claim 1, wherein the biomass being steam is biomass that comprises up to 35 percent corn cobs.

4. The method of claim 1, wherein the biomass being steam is biomass that comprises about 30 percent corn cobs.

5. The method of claim 1, wherein the steaming of biomass comprises steaming biomass that is up to 50 percent corn leaves and husks.

6. The method of claim 1, wherein the biomass being steamed is biomass comprising about 45 percent corn leaves and husks.

7. The method of claim 1, wherein the biomass being steamed is biomass comprising up to 30 percent corn stalks.

8. The method of claim 1, wherein the biomass being steamed is biomass including about 20 percent corn stalks.

9. The method of claim 1, wherein the steaming further comprises mixing the water with the biomass to a range of about 10 to 50 percent moisture.

10. The method of claim 1, wherein the biomass being steamed comprises about 30 to 55 percent cellulose.

11. The method of claim 1, wherein the biomass being steamed comprises about 20 to 50 percent hemicellulose.

12. The method of claim 1, wherein the biomass being steamed comprises about 10 to 25 percent lignin.

13. The method of claim 1, wherein the biomass being steamed comprises about 1 to 10 percent ash.

14. The method of claim 1, wherein the steaming comprises heating the biomass to about 100 degrees Celsius.

15. The method of claim 1, wherein the removing comprises forcing the biomass out of the first pretreatment reactor with water and mechanical agitation.

16. The method of claim 1, wherein the removing comprises counter current washing of the processed biomass.

17. The method of claim 1, wherein the liquids with sugars comprises 1 to 8 percent solids.

18. The method of claim 1, wherein the liquids with sugars comprises 1 to 6 percent solids.

19. The method of claim 1, wherein the liquids with sugars comprises 1 to 5 percent solids.

20. The method of claim 1, wherein the liquids with sugars comprises 1 to 4 percent solids.

21. The method of claim 1, wherein the liquids with sugars comprises 1 to 8 percent xylose.

22. The method of claim 1, wherein the liquids with sugars comprises 0 to 1 percent glucose.

23. The method of claim 1, wherein the liquids with sugars comprises 0 to 1 percent arabinose.

24. The method of claim 1, wherein the feeding comprises pressing the processed biomass to a consistency of 40 to 60 percent solids.

25. The method of claim 1, wherein the processed biomass comprises 45 to 70 percent cellulose.

26. The method of claim 1, wherein the process biomass comprises 5 to 20 percent hemicellulose.

27. The method of claim 1, wherein the processed biomass comprises 20 to 32 percent lignin.

28. The method of claim 1, wherein the processed biomass comprises 1 to 10 percent ash.

29. The method of claim 1, wherein the feeding comprises heating the processed biomass in a range of 150 degrees Celsius to about 210 degrees Celsius.

30. The method of claim 29, wherein the heating comprises applying direct contact steam to the processed biomass.

31. The method of claim 1, wherein the feeding comprises holding the processed biomass in the second pretreatment reactor for up to five minutes.

32. The method of claim 1, further comprising supplying an acid solution to the processed biomass.

33. The method of claim 32, wherein the acid solution is at an acid level from a range of 0.1 to 4.0 percent w/w.

34. The method of claim 32, wherein the acid solution is at an acid level from a range 0.25 to 2.0 percent w/w.

35. The method of claim 32, wherein the acid solution is at an acid level from a range 0.4 to 1.5 percent w/w.

36. The method of claim 32, wherein the acid solution is at an acid level from a range 0.5 to 1.25 percent w/w.

37. The method of claim 32, wherein the acid solution is at an acid level from about 0.75 to 1.0 percent w/w.

38. The method of claim 1, wherein the removing comprises conducting a steeping process at a temperature range from 50 degrees Celsius to 180 degrees Celsius.

39. The method of claim 1, wherein the removing comprises conducting a steeping process at a temperature range from 75 degrees Celsius to 170 degrees Celsius.

40. The method of claim 1, wherein the removing comprises conducting a steeping process at a temperature range from 100 degrees Celsius to 160degrees Celsius.

41. The method of claim 1, wherein the removing comprises conducting a steeping process at a temperature range from 100 degrees Celsius to 130degrees Celsius.

42. The method of claim 1, wherein the removing comprises conducting a steeping process at a temperature range from 100 degrees Celsius to 120degrees Celsius.