Amperometric in-pipe electrochemical sensing probe

• US 8,608,926 B2
• Filed: 11/20/2008
• Issued: 12/17/2013
• Est. Priority Date: 11/20/2008
• Status: Active Grant

• Current Assignee: Neroxis SA
• Original Assignee: Neroxis SA
• Inventors: De Coulon, Yves, Beriet Herrera, Carine
• Primary Examiner(s): LEONG, SUSAN DANG
• Application Number:
  US12/274,870
• Publication Number:
  US 20100122905A1
• Time in Patent Office: 1,853 Days
• Field of Search: 204/400, 204/403.02, 204415-419, 204/422, 204/433, 205/775, 205/778.5, 205/782.5, 2057865-7875, 205789-7895, 205/793
• US Class Current: 204/416
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors

Abstract

A sensing probe intended to measure the content of an oxygen reducible substance in a fluid, includes:

• • a probe body containing an interface and processing circuit,
  • a dry sensing head including an amperometric sensor intended to measure the content of the oxygen reducible substance. The sensing head is removable. The sensing head and the probe body include respectively coupling elements cooperating with each other and able to be separated, and the sensing probe furthermore includes connecting elements designed to connect the removable sensing head to the interface and processing circuit of the probe body.

Claims

1. A sensing probe, configured to measure the content of an oxygen reducible substance in a fluid, comprising:

a probe body containing an interface and processing circuit,

a dry sensing head comprising an amperometric sensor configured to measure the content of said oxygen reducible substance,

wherein said dry sensing head is removable from said probe body, said dry sensing head and said probe body comprising respective coupling means cooperating with each other and configured to be separable to allow removing of said dry sensing head from said probe body,

wherein said sensing probe further comprises connecting elements configured to connect in a removable manner said removable dry sensing head to the interface and processing circuit of said probe body, and

wherein the removable dry sensing head further comprises a cap and a printed circuit board (PCB) fixedly attached to the cap, said printed circuit board (PCB) being mounted transversally with respect to said sensing probe, the amperometric sensor being mounted on the printed circuit board (PCB), on a face opposed to the probe body.

2. The sensing probe according to claim 1, wherein said coupling means of said probe body comprises a male threaded portion and wherein said coupling means of said removable dry sensing head comprises a female threaded portion that cooperates with said male threaded portion of said probe body.

3. The sensing probe according to claim 2, wherein it furthermore comprises sealing means between the probe body and the removable dry sensing head.

4. The sensing probe according to claim 1, further comprising a non-volatile memory and an interface integrated circuit, said non-volatile memory and interface integrated circuit being mounted on said printed circuit board (PCB), and wherein said non-volatile memory stores calibration data of said amperometric sensor.

5. The sensing probe according to claim 4, wherein said printed circuit board (PCB) furthermore comprises metalized concentric circular traces, said metalized concentric traces being engraved on the side opposed to the amperometric sensor and being electrically connected to said amperometric sensor and said non-volatile memory.

6. The sensing probe according to claim 1, wherein a protective resin is casted onto the whole surface of the printed circuit board (PCB) on which the amperometric sensor is mounted, except the surface taken by said amperometric sensor.

7. The sensing probe according to claim 1 wherein said removable dry sensing head furthermore comprises lateral protecting tabs, said tabs being disposed on the periphery of the removable dry sensing head, and oriented vertically with respect to said printed circuit board (PCB).

8. The sensing probe according to claim 1, wherein said amperometric sensor is a micro fabricated silicon amperometric sensor.

9. The sensing probe according to claim 1, wherein said amperometric sensor comprises a working electrode, a counter electrode and a reference electrode, said electrodes being planar and micro structured.

10. The sensing probe according to claim 9, wherein the working electrode is covered by a selective membrane and wherein the selective membrane is covered partially or totally by a packaging membrane.

11. The sensing probe according to claim 9, wherein the working electrode and the counter electrode are covered by a selective membrane and wherein the selective membrane is covered partially or totally by a packaging membrane.

12. The sensing probe according to claim 1 wherein said interface and processing circuit furthermore comprises a wireless communication circuit, and wherein the probe body furthermore comprises a battery.

13. A sensing probe, configured to measure the content of an oxygen reducible substance in a fluid, comprising

a probe body containing a short range radio interface and processing circuit,

a dry sensing head comprising an amperometric sensor configured to measure the content of said oxygen reducible substance,

wherein, said dry sensing head is a removable dry sensing head, said dry sensing head and said probe body comprising respective coupling means cooperating with each other and configured to be separable to allow removal of said dry sensing head from said probe body, and

wherein said sensing probe further comprises a short range radio interface enabling wireless communication between said removable dry sensing head and the radio interface and processing circuit of said probe body.

14. The sensing probe of claim 13, wherein, the removable dry sensing head further comprises a cap and a printed circuit board (PCB) fixedly attached to the cap.

15. A sensing probe, configured to measure the content of an oxygen reducible substance in a fluid, said sensing probe comprising:

a dry sensing head; and

a probe body, the probe body comprising i) a housing, and ii) an interface and processing circuit located within the housing, wherein,

the sensing head comprises a cap, a printed circuit board fixed into the cap, an amperometric silicon sensor mounted on the printed circuit board, an interface integrated circuit mounted on the printed circuit board and transforming a sensor current signal from the sensor into a voltage signal,

the cap comprises a hole in correspondence to the silicon sensor, so that, when the sensing head is immersed into a fluid, electrodes of the silicon sensor are in contact with the fluid, and

each of the cap of the dry sensing head and the probe body comprise leak-tight complementary coupling elements providing for removal of the cap from the probe body.

16. The sensing probe of claim 15, wherein,

the probe body further comprises a plurality of connecting elements located at a first distal end of the probe body,

the sensing head further contact surfaces electrically bounded to the sensor and to the interface integrated circuit, the contact surfaces of the dry sensing head being plural concentric metalized traces, and

when the cap of the dry sensing head is mounted to the probe body, the connecting elements of the probe body make a connection with contact surfaces of the dry sensing head.

17. The sensing probe of claim 15, further comprising:

an electrical cable mechanically linked to the probe body and electrically connected to the interface and processing circuit,

the electrical cable i) providing power supply input to the interface and processing circuit, and ii) providing signal output from the interface and processing circuit to outside of the probe body.

18. The sensing probe of claim 15, wherein,

the housing comprises a first male threaded portion with exposed threads allowing the housing to be screwed into another element having a first female threaded portion complementary to the first male threaded portion;

and

the coupling element of the housing comprises a second male threaded portion at a first distal end, wherein,

the coupling element of the cap comprises a second female threaded portion complementary to the second male threaded portion allowing the cap to be screwed onto the first distal end of the housing in a leak-tight manner.

19. The sensing probe of claim 15, wherein the sensor is a chlorine sensor.

20. The sensing probe of claim 15, wherein,

the interface and processing circuit of the probe body is a first wireless interface, and

the dry sensing head further comprises a second wireless interface configured to communicate signals from the sensor to the first wireless interface of the probe body.