Lignin dewatering process

• US 8,613,781 B2
• Filed: 08/08/2008
• Issued: 12/24/2013
• Est. Priority Date: 08/08/2007
• Status: Active Grant

• Current Assignee: Harrison R. Cooper
• Original Assignee: Harrison R. Cooper
• Inventors: Cooper, Harrison R.
• Primary Examiner(s): Goloboy, James
• Assistant Examiner(s): GRAHAM, CHANTEL LORAN
• Application Number:
  US12/189,046
• Publication Number:
  US 20090038212A1
• Time in Patent Office: 1,964 Days
• Field of Search: 162/16, 162/17, 162/29, 445/50
• US Class Current: 44/550
• CPC Class Codes: C08H 6/00 Macromolecular compounds derived from lignin, e.g. tannins, humic acids
• CPC Class Codes: C08L 97/005 Lignin
• CPC Class Codes: D21C 11/0007 Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for volatile compounds obtained by decomposition of spent liquors in order to regenerate them D21C11/125; compounds obtained by fractionating the liquors in order to regenerate them D21C11/0042
• CPC Class Codes: D21C 9/002 by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives
• CPC Class Codes: D21C 9/18 De-watering de-watering in general F26B; Elimination of cooking or pulp-treating liquors from the pulpD21C9/002, D21C9/02 take precedence; paper-making machines D21F; strainers in digesters D21C7/00; presses in general B30B

Abstract

A lignin plastics solids mass containing lignin solids and liquids with up to 85% liquids can be partially dewatered by heating the lignin plastics solids mass to above a critical temperature at which time the lignin plastics solids agglomerate into lower moisture granular solids with between about 45% to 55% liquids releasing excess liquid which can be easily removed from the solids. The process is particularly useful for lignin plastics solids removed from black liquor from paper mills, or for similar lignin plastics solids masses, which can contain up to 85% liquids and which need to be dried to form useful lignin solids, which can be used for example for fuel. The dewatering process can be combined with the process for separating the lignin from the black liquor to separate the dewatered lignin directly from the black liquor.

Claims

1. A process for treating a substantially spent, alkaline and non-sulphite digestion liquor obtained from digestion of a cellulosic biomass, said digestion liquor containing lignin as a potential precipitant upon acidification of said digestion liquor, leaving substantially clarified residual liquid, said process comprising:

mixing into said spent digestion liquor a water soluble, surface active, polymeric, coagulant agent;

making a heated acidified dilution liquid;

mixing the heated acidified dilution liquid and the spent digestion liquor into which the water soluble, surface active, polymeric, coagulant agent has been mixed to produce a mixture having a pH below 7 and a temperature above a critical temperature;

cooling the mixture to a temperature below the critical temperature thus causing the lignin to agglomerate into granular lignin solids as a precipitate in a residual liquid, said granular lignin solids having a moisture content of less than about 60%; and

separating at least a portion of the residual liquid from the granular lignin solids to obtain dewatered granular lignin solids and clarified residual liquid.

2. The process of claim 1, wherein the temperature of the heated acidified dilution liquid is at a temperature above about 180°

F.

3. The process of claim 1, wherein the temperature of the digestion liquor is between about 200°

F. and 300°

F.

4. The process of claim 1, wherein the step of cooling the mixture includes the step of placing the mixture in a tank.

5. The process of claim 4, wherein the granular lignin solids collect in the bottom of the tank, and the step of separating at least a portion of the residual liquid from the granular lignin solids includes removing granular lignin solids collected in the bottom of the tank from the tank.

6. The process of claim 1, wherein the critical temperature is from about 170°

F. to about 200°

F.

7. The process of claim 1, wherein the step of mixing the heated acidified dilution liquid and the spent digestion liquor to produce a mixture having a pH below 7 is the step of mixing the heated acidified dilution liquid and the spent digestion liquor to produce a mixture having a pH below 3.5.