Processing of titanium-aluminum-vanadium alloys and products made thereby

• US 8,597,443 B2
• Filed: 09/12/2011
• Issued: 12/03/2013
• Est. Priority Date: 05/09/2003
• Status: Active Grant

• Current Assignee: ATI Properties LLC
• Original Assignee: ATI Properties Incorporated (Allegheny Technologies Incorporated)
• Inventors: Hebda, John J., Hickman, Randall W., Graham, Ronald A.
• Primary Examiner(s): ZHENG, LOIS L
• Application Number:
  US13/230,143
• Publication Number:
  US 20120003118A1
• Time in Patent Office: 813 Days
• Field of Search: 148/421, 148668-670, 420417-418, 420/420
• US Class Current: 148/670
• CPC Class Codes: B21B 1/26 by hot-rolling , e.g. Steckel hot mill
• CPC Class Codes: C22C 14/00 Alloys based on titanium
• CPC Class Codes: C22F 1/183 of titanium or alloys based thereon

Abstract

A method of forming an article from an α-β titanium including, in weight percentages, from about 2.9 to about 5.0 aluminum, from about 2.0 to about 3.0 vanadium, from about 0.4 to about 2.0 iron, from about 0.2 to about 0.3 oxygen, from about 0.005 to about 0.3 carbon, from about 0.001 to about 0.02 nitrogen, and less than about 0.5 of other elements. The method comprises cold working the α-β titanium alloy.

Claims

1. A method of forming an article from an α

-β

titanium alloy,

the α

-β

titanium alloy consisting essentially of, in weight percentages, from 2.9 to 5.0 aluminum, from 2.0 to 3.0 vanadium, from 0.4 to 2.0 iron, from 0.2 to 0.3 oxygen, from 0.005 to 0.3 carbon, from 0.001 to 0.02 nitrogen, from 0 to 0.1 chromium, from 0 to 0.1 nickel, incidental impurities, and titanium,

the method consisting essentially of;

α

-β

working the α

-β

titanium alloy at a temperature greater than 1600°

F. to provide the α

-β

titanium alloy with a microstructure conducive to subsequent cold deformation;

reducing a thickness of the α

-β

titanium alloy at a temperature in the range of ambient temperature to less than 1250°

F. by a process comprising at least two cold rolling steps, wherein in at least one cold rolling step a thickness of the α

-β

titanium alloy is reduced by 30% to 60%; and

annealing the α

-β

titanium alloy intermediate successive cold rolling steps and thereby reducing stresses within the α

-β

titanium alloy;

wherein the article has tensile strength of at least 120 ksi and ultimate tensile strength of at least 130 ksi.

2. The method of claim 1, wherein the cold rolling steps are conducted at a temperature that is no greater than 400°

F. below the beta transus temperature of the alloy.

3. The method of claim 1, wherein the cold rolling steps are conducted at a temperature that is in the range of 700°

F. below the beta transus temperature of the alloy to 400°

F. below the beta transus temperature of the alloy.

4. The method of claim 1, wherein at least one anneal intermediate successive cold rolling steps is conducted on a continuous anneal furnace line.

5. A method of making a plate from an α

-β

titanium alloy,

the α

-β

titanium alloy consisting essentially of, in weight percentages, from 2.9 to 5.0 aluminum, from 2.0 to 3.0 vanadium, from 0.4 to 2.0 iron, from 0.2 to 0.3 oxygen, from 0.005 to 0.3 carbon, from 0.001 to 0.02 nitrogen, from 0 to 0.1 chromium, from 0 to 0.1 nickel, incidental impurities, and titanium,

the method consisting essentially of;

α

-β

working the α

-β

titanium alloy at a temperature greater than 1600°

F. to provide the α

-β

titanium alloy with a microstructure conducive to subsequent cold deformation; and

cold rolling the α

-β

titanium alloy at a temperature that is no greater than 400°

F. below the beta transus temperature of the alloy;

wherein the plate has tensile strength of at least 120 ksi and ultimate tensile strength of at least 130 ksi.

6. The method of claim 5, wherein cold rolling the α

-β

titanium alloy comprises rolling the alloy at a temperature that is in the range of 700°

F. below the beta transus temperature of the alloy to 400°

F. below the beta transus temperature of the alloy.

7. The method of claim 5, wherein cold rolling the α

-β

titanium alloy includes at least two cold rolling steps with a mill anneal between successive cold rolling steps, wherein the annealing reduces stresses within the α

-β

titanium alloy.

8. The method of claim 7, wherein in at least one cold rolling step a thickness of the α

-β

titanium alloy is reduced by 30% to 60%.

9. A method of forming an article from an α

-β

titanium alloy,

the α

-β

titanium alloy consisting essentially of, in weight percentages, from 2.9 to 5.0 aluminum, from 2.0 to 3.0 vanadium, from 0.4 to 2.0 iron, from 0.2 to 0.3 oxygen, from 0.005 to 0.3 carbon, from 0.001 to 0.02 nitrogen, from 0 to 0.1 chromium, from 0 to 0.1 nickel, incidental impurities, and titanium,

the method consisting essentially of;

α

-β

working the α

-β

titanium alloy at a temperature greater than 1600°

F. to provide the α

-β

titanium alloy with a microstructure conducive to subsequent cold deformation; and

cold working the α

-β

titanium alloy at a temperature in the range of ambient temperature to less than 1250°

F.;

wherein the article has tensile strength of at least 120 ksi and ultimate tensile strength of at least 130 ksi.

10. The method of claim 9, wherein cold working the α

-β

titanium alloy is conducted at a temperature in the range of ambient temperature up to 1000°

F.

11. The method of claim 9, wherein cold working the α

-β

titanium alloy includes cold rolling the α

-β

titanium alloy, and wherein the article is selected from the group consisting of a bar, a sheet, a strip, a coil, and a plate.

12. The method of claim 9, wherein cold working the α

-β

titanium alloy includes reducing a thickness of the α

-β

titanium alloy by at least two cold rolling steps with a mill anneal between successive cold rolling steps, wherein the annealing reduces stresses within the α

-β

titanium alloy.

13. The method of claim 12, wherein at least one anneal intermediate successive cold rolling steps is conducted on a continuous anneal furnace line.

14. The method of claim 12, wherein in at least one of the cold rolling steps, a thickness of the α

-β

titanium alloy is reduced by 30% to 60%.

15. The method of claim 9, wherein cold working the α

-β

titanium alloy includes working the α

-β

titanium alloy at less than 1250°

F. by at least one technique selected from the group consisting of rolling, forging, extruding, pilgering, rocking, drawing, flow-turning, liquid compressive forming, gas compressive forming, hydro-forming, bulge forming, roll forming, stamping, fine-blanking, die pressing, deep drawing, coining, spinning, swaging, impact extruding, explosive forming, rubber forming, back extrusion, piercing, stretch forming, press bending, electromagnetic forming, and cold heading.

16. The method of claim 9, wherein cold working the α

-β

titanium alloy includes at least one of pilgering and rocking the α

-β

titanium alloy, and wherein the article is one of a tube and a pipe.

17. The method of claim 9, wherein cold working the α

-β

titanium alloy includes drawing the α

-β

titanium alloy, and wherein the article is selected from the group consisting of a rod, a wire, a bar, and a tubular hollow.

18. The method of claim 9, wherein the article has a thickness up to 4 inches, and wherein room temperature properties of the article include elongation of at least 10%.

19. The method of claim 18, wherein the article has elongation of at least 12%.

20. The method of claim 9, wherein the article can be bent around a radius of 4 times its thickness without failure of the article.

21. The method of claim 9, wherein yield strength, ultimate tensile strength, and elongation properties of the article are each at least as great as for an identical article made of Ti-6Al-4V.

22. The method of claim 9, where the α

-β

titanium alloy has lower flow stress than Ti-6Al-4V alloy.