Bismuth oxide primer composition

• US 8,597,445 B2
• Filed: 02/01/2012
• Issued: 12/03/2013
• Est. Priority Date: 01/23/2004
• Status: Expired due to Fees

• Current Assignee: RA Brands LLC (RA Factors, Inc.)
• Original Assignee: RA Brands LLC (RA Factors, Inc.)
• Inventors: Pile, Donald A., John, Henry J. Jr.
• Primary Examiner(s): MCDONOUGH, JAMES E
• Application Number:
  US13/363,720
• Publication Number:
  US 20120125493A1
• Time in Patent Office: 671 Days
• Field of Search: 149/39, 149/37, 149/40, 149/108.6, 149/109.2, 149/109.4, 149/109.6
• US Class Current: 149/39
• CPC Class Codes: C06B 25/04 the nitrated compound being an aromatic
• CPC Class Codes: C06B 43/00 Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00 - C06B41/00
• CPC Class Codes: C06C 7/00 Non-electric detonators; Blasting caps; Primers

Abstract

A priming mixture is provided having a primary explosive and an oxidizer system containing bismuth oxide. The priming mixture generally is applicable to any application or device that employs ignition of a propellant or fuel, including, but not limited to, air bag gas generator systems, signaling devices, ejection seats, small or large arms ammunition primers, and the like.

Claims

1. A priming mixture comprising:

a primary explosive comprising up to approximately 70% of the priming mixture by weight;

a substantially non-hygroscopic oxidizer system comprising bismuth oxide, and having a texture sufficient to enable the oxidizer system to flow and form a substantially homogenous priming mixture when blended with the primary explosive; and

wherein the oxidizer system comprises approximately 20%-70% of the priming mixture by weight, and includes between about 1%-100% bismuth oxide by weight of the oxidizer system; and

a gas producing agent present in amount of about 5% to about 25% by weight of the priming mixture.

2. The priming mixture of claim 1, wherein the primary explosive comprises a compound selected from salts of trinitroresorcinol (TNR), salts of dinitrobenzofuroxan (DNBF), diazodinitrophenol (DDNP), salts of 5-nitrotetrazole, salts of fulminate, salts of hydrazoic acid, tetrazene, salts of tetrazene, silver salt of tetrazene, cuprous salt of tetrazene, salts of amino guanidine, salts of cyanamide, nitrocyanamide salts, nitrophenol salts, nitrosophenol salts, nitramine salts, salts of metazonic acid, oxalic salts, peroxides, acetylide salts, nitrogen sulphide, nitrogen selenide, thiocyanic salts, silver perchlorate, hexanitromannitol, barium trinitroresorcinol, thallium trinitroresorcinol, barium-lead trinitroresorcinol, copper-lead trinitroresorcinol, calcium-barium trinitroresorcinol, sodium dinitrobenzofuroxan, potassium dinitrobenzofuroxan, silver dinitrobenzofuroxan, mercury fulminate, lead azide, lead styphnate, silver azide, or any combination thereof.

3. The priming mixture of claim 1, wherein the oxidizer system further comprises a secondary oxidizer selected from zinc peroxide, manganese dioxide, molybdenum trioxide, strontium nitrate, strontium peroxide, tin oxide, iron oxide, potassium nitrate, barium nitrate, or any combination thereof.

4. The priming mixture of claim 1, wherein the gas producing agent is selected from pentaerythritol tetranitrate, trinitrotoluene, or a combination thereof.

5. The priming mixture of claim 1, further comprising a reducing agent selected from aluminum, boron, calcium silicide, magnesium, magnesium-aluminum alloy, silicon, titanium, tungsten, zirconium, nitrocellulose, or any combination thereof.

6. The priming mixture of claim 1, further comprising a sensitizer selected from tetrazene, ground glass, or a combination thereof.

7. The priming mixture of claim 1, and further comprising a conducting component selected from aluminum, carbon black, titanium, zirconium, silver, gold, uranium, lead azide, silver azide, or any combinations thereof.

8. The priming mixture of claim 1 and further comprising:

0% to about 30% by weight of a sensitizer;

0% to about 20% by weight of a reducing agent; and

0% to about 20% by weight of a conductive component.

9. A priming mixture comprising:

from about 20% about 70% by weight of a primary explosive;

from about 10% to about 70% by weight of a substantially non-hygroscopic oxidizer system comprising approximately 5%-100% bismuth oxide and having a texture sufficient to flow with the primary explosive to form a substantially homogeneous priming mixture when the oxidizer system is blended with the primary explosive;

from about 5% to about 25% by weight of a gas producing agent;

from about 5% to about 20% by weight of a sensitizer;

from about 5% to about 20% by weight of a reducing agent; and

from about 0% to about 20% by weight of a conductive component.

10. The priming mixture of claim 9, wherein the wherein the primary explosive comprises a compound selected from metal salts of trinitroresorcinol, metal salts of dinitrobenzofuroxan, potassium dinitrobenzofuroxane (KDNBF), diazodinitrophenol (DDNP), mercury fulminate, lead azide, lead styphnate, silver azide, tetrazene, metal salts of 5-nitrotetrazole, or any combination thereof.

11. The priming mixture of claim 9, wherein the oxidizer system further comprises a secondary oxidizer selected from zinc peroxide, manganese dioxide, molybdenum trioxide, strontium nitrate, strontium peroxide, tin oxide, iron oxide, potassium nitrate, barium nitrate, or any combination thereof.

12. The priming mixture of claim 9, wherein the gas producing agent is selected from pentaerythritol tetranitrate, trinitrotoluene, or a combination thereof.

13. The priming mixture of claim 9, wherein the reducing agent is selected from aluminum, boron, calcium silicide, magnesium, magnesium-aluminum alloy, silicon, titanium, tungsten, zirconium, nitrocellulose, or any combination thereof.

14. The priming mixture of claim 9, wherein the sensitizer is selected from tetrazene, ground glass, or a combination thereof.

15. The priming mixture of claim 9, wherein the conducting component is selected from aluminum, carbon black, titanium, zirconium, silver, gold, uranium, lead azide, silver azide, or any combinations thereof.

16. The priming mixture of claim 9, wherein the priming mixture comprises from about 0.1% to about 10% by weight of the conductive component.

17. The priming mixture of claim 9, further comprising up to about 2.0% by weight of a binder.

18. A method of preparing a priming mixture for detonation of explosive devices including small arms ammunition, comprising:

mixing a primary explosive material comprising approximately 20% to approximately 70% by weight of the priming mixture with water in an amount sufficient to substantially wet the priming mixture and form a wet explosive mixture;

adding to and mixing with the wet explosive mixture about 5% to about 25% by weight of a gas producing agent and at least one of;

about 0% to about 30% by weight of a sensitizer; and

about 0% to about 20% by weight of a reducing agent; and

about 0% to about 20% by weight of a conductive component;

blending a substantially non-hygroscopic, non-toxic oxidizer system into the wet explosive mixture, the oxidizer system comprising about 10% to about 70% by weight of the priming mixture, and including approximately 1% to approximately 100% bismuth oxide by weight of the oxidizer system and having a texture sufficient to form a substantially homogeneous priming mixture after blending with the wet explosive mixture; and

drying the mixture.

19. The method of claim 18, further comprising adding about 0.1% to about 20% by weight of a conductive component to the wet primary explosive mixture.

20. The method of claim 18 wherein drying the wet priming mixture comprises applying the wet priming mixture to a plate having a series of recesses in which the wet priming mixture is formed into pellets.